Thermosetting composition, cured film and color filter
A thermosetting and compositional technology, applied in the direction of optical filters, coatings, epoxy resin coatings, etc., can solve the problems of flatness and foreign matter tracking, and achieve high yield and high display quality
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[0169] Hereinafter, although an Example demonstrates this invention further, this invention is not limited to these Examples.
[0170] Compounds used in Synthesis Examples, Comparative Synthesis Examples, Reference Examples, Examples, and Comparative Examples are described for each component.
[0171] Low molecular weight epoxy compound (A):
[0172] A-1: Techmore VG3101L (trade name, Printec Co., Ltd.)
[0173] A-2: jER 157S65 (trade name, Mitsubishi Chemical Corporation)
[0174] Radical polymerizable monomer (b1) having an epoxy group:
[0175] b1-1: Glycidyl methacrylate
[0176] Other radically polymerizable monomers (b2):
[0177] b2-1: n-butyl methacrylate
[0178] b2-2: Monomethacryloxypropyl-modified polydimethylsiloxane (trade name: Silaplane FM-0721 (number average molecular weight catalog registration value: 5,000), JNC Co., Ltd. , hereinafter referred to as "FM-0721")
[0179] b2-3: N-cyclohexylmaleimide
[0180] b2-4: N-phenylmaleimide
[0181] Polymeriz...
Synthetic example 1
[0217] [Synthesis Example 1] Synthesis of Epoxy Group-Containing Polymer (Ba-1)
[0218] In a four-necked flask with a stirrer, MMP as a polymerization solvent, methacrylic acid as a radically polymerizable monomer (b1) having a carboxyl group, and other radically polymerizable monomers (b2) were added with the following composition: ) of n-butyl methacrylate and V-601 as a polymerization initiator were heated at 80°C for 3 hours and then at 90°C for 3 hours.
[0219]
[0220] The solution after completion|finish of reaction was cooled to room temperature, and the 30 weight% solution of the epoxy group containing polymer (Ba-1) was obtained. The weight average molecular weight determined by GPC analysis was 78,000, and the polydispersity was 2.6.
[0221] In addition, the term "30% by weight solution of the epoxy group-containing polymer (Ba-1)" here means that all the compounds added as described above are considered to be reacted and obtained from the weight of the solid...
Synthetic example 2
[0222] [Synthesis Example 2] Synthesis of epoxy group-containing polymer (Ba-2)
[0223] In the same manner as in Synthesis Example 1, the following components were added by the following weights to perform polymerization.
[0224]
[0225] The same treatment as in Synthesis Example 1 was performed to obtain a 30% by weight solution of an epoxy group-containing polymer (Ba-2). The weight average molecular weight determined by GPC analysis was 80,000.
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