Enamel material and preparation method and application thereof

An enamel and glaze technology, applied in the field of enamel materials and their preparation, can solve the problems of decreasing microwave output efficiency, accelerating diffusion speed, restricting the application of enamel materials, etc., and achieving the effects of improving microwave output efficiency and low microwave absorption rate

Active Publication Date: 2017-04-05
GUANGDONG MIDEA KITCHEN APPLIANCES MFG CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the current enamel technology requires a high temperature of more than 800 °C to sinter the enamel glaze on the surface of the metal substrate, a small amount of elemental carbon in the metal material undergoes a redox reaction with the glaze components to generate hydrogen, and the produced H 2 At higher temperatures, the diffusion speed is greatly accelerated, and it quickly diffuses from the inside of the glaze to the air layer, resulting in a pinhole appearance on the surface of the enamel layer, which affects the appearance and performance of the materials and products treated on the surface of the enamel layer; and because the enamel Part of the composition in the glaze has microwave-absorbing properties, resulting in microwave energy loss, which reduces the microwave output efficiency and affects the actual microwave energy utilization rate of the microwave oven.
The above two main problems of the prior art have seriously restricted the application of enamel materials in microwave ovens and microwave accessories, ovens and oven accessories, making the enamel materials' high temperature resistance, acid and alkali resistance, scratch resistance, corrosion resistance and other advantages unable to be used in Displayed in kitchen appliances such as microwave ovens and ovens

Method used

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  • Enamel material and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] The composition of the enamel material: the oxide of the first main group metal element: 18 parts by weight of Li 2 0, 6 parts by weight of Rb 2 O, 11 parts by weight of K 2 O; oxides of elements of the third main group: 2 parts by weight of B 2 o 3 , 3 parts by weight of Al 2 o 3 ; Oxides of the fourth subgroup element: 22 parts by weight of TiO 2 , 3 parts by weight of HfO 2 , 7 parts by weight of ZrO 2 ; The oxide of the fourth main group element: 17 parts by weight of SiO 2 , 4 parts by weight of SnO 2 ; Oxides of the fifth main group element: 2 parts by weight of Sb 2 o 3 , 1 part by weight of Bi 2 o3 ; The oxide of the fifth subgroup element: 1 part by weight of V 2 o 5 ; Oxides of the second subgroup element: 1 part by weight of ZnO; Oxides of lanthanide elements: 0.2 parts by weight of Ce 2 o 3 , 0.2 parts by weight of Yb 2 o 3 , 0.1 parts by weight of Pr 6 o 11 ; Wave-transparent resin: 1.5 parts by weight of polyether ether ketone.

[0062]...

Embodiment 2

[0064] The composition of the enamel material: the oxide of the first main group metal element: 10 parts by weight of Li 2 O, 15 parts by weight of Na 2 O, 15 parts by weight of K 2 O; oxides of elements of the third main group: 3 parts by weight of B 2 o 3 ; Oxides of the fourth subgroup element: 20 parts by weight of TiO 2 , 4 parts by weight of HfO 2 ; The oxide of the fourth main group element: 23 parts by weight of SiO 2 , 2 parts by weight of SnO 2 ; Oxides or / and inorganic salts of the fifth main group element: 3 parts by weight of Na 3 PO 4 , 1 part by weight of Bi 2 o 3 ; Oxides of the fifth subgroup element: 1 part by weight of Nb 2 o 5 ; Oxides of the second subgroup element: 1 part by weight of ZnO; Oxides of lanthanide elements: 0.2 parts by weight of Ce 2 o 3 , 0.2 parts by weight of Nd 2 o 3 ; Wave-transparent resin: 1.6 parts by weight of polyamide-polyimide.

[0065] Preparation method: melting treatment at 1000°C, second ball milling treatment...

Embodiment 3

[0067] The composition of the enamel material: oxides of metal elements of the first main group: 8 parts by weight of Li 2 O, 3 parts by weight of Ce 2 O, 6 parts by weight of K 2 O; oxides of elements of the third main group: 5 parts by weight of Al 2 o 3 , 1 part by weight of B 2 o 3 ; Oxides of the fourth subgroup element: 30 parts by weight of TiO 2 , 2 parts by weight of HfO 2 ; The oxide of the fourth main group element: 29 parts by weight of SiO 2 ; Oxides or / and inorganic salts of the fifth main group element: 12 parts by weight of Na 3 PO 4 ; The oxide of the fifth subgroup element: 1 part by weight of V 2 o 5 ; Oxides of the second subgroup element: 1 part by weight of ZnO; Oxides of lanthanide elements: 0.3 parts by weight of Pr 6 o 11 , 0.2 parts by weight of Nd 2 o 3 , 0.2 parts by weight of Yb 2 o 3 ; Wave-transparent resin: 1.3 parts by weight of polyimide.

[0068] Preparation method: melting treatment at 900°C, second ball milling treatment fo...

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Abstract

The invention discloses an enamel material, and a preparation method and application thereof. The enamel material contains oxides of first main group metal elements, oxides of third main group elements, oxides of fourth subgroup elements, oxides of fourth main group elements, oxides of lanthanide elements and a wave-transparent resin. The preparation method comprises the following steps: (1) mixing glaze materials to obtain a mixture; (2) melting the mixture to obtain a molten material; (3) carrying out water quenching treatment on the molten material to obtain a fusion cake; (4) carrying out first ball milling treatment on the fusion cake to obtain glaze powder; (5) mixing the glaze powder with the wave-transparent resin to obtain mixed powder; and (6) carrying out second ball milling treatment on the mixed powder to obtain the enamel material. The enameled coating formed by the enamel material has the advantages of low surface pinhole rate and low microwave absorptivity, thereby obviously enhancing the microwave output efficiency of the obtained product, such as microwave oven or baking oven.

Description

technical field [0001] The invention belongs to the field of coatings, in particular, the invention relates to an enamel material and its preparation method and application. Background technique [0002] Microwave ovens and ovens and other kitchen appliances have a high internal working environment temperature, long-term contact with oil, acidic and alkaline seasonings and detergents, and are very easy to come into contact with sharp and sharp objects, and microwave ovens and microwave accessories are exposed to microwave environments for a long time. It is required that the outer surfaces of microwave ovens, oven liners, and microwave oven and oven accessories should have properties such as high temperature resistance, acid and alkali resistance, scratch resistance, and corrosion resistance. In addition to meeting the above properties, the outer surface of microwave oven liners must also have The performance of low microwave loss, and the above-mentioned performance cannot ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C8/02C03C8/08
Inventor 郑文强赵莉薛小山孙宁栾春
Owner GUANGDONG MIDEA KITCHEN APPLIANCES MFG CO LTD
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