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Colored photocurable resin composition, color filter, and liquid crystal display device including same

A light-curing resin and resin-curing technology, which is applied in the direction of silicon organic compounds, instruments, optics, etc., can solve the problems of developing residue, insufficient developing property, poor solubility, etc., and achieve high sensitivity and reliability, excellent developing property and curing degree high effect

Active Publication Date: 2019-10-22
DONGWOO FINE CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when a pixel is formed using a colored photocurable resin composition with a high colorant content, there is a problem that a development residue is generated on the substrate of the unexposed portion during the development process, or the unexposed portion is developed in a peeled form that is not completely dissolved. , The developer clogs the color filter, and the remaining impurities that are not dissolved in the process adhere to the pixel and non-pixel substrates
However, the aforementioned composition has the disadvantages of insufficient developability and poor solubility

Method used

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  • Colored photocurable resin composition, color filter, and liquid crystal display device including same
  • Colored photocurable resin composition, color filter, and liquid crystal display device including same
  • Colored photocurable resin composition, color filter, and liquid crystal display device including same

Examples

Experimental program
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Effect test

manufacture example 1

[0163] Manufacture of Pigment Dispersion Composition (M1)

[0164] 13.5 parts by weight of pigment C.I. Pigment Red 177, 5.0 parts by weight of pigment dispersant DISPERBYK-2001 (manufactured by BYK Company), 61.5 parts by weight of propylene glycol monomethyl ether acetate as a solvent, and 4-hydroxy-4-methyl- 20 parts by weight of 2-pentanone were mixed and dispersed by a bead mill for 12 hours to prepare a pigment dispersion composition M1.

manufacture example 2

[0165] Synthesis of Binder Resin (B1) Containing a Monomer Represented by Chemical Formula (2)

[0166] 23.3g of 2-(bromomethyl) methyl acrylate (product of Aldrich Company), 15.8g of triethylamine (product of Aldrich Company) and 115.0g of propylene glycol methyl ether (product of TCI Company) were added to a dropping funnel equipped with , a thermometer, a cooling tube and a stirrer in a four-necked flask, and replace the inside of the four-necked flask with nitrogen. Next, after heating the flask to 90° C., 15.1 g of 2-(hydroxymethyl)methyl acrylate (product of Aldrich Company), 3.2 g of 2,2′-azobisisobutyronitrile (Wako Company product) and 110.0 g of propylene glycol methyl ether (TCI company product) mixed solution, carry out 0.5 hour polymerization reaction to generate the polymer containing pyran. Then, 37.5 g of methacrylic acid, 19.0 g of methyl methacrylate, 225.0 g of propylene glycol methyl ether, and 3.2 g of 2,2'-azobisisobutyronitrile (product of Wako Corpora...

manufacture example 3

[0167] Synthesis of Binder Resin (B2) Containing a Monomer Represented by Chemical Formula (3)

[0168] With 37.5g of methacrylic acid (produced by Gongrong Company), 19.0g of methyl methacrylate (produced by Gongrong Company), 9.1g of 2,5-dihydrofuran (produced by TCI Company) and propylene glycol methyl of 225.0g Ether (product of TCI Corporation) was charged into a four-necked flask equipped with a dropping funnel, a thermometer, a cooling tube, and a stirrer, and the inside of the four-necked flask was replaced with nitrogen. Next, after heating the flask to 70° C., 37.5 g of methacrylic acid, 19.0 g of methyl methacrylate, 9.1 g of 2,5-dihydrofuran, and 225.0 g of propylene glycol methyl ether ( TCI company product) and 3.2 g of 2,2'-azobisisobutyronitrile (Wako company product). After polymerization for 8 hours, the resultant was cooled to room temperature, and the inside of the four-necked flask was replaced with nitrogen, and 61.5 g of glycidyl methacrylate (product ...

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Abstract

The invention relates to a colored photo-curing resin composition, a color filter using the same and a liquid crystal display device using the same. The colored photo-curing resin composition is characterized by containing a photo-curing compound (A), adhesive resin (B), a photoinitiator (D) and a solvent (E). The photo-curing compound (A) contains compounds of the chemical formula (1) and the adhesive resin (B) contains monomer of the chemical formula (2) or chemical formula (3). The chemical formulas are described in the specification.

Description

technical field [0001] The present invention relates to a colored photocurable resin composition, a color filter, and a liquid crystal display device including the color filter, and more particularly, to a coloring method for producing a color filter with a high colorant content and high color reproducibility Photocurable resin composition. Background technique [0002] The color filter used in liquid crystal display devices is a color filter in which fine pixels such as red, green, and blue are formed on a transparent substrate such as glass by dyeing, printing, electrodeposition, and pigment dispersion. Among them, recently, in order to manufacture color filters used in liquid crystal display devices, the pigment dispersion method with high productivity and excellent fine processability, that is, the production method using a pigment-dispersed photocurable resin composition is often used. This method is a method carried out in the following manner: apply a pigment-dispers...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03F7/033G02B5/20G02B1/04G02F1/1335
CPCC07F7/21C08F2/50C08G18/8116C08L83/10G02B5/223G03F7/0007G03F7/0045G03F7/032G03F7/0757
Inventor 柳在范禹昌昊
Owner DONGWOO FINE CHEM CO LTD