Method and device for reduction absorption treatment of pollutants in natural gas boiler smoke
A technology for boiler flue gas and pollutants, which is applied in separation methods, chemical instruments and methods, and air quality improvement, etc., can solve the problems of inability to take into account removal rate and cost, high investment and operating costs
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Embodiment 1
[0030] The method for reducing and absorbing pollutants in natural gas boiler flue gas of the present embodiment includes the following steps:
[0031] S101. After the initial flue gas is cooled and dewatered by a gas / liquid heat exchanger, the dehydrated flue gas and flue gas condensed water are obtained, and the temperature is lowered to below 50° C.;
[0032] S102, adopting Na of 5% mass concentration 2 S aqueous solution is used as the absorption solution to reduce and absorb NOx in the flue gas in the reduction tower, and the main reaction is:
[0033] Na 2 S+2H 2 O=H 2 S+2NaOH
[0034] Na 2 S+H 2 O=NaHS+NaOH
[0035] 4H 2 S+6NO=N 2 +2N 2 O+4S+4H 2 o
[0036] NaHS+N 2 O=N 2 +S+NaOH.
[0037] The residence time of the cooled flue gas through the reduction absorption tower is 1s, and the liquid-gas ratio is 10L. m -3 .
[0038]S103. After atomization of the depleted part of the reduction absorption solution, it is used to neutralize the soluble acid gas in...
Embodiment 2
[0042] The method for reducing and absorbing pollutants in natural gas boiler flue gas of the present embodiment includes the following steps:
[0043] S201. After the initial flue gas is cooled and dewatered by a gas / liquid heat exchanger, the dehydrated flue gas and flue gas condensed water are obtained, and the temperature is lowered to below 50° C.;
[0044] S202, adopt the Na of 15% mass concentration 2 S aqueous solution is used as the absorption solution to reduce and absorb NOx in the flue gas in the reduction tower, and the main reaction is:
[0045] Na 2 S+2H 2 O=H 2 S+2NaOH
[0046] Na 2 S+H 2 O=NaHS+NaOH
[0047] 4H 2 S+6NO=N 2 +2N 2 O+4S+4H 2 o
[0048] NaHS+N 2 O=N 2 +S+NaOH.
[0049] The residence time of the flue gas after the cooling through the reduction absorption tower is 4s, and the liquid-gas ratio is 25L. m -3 .
[0050] S203. After atomizing the deficient part of the reduction absorption solution, it is used to neutralize the soluble a...
Embodiment 3
[0054] The device for reducing pollutants in natural gas boiler flue gas in this embodiment includes a three-way flue 1, a gas / liquid heat exchanger 2, a reduction absorption tower 3, an induced draft fan 4 and a discharge cylinder 5;
[0055] The three-way flue 1 is connected to the flue gas outlet of the boiler, one outlet of the three-way flue 1 is connected to the flue gas inlet of the gas / liquid heat exchanger 2 through the flue pipe 6, and the other outlet is connected to the discharge cylinder 5 Connection, since the three-way flue 1 is provided, it can be used to balance the pressure in the combustion chamber of the natural gas boiler. In addition, the liquid inlet of the gas / liquid heat exchanger 2 communicates with the user heating return pipe 11 , and the liquid outlet communicates with the user heating water supply pipe 12 for recovering waste heat from flue gas. The temperature of the flue gas is reduced to below 50°C through heat exchange in the gas / liquid heat e...
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