Indium-based metal organic framework wrapped functional positive ion Ru(bpy)32+ fluorescent material and preparation method therefor

An organic framework and fluorescent material technology, applied in the field of fluorescent materials, can solve problems such as undiscovered public documents, and achieve the effect of prolonging fluorescent life and simple process

Inactive Publication Date: 2015-12-16
BEIJING INSTITUTE OF TECHNOLOGYGY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] At present, no publications identical or similar to the application of the present invention have been found

Method used

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  • Indium-based metal organic framework wrapped functional positive ion Ru(bpy)32+ fluorescent material and preparation method therefor
  • Indium-based metal organic framework wrapped functional positive ion Ru(bpy)32+ fluorescent material and preparation method therefor
  • Indium-based metal organic framework wrapped functional positive ion Ru(bpy)32+ fluorescent material and preparation method therefor

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Embodiment 1

[0040] Indium-Based Metal-Organic Framework Encapsulated Functional Cation Ru(bpy) 3 2+ Fluorescent material In(BTB)(OA) 1 / 2 Ru 1 / 2 (bpy) 3 / 2 Synthesis

[0041] 0.08mmol hydrated indium nitrate In(NO 3 ) 3 .XH 2 O was dissolved in 6 mL of N,N-dimethylformamide (DMF), N,N-diethylformamide (DEF) and ethanol (EtOH) mixed solution (volume ratio 1:1:1), under slow stirring Add 0.010mmol 1,3,5-tris(4-carboxyphenyl)benzene (BTB), 0.15mmol oxalic acid (OA) and 0.0156mmol Ru(bpy) 3 2+ X, stir evenly at room temperature to obtain a mixed solution. The solution was transferred to a 20mL polytetrafluoroethylene reactor, heated at 130°C for 4 days, controlled at 10°C / min to room temperature, and red blocky crystals were obtained. The crystals were separated by filtration and air-dried under natural conditions to obtain the indium-based metal-organic framework-wrapped functional cation Ru(bpy) 3 2+ fluorescent material.

[0042] figure 1 Shown is the indium-based metal-organic...

Embodiment 2

[0044] Indium-Based Metal-Organic Framework Encapsulated Functional Cation Ru(bpy) 3 2+ Fluorescent material In(BTB)(OA) 1 / 2 Ru 1 / 2 (bpy) 3 / 2 Synthesis

[0045] 0.08mmol hydrated indium nitrate In(NO 3 ) 3 .XH 2 O was dissolved in 6 mL of N,N-dimethylformamide (DMF), N,N-diethylformamide (DEF) and ethanol (EtOH) mixed solution (volume ratio 1:1:1), under slow stirring Add 0.010mmol 1,3,5-tris(4-carboxyphenyl)benzene (BTB), 0.15mmol oxalic acid (OA) and 0.0156mmol Ru(bpy) 3 2+ X, stir evenly at room temperature to obtain a mixed solution. The solution was transferred to a 20mL polytetrafluoroethylene reactor, heated at 130°C for 5 days, controlled at 10°C / min to room temperature, and red blocky crystals were obtained. The crystals were separated by filtration and air-dried under natural conditions to obtain the indium-based metal-organic framework-wrapped functional cation Ru(bpy) 3 2+ fluorescent material.

Embodiment 3

[0047] Indium-Based Metal-Organic Framework Encapsulated Functional Cation Ru(bpy) 3 2+ Fluorescent material In(BTB)(OA) 1 / 2 Ru 1 / 2 (bpy) 3 / 2 Synthesis

[0048] 0.08mmol hydrated indium nitrate In(NO 3 ) 3 .XH 2 O was dissolved in 3 mL of N,N-dimethylformamide (DMF), and 0.010 mmol of 1,3,5-tris(4-carboxyphenyl)benzene (BTB), 0.15 mmol of oxalic acid (OA) and 0.0156 mmol of Ru were added under slow stirring (bpy) 3 2+ X, stir evenly at room temperature to obtain a mixed solution. The solution was transferred to a 20mL polytetrafluoroethylene reactor, heated at 130°C for 3 days, controlled at 10°C / min to room temperature, and red blocky crystals were obtained. The crystals were separated by filtration and air-dried under natural conditions to obtain the indium-based metal-organic framework-wrapped functional cation Ru(bpy) 3 2+ fluorescent material.

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Abstract

The invention belongs to the field of fluorescent materials and particularly relates to an indium-based metal organic framework wrapped functional positive ion Ru(bpy)32+ fluorescent material. The indium-based metal organic framework wrapped functional positive ion Ru(bpy)32+ fluorescent material is characterized in that the molecular formula of the fluorescent material is In(BTB)(OA)1/2Ru1/2(bpy)3/2, wherein BTB is 1,3,5-tri(4-carboxyl phenyl) benzene, OA is oxalic acid and byp is 2,2'-bipyridine. The indium-based metal organic framework wrapped functional positive ion Ru(bpy)32+ fluorescent material provided by the invention not only retains excellent properties of an indium-based metal organic framework, but also can change the fluorescent service life of the fluorescent material in an organic ligand framework, so that a purpose of prolonging the fluorescent service life of Ru(bpy)32+ to [mu]s level is achieved. The preparation method is simple in process and easy to operate.

Description

technical field [0001] The invention belongs to the field of fluorescent materials, in particular to an indium-based metal-organic framework wrapped functional cation Ru(bpy) 3 2+ fluorescent material. Background technique [0002] Metal-organic frameworks (MOFs) are porous solid-state materials composed of organic ligands and metal coordination compounds (molecular building blocks or MBBs). From the perspective of the components of metal-organic frameworks, the metal ions involved in the construction of metal-organic frameworks are no longer limited to commonly used transition metal ions (such as: Zn 2+ 、Cd 2+ 、Cu 2+ ) and rare earth ions, alkali metal ions (Li + 、Na + etc.), alkaline earth metal ions (Mg 2+ ) and some ions with special properties (such as: In 3+ , Zr 4+ ) and so on have joined the ranks of metal ions that can construct MOFs. The ligands for building metal-organic frameworks have developed from simple monodentate nitrogen-containing ligands to pol...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K11/06C09K11/02
Inventor 许颜清孔许净
Owner BEIJING INSTITUTE OF TECHNOLOGYGY
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