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Method for preparing activated carbon from corn stalk waste residue after xylitol preparation process

A technology for preparing activated carbon and corn stalks, which is applied in the field of agricultural waste recycling and reuse, can solve problems such as low added value, and achieve the effects of increasing quantity, increasing specific surface area, and enhancing impregnation effect.

Active Publication Date: 2017-08-29
QILU UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process of preparing xylooligosaccharides and xylitol from corn stalks will produce a large amount of waste residue, the main components of which are cellulose and lignin. The main way to treat waste residue is to burn it to generate heat for power generation, but this treatment method has relatively low added value

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035]Add 5g corn stalk waste sugar slag to the crucible, take 0.06g boric acid, 10ml 50% phosphoric acid, under the uniform stirring of an automatic stirrer, soak in a constant temperature water bath at 85°C for 1.5 hours; take out the soaked sample, and then put it in 450°C After heat preservation in a muffle furnace for 1 hour, take it out and cool it, then grind it slightly for 5 minutes, wash it with hot water until it is neutral, dry it at 105 degrees, cool it and grind it to powder, and get 2.26g of powdered activated carbon with a specific surface area of ​​917m 2 / g, boil the powdered activated carbon in 1mol / L HCl solution for 1h, then wash the filtrate with water until it becomes neutral, and dry it at 105°C for 8h to obtain activated activated carbon, and the measured specific surface area is 1365m 2 / g, the pore size is 10-15nm, the yield of activated carbon is 45.2%, and the consumption of phosphoric acid is 1.3%.

[0036] When the activated carbon is applied to ...

Embodiment 2

[0038] Add 5g corn stalk waste sugar slag to the crucible, take 0.05g boric acid, 8ml 50% phosphoric acid, and soak in a constant temperature water bath at 80°C for 1 hour under the uniform stirring of an automatic stirrer; take out the soaked sample, and then put it in 500°C After keeping warm in a muffle furnace for 1 hour, take it out and cool it, then grind it slightly for 4 minutes, wash it with hot water until it is neutral, dry it at 110°C, cool it and grind it to powder, and get 2.235g of powdered activated carbon with a specific surface area of ​​1026m 2 / g, boil the powdered activated carbon in 1mol / L HCl solution for 1.1h, then wash the filtrate with water until it is neutral, and dry it at 105°C for 8.5h to obtain activated activated carbon, and the measured specific surface area is 1459m 2 / g, the pore size is 5-18nm, the yield of activated carbon is 44.7%, and the consumption of phosphoric acid is 1.35%.

[0039] When the activated carbon is applied to the decolo...

Embodiment 3

[0041] Add 5g of corn stalk waste residue into the crucible, take 0.07g of boric acid and 12ml of 50% phosphoric acid, heat it in a muffle furnace at 500°C for 1 hour, grind it slightly for 5 minutes, wash the neutral paper with hot water, and bake it at 100°C Dry and grind to powder to get 2.285g of powdered activated carbon with a specific surface area of ​​1083m 2 / g, boil the powdered activated carbon in 1mol / L HCl solution for 1.2h, then wash the filtrate with water until it is neutral, and dry it at 105°C for 8.5h to obtain activated activated carbon, and the measured specific surface area is 1356m 2 / g, the pore size is 5-15nm, the yield of activated carbon is 45.7%, and the consumption of phosphoric acid is 1.4%.

[0042] When the activated carbon is applied to the decolorization and detoxification of corn stalk weak alkali hydrolyzate, the amount of activated carbon added is 0.8% of the mass of the hydrolyzate, the decolorization temperature is 37° C., and the decolor...

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Abstract

The present invention discloses a method for preparing active carbon by using corn straw waste residue obtained from a xylitol preparation process. The method comprises: (1) screening waste residue obtained through extraction of hemicelluloses from corn straws, adding a phosphoric acid solution and a set amount of boric acid, uniformly mixing, and soaking at a temperature of 70-90 DEG C; (2) taking the soaked sample, placing in a muffle furnace, and carrying out thermal insulation for 0.5-2 h at a temperature of 450-550 DEG C; (3) grinding the carbonized corn straw waste residue obtained in the step (2), and washing to achieve a neutral state; (4) drying the neutral active carbon obtained in the step (3), and grinding to obtain active carbon; and (5) activating the active carbon obtained in the step (4) with a HCl solution to obtain the finished product. According to the present invention, the simple physical and chemical method is used to prepare the hemicellulose-extracting corn straw waste residue into the powdery active carbon for decolorization and detoxification during the xylo-oligosaccharide preparation through extraction of hemicellulose from the corn straw raw material so as to achieve the high-value utilization of the corn straw raw material.

Description

technical field [0001] The invention belongs to the field of recovery and reuse of agricultural waste, and in particular relates to a method for preparing activated carbon from corn stalk waste residue after a xylitol preparation process. Background technique [0002] Corn stalk is one of the main agricultural wastes in the corn production areas in northern my country, and its main components are cellulose, hemicellulose and lignin. Corn stalks can be used for animal feed, pulp and paper making, and can also be used to prepare xylooligosaccharides, xylitol and the like. The production of xylooligosaccharides and xylitol from corn stalks is mainly to extract the hemicellulose pentosan in the raw material of corn stalks, and then degrade the pentosans to small molecule oligomeric xylosaccharides through chemical, biological, or biochemical methods. Sugar, hydrogenated to make xylitol. The process of preparing xylooligosaccharides and xylitol from corn stalks will produce a l...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/324C01B32/342C07C31/18C07C29/76
CPCC01P2006/12C01P2006/16C07C29/76C07C31/18
Inventor 吉兴香马浩陈嘉川田中建杨桂花刘珊珊
Owner QILU UNIV OF TECH