The invention provides a polymerization method for preparing fluorine-containing alternating copolymer through gradual transfer-addition-ending with free radicals under the condition of visible light. The preparation method includes the following steps that 1, two types of bifunctional monomers A and B, a photocatalyst, a reducing agent and mixed organic solvent are simultaneously added into a reaction reactor and stirred till a system is in a homogeneous phase, after deoxygenization is conducted four times, the reaction container is sealed, and a homogeneous polymerization system I is obtained; 2, the temperature of the reaction container is set to be 25 DEG C, the rotation speed is set to be 1500-2000 rpm, the homogeneous polymerization system I is subjected to a polymerization reaction under visible light, and the reaction time is 0.5-24 hours; 3, after the reaction is ended, the reaction container is opened, tetrahydrofuran is added to dilute the system, the diluted substance is poured into methyl alcohol for sediment, then suction filtration and drying are conducted, and the fluorine-containing alternating copolymer is obtained. By the application of the novel polymerization method, the fluorine-containing alternating copolymer is obtained successfully, and the polymerization method is a brand-new polymerization method.