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A kind of zinc-aluminum-magnesium wire drawing coated steel plate and its production method

A zinc-aluminum-magnesium wire drawing and coating steel plate technology, which is applied to layered products, metal layered products, chemical instruments and methods, etc. , the effect of high surface hardness

Active Publication Date: 2017-09-08
ANGANG STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

CN102848639A proposes an aluminum-based coated wire drawing board, but the price and cost of aluminum are relatively high, and the surface of aluminum is relatively soft, so there is a certain degree of difficulty in the process for wire drawing machining
However, the hardness of the surface of the galvanized layer is lower than that of the steel plate, and it is difficult to carry out wire drawing processing, and the coating layer is thinned to a certain extent after wire drawing, and the corrosion resistance is greatly affected, so it cannot completely replace the stainless steel wire drawing plate.
[0005] The surface hardness of ordinary zinc layer is significantly lower than that of stainless steel, and galvanized sheet is a composite sheet combined with zinc layer and substrate after all. Using traditional stainless steel wire drawing process to process traditional hot-dip galvanized products will cause many problems. Such as napping, delamination, straining, etc. Therefore, in order to completely replace the high-cost stainless steel wire drawing steel plate, it is necessary to improve it from various aspects such as galvanizing process, coating variety and wire drawing process.

Method used

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  • A kind of zinc-aluminum-magnesium wire drawing coated steel plate and its production method
  • A kind of zinc-aluminum-magnesium wire drawing coated steel plate and its production method
  • A kind of zinc-aluminum-magnesium wire drawing coated steel plate and its production method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] The main chemical composition of the steel substrate is C 0.003%, Si 0.16, Mn 0.56, S 0.01, P0.01, Ti 0.05% by mass percentage.

[0038] The chemical composition in the zinc-aluminum-magnesium coating is Al 6.2%, Mg 1.7%, Si 1.6%, Fe 0.2%, and the rest is Zn by mass percentage;

[0039] After the cold-rolled steel strip is continuously annealed and hot-dip galvanized aluminum-magnesium coating in the continuous hot-dip galvanizing unit, the thickness of the coating is 22 μm, and the surface hardness of the coating is HV156.

[0040]The chemical composition in the plating solution is Al 5.6wt%, Mg1.2wt%, Si1.2wt%, Fe0.17wt%, and the rest is Zn;

[0041] Steel plate containing 5vol% H 2 N 2 After annealing, dip into the plating solution after cooling, the temperature of the plating solution is 480°C, the temperature of the steel plate into the zinc pot is 460°C, and the dipping time of the steel plate in the plating solution is 5s;

[0042] After being cooled by an air...

Embodiment 2

[0049] The main chemical composition of the steel substrate is C 0.06% by mass percentage, Si 0.2, Mn 0.62, S 0.008, P0.012, Ti 0.02.

[0050] The chemical composition in the zinc-aluminum-magnesium coating is 13.3% by mass percentage of Al, 6.3% of Mg, 3.9% of Si, 0.5% of Fe, 0.12% of mixed rare earth, and the rest is Zn;

[0051] After the cold-rolled steel strip is continuously annealed and hot-dip galvanized aluminum-magnesium coating in the continuous hot-dip galvanizing unit, the thickness of the coating is 12 μm, and the surface hardness of the coating is HV200.

[0052] The chemical composition in the plating solution is Al 12wt%, Mg 5.3wt%, Si 3.1%, Fe0.5wt%, and the rest is Zn; in addition, the plating solution also contains 0.10wt% mixed rare earth;

[0053] Steel plate containing 30vol% H 2 N 2 After annealing, after cooling, immerse in the plating solution, the temperature of the plating solution is 550°C, the temperature of the steel plate into the zinc pot is ...

Embodiment 3

[0061] The main chemical composition of the steel substrate is C 0.035% by mass percentage, Si 0.32, Mn 0.52, S 0.009, P0.01, Ti 0.032.

[0062] The chemical composition in the zinc-aluminum-magnesium coating is 8.6% by mass percentage of Al, 4.1% of Mg, 2.5% of Si, 0.31% of Fe, 0.13% of mixed rare earth, and the rest is Zn;

[0063] After the cold-rolled steel strip is continuously annealed and hot-dip galvanized aluminum-magnesium coating in the continuous hot-dip galvanizing unit, the thickness of the coating is 30 μm, and the surface hardness of the coating is HV120.

[0064] The chemical composition in the plating solution is Al 8.2wt%, Mg3.3wt%, Si2.1wt%, Fe0.26wt%, the rest is Zn; the plating solution also contains 0.010wt% mixed rare earth

[0065] After the steel plate is annealed in N2 containing 15vol% H2, it is cooled and immersed in the plating solution. The temperature of the plating solution is 500°C, the temperature of the steel plate entering the zinc pot is 5...

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Abstract

The invention discloses a zinc-aluminum-magnesium wiredrawing coated steel plate, which comprises a steel substrate, and is characterized in that the wiredrawing surface is a passivation film, a zinc-aluminum-magnesium coating, and a steel substrate in sequence from the outside to the inside; Chemical film, zinc-aluminum-magnesium coating, steel substrate, the chemical composition of zinc-aluminum-magnesium coating is Al 6.1%-13.8% by mass percentage, Mg1.5%-6.7%, Si1.5%-4.2%, Fe0.1% ~0.5%, mixed rare earth ≤0.15%, the rest is Zn; the thickness of Zn-Al-Mg coating on the drawing surface is ≥8 μm, the thickness of Zn-Al-Mg coating on the undrawn surface is 12 μm~30 μm, the surface hardness of Zn-Al-Mg coating is HV120~HV200, and the drawing surface is transverse Ra≤0.5μm, Rz≤4, 200≥Rpc≥140( / cm).

Description

technical field [0001] The invention belongs to the field of hot-dip coating of steel plates, in particular to a zinc-aluminum-magnesium wire-drawn coated steel plate and a production method thereof. Background technique [0002] Due to its excellent anti-corrosion properties, hot-dip coated steel sheets have been widely used in automobiles, home appliances and other fields. Compared with the traditional hot-dip galvanized steel plate, the hot-dip galvanized aluminum-magnesium coating has better corrosion resistance, and has been highly valued by advanced steel companies in Europe, the United States, Japan and South Korea. South Korea's Posco, Japan's Nippon Steel, and large European and American steel companies have successively developed products such as ZM, Z6A3M, and Z10A3M. CN101812653A, US6235410B1, etc. developed zinc-based coatings containing aluminum and magnesium, which greatly improved corrosion resistance. [0003] Due to the addition of Al and Mg elements on t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B15/04B32B15/18C22C38/14C23F17/00C23C2/06B44C5/04
Inventor 杨洪刚李锋吕家舜周芳
Owner ANGANG STEEL CO LTD
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