Conductive transparent laminate, patterned conductive transparent laminate, and touch panel
A conductive, transparent, laminate technology, which is applied to conductive layers on insulating carriers, layered products, electrical digital data processing, etc. Display quality effects
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preparation example Construction
[0028] The preparation method of the conductive transparent laminate of the present invention comprises the following steps: providing a transparent substrate, forming an optical adjustment layer with a refractive index ranging from 1.33 to 1.52 at a wavelength of 400 nm on the transparent substrate to obtain a first laminate. A metal oxide layer is then formed on the optical adjustment layer to obtain a second laminated body. Then, the metal oxide layer of the second laminate is crystallized and annealed to obtain a transparent conductive layer (the carrier concentration range is 10×10 21 piece / cm 3 up to 20×10 21 piece / cm 3 ), that is, the conductive transparent laminate of the present invention is obtained.
[0029] The method of forming the optical adjustment layer on the transparent substrate is not particularly limited, and existing methods can be used, for example, dry coating method, wet coating method and the like can be used. In terms of production efficiency and...
preparation example 1
[0071] [Preparation Example 1] Composition for optical adjustment layer
[0072] 4 wt% of ultraviolet curable acrylic resin (model: 7150, manufactured by DIC, refractive index: 1.52), 93 wt% of methyl isobutyl ketone, 1 wt% of fluororesin (model: F-8261, manufactured by Degussa), 1 wt% The fluorine-based monomer (model: FSO, manufactured by DuPont) and 1 wt % photoinitiator (model: IRGACURE184, manufactured by Ciba) were evenly mixed to form a mixed solution. Next, based on the total amount of the mixed solution being 100 parts by weight, 3 parts by weight of silicon dioxide particles (model: MIBK-ST, manufactured by Nissan Chemical, average particle diameter: 10 nm) were added to obtain the mixture of Preparation Example 1. A composition for an optical adjustment layer.
preparation example 2 to 5
[0073] [Preparation Examples 2 to 5] Compositions for Optical Adjustment Layers
[0074] According to the types and usage amounts of the raw materials in Table 1 below, and referring to the same process of Preparation Example 1, the optical adjustment layer compositions of Preparation Examples 2 to 5 were prepared respectively. Among them, in Preparation Examples 4 and 5, zirconia (model: SZR-K, manufactured by Sakai Chemical Industry Co., Ltd., refractive index: 2.2, average particle diameter: 4 nm) was used instead of silica particles.
[0075] Table 1
[0076]
[0077] Note: "a": The amount used is calculated based on the total amount of the mixed solution as 100wt%;
[0078] "b": the amount used is calculated based on the total amount of the mixed solution being 100 parts by weight;
[0079] "---": Indicates no use.
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