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A kind of sludge heavy metal resource recovery extraction system and its extraction method

An extraction system and heavy metal technology, applied in chemical instruments and methods, sludge treatment, water/sludge/sewage treatment, etc., can solve harsh operating conditions, high safety risks, strong acids, and large consumption of oxidants and reducing agents, etc. question

Inactive Publication Date: 2018-12-25
HUZHOU SENNUO MEMBRANE TECH ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this wet extraction process using high-concentration strong acid as the working medium consumes a lot of strong acid, oxidant and reducing agent; large-scale strong acid wet extraction also has high requirements for equipment materials, and the operating conditions are harsh. High security risk
These all limit the popularization and application of wet extraction process

Method used

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  • A kind of sludge heavy metal resource recovery extraction system and its extraction method

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Embodiment Construction

[0029] Examples, see attached figure 1 , a sludge heavy metal resource extraction system, including a culture solution storage tank 1, a mixture of sulfur and ferrous sulfide is housed in the culture solution storage tank, the volume of the culture solution storage tank in this embodiment is 5m 3 ; The liquid outlet of the culture fluid storage tank is connected with two groups of bioreactors 2 in parallel, and the volume of each group of bioreactors is 60m 3 , the bioreactor is filled with water and microorganisms, the mixture in the culture liquid storage tank enters the bioreactor, and reacts with the water and microorganisms in the bioreactor for 5 hours, which can convert sulfur and pyrite into biologically active acids , using the active acid can effectively wash the heavy metals in the hazardous solid waste; the liquid outlets of the two sets of bioreactors are respectively connected to the biological leachate storage tank 3, and the volume of the biological leachate st...

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Abstract

The invention relates to an extraction system and method for recycling sludge heavy metal. A culture solution storage tank is connected with a bioreactor; the bioreactor is connected with a biological leaching solution storage tank; the biological leaching solution storage tank is connected with a biological leaching reaction tank; the biological leaching reaction tank is connected with a solid-liquid separation pool a, the bottom of the solid-liquid separation pool a is connected with a solid collection pool, and the upper portion of the solid-liquid separation pool a is connected with a PH adjusting pool; the PH adjusting pool is connected with a solid-liquid separation pool b, the bottom of the solid-liquid separation pool b is connected with a solid recycling pool, the upper portion of the solid-liquid separation pool b is connected with a fluoride-removal filter tank, the solid recycling pool is connected with the biological leaching reaction tank, and the fluoride-removal filter tank is connected with a storage tank a; a liquid discharging opening of the storage tank a is connected with the bioreactor; the storage tank a is connected with a storage tank b, and a liquid outlet of the storage tank b is connected with a membrane distillation and concentration device; the membrane distillation and concentration device is connected with an extraction electrolysis device. According to the extraction system and method, the bioleaching technology is adopted, solid waste is treated while heavy metal is recycled, and the extraction system and method are economical, environmentally friendly and safe.

Description

Technical field: [0001] The invention relates to the field of sludge treatment equipment, in particular to a sludge heavy metal resource extraction system and an extraction method thereof. Background technique: [0002] Yellow mud is the main pollutant produced in the production process of stainless steel. It contains iron, heavy metals, chromium and other heavy metals. It may cause serious harm to the environment after landfill. Therefore, the treatment of yellow mud has become an important issue in environmental protection. . [0003] At present, the main method used for the removal of heavy metals in sludge is wet leaching. Wet leaching is the use of acid solution to extract metals from solid waste. Hydrometallurgy has strong selectivity, high recovery efficiency, less environmental pollution, and is easy to mass produce and automate. However, this wet extraction process using high-concentration strong acid as the working medium consumes a lot of strong acid, oxidant a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/00C02F9/10
CPCC02F1/447C02F1/46104C02F9/00C02F11/00
Inventor 王中华刘宁生张传友梁钦吴东晗张杨威沈锦鹏罗建宇周云飞陈越平杨依然韩新宽
Owner HUZHOU SENNUO MEMBRANE TECH ENG
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