Prelithiated positive electrode material for lithium ion secondary battery
A secondary battery and positive electrode material technology, applied in the direction of secondary batteries, battery electrodes, nanotechnology for materials and surface science, etc., can solve the problems of strict environmental control requirements, complex processes, etc., and achieve good stability, The effect of improving the first delithiation capacity
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Embodiment 1
[0018] (1) Place analytically pure lithium fluoride in a ball mill protected by an inert atmosphere, and ball ink for 12 hours to obtain nanometer lithium fluoride for use;
[0019] (2) According to 88g positive electrode active material lithium nickel cobalt manganese ternary material LiNi 0.5 co 0.2 mn 0.3 o 2 , 0.5g conductive agent acetylene black, 0.7g binder PVDF, 2g nano-lithium fluoride Weigh each component, and add each component into an organic solvent to make a positive electrode slurry.
Embodiment 2
[0021] (1) Place the analytically pure lithium fluoride in a ball milling equipment protected by an inert atmosphere, and ball ink for 20 hours to obtain nanometer lithium fluoride for use;
[0022] (2) According to 90g positive electrode active material lithium nickel cobalt manganese ternary material LiNi0.4Co0.2Mn0.4O 2 , 2g conductive agent acetylene black and Ketjen black (mass ratio 1:1), 2g binder PVDF, 5g nano-lithium fluoride Weigh each component, add each component to an organic solvent to make a positive electrode slurry material.
Embodiment 3
[0024] (1) Place analytically pure lithium fluoride in a ball mill protected by an inert atmosphere, and ball ink for 48 hours to obtain nanometer lithium fluoride for use;
[0025] (2) According to 88-95 parts of positive electrode active material lithium-rich manganese-based solid solution material 0.8Li 2 MnO 3 0.8LiMoO 2 , 3g of conductive agent Super P-Li, 4g of binder PVDF, and 10g of nano-lithium fluoride were weighed for each component, and each component was added to an organic solvent to make a positive electrode slurry.
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