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Secondary-cyclone flying ash treatment method

A treatment method and fly ash technology, applied in the field of fly ash treatment, can solve problems such as poor wettability, difficulty in realizing catalyst recovery in fly ash, poor reactivity, etc.

Active Publication Date: 2016-12-21
ENN SCI & TECH DEV
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Problems solved by technology

[0002] In the coal catalytic gasification process, the outlet of the gasifier is usually equipped with at least two cyclone processors, which are used to recover and gasify the fly ash produced in the coal catalytic gasification reaction to improve the carbon conversion rate, and the first-stage cyclone processor The separated fly ash particles are larger and can be directly returned to the gasifier for secondary gasification, while the fly ash particles separated by the secondary cyclone processor are finer (usually less than or equal to 0.2mm), due to the In a high-pressure environment, it is difficult to return the secondary fly ash to the gasifier for secondary gasification, and the reactivity is poor, which often results in the ineffective circulation of the fly ash in the gasifier and is discharged to the outside of the gasifier; At the same time, there is a large amount of potassium catalyst in the fly ash that needs to be recovered. Due to the fine particles of the fly ash, high carbon content, and poor wettability with water, it is difficult to recover the catalyst in the fly ash. In this way, when the fly ash is directly The carbon conversion rate of coal catalytic gasification is low and the consequences of serious environmental pollution

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  • Secondary-cyclone flying ash treatment method

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Embodiment Construction

[0022] A method for treating fly ash provided by an embodiment of the present invention will be described in detail below with reference to the accompanying drawings.

[0023] An embodiment of the present invention provides a treatment method for two-rotation fly ash, comprising:

[0024] Step 1) In the presence of a decomposer and a gasification agent, the two-stage fly ash is used as a fuel to be processed through chemical looping combustion, and at the same time, the catalyst carried by the two-stage fly ash undergoes an ion exchange reaction with the digestion agent, Obtaining ash containing soluble catalyst;

[0025] Step 2) washing the ash containing the soluble catalyst with water, and recovering the soluble catalyst.

[0026] The basic principle of chemical loop combustion is to decompose the traditional combustion of direct contact reaction between fuel and air into two gas-solid reactions with the help of oxygen carrier. The oxygen in the air is transferred to the a...

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Abstract

The invention relates to the technical field of flying ash treatment, in particular to a secondary-cyclone flying ash treatment method. By the adoption of the secondary-cyclone flying ash treatment method, the carbon conversion rate of secondary-cyclone flying ash can be improved, catalysts carried by the secondary-cyclone flying ash can also be efficiently recycled, and the defects that in the prior art, because the secondary-cyclone flying ash is difficult to return to a gasification furnace for secondary combustion, the carbon conversion rate is lowered, and serious environmental pollution is caused are overcome. The secondary-cyclone flying ash treatment method comprises the steps that firstly, in the presence of a digestion agent and a gasification agent, the secondary-cyclone flying ash is used as fuel and treated through chemical looping combustion, and meanwhile, the catalysts carried by the secondary-cyclone flying ash perform an ion exchange reaction with the digestion agent, so that ash residues containing the soluble catalysts are obtained; and secondly, water processing is conducted on the ash residues containing the soluble catalysts, and then the soluble catalysts are recycled. The secondary-cyclone flying ash treatment method is used for treating the secondary-cyclone flying ash.

Description

technical field [0001] The invention relates to the technical field of fly ash treatment, in particular to a treatment method of two-rotation fly ash. Background technique [0002] In the coal catalytic gasification process, the outlet of the gasifier is usually equipped with at least two cyclone processors, which are used to recover and gasify the fly ash produced in the coal catalytic gasification reaction to improve the carbon conversion rate, and the first-stage cyclone processor The separated fly ash particles are larger and can be directly returned to the gasifier for secondary gasification, while the fly ash particles separated by the secondary cyclone processor are finer (usually less than or equal to 0.2mm), due to the In a high-pressure environment, it is difficult to return the secondary fly ash to the gasifier for secondary gasification, and the reactivity is poor, which often results in the ineffective circulation of the fly ash in the gasifier and is discharged...

Claims

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Application Information

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IPC IPC(8): B09B3/00B09B5/00C10J3/84
CPCY02P20/52B09B3/00B09B5/00C10J3/84C10J2300/1628
Inventor 王会芳贺丙飞刘雷李克忠
Owner ENN SCI & TECH DEV
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