Tantalum powder performance improving method, tantalum powder and tantalum capacitor anode block prepared from tantalum powder

A technology of tantalum powder and high performance, which is applied in the field of tantalum capacitor anode blocks, can solve the problems of tantalum powder with high bulk density, failure to meet product requirements, and large product weight deviation, so as to reduce friction damage rate, improve molding efficiency, and improve The effect of production efficiency

Active Publication Date: 2017-01-04
CHINA ZHENHUA GRP XINYUN ELECTRONICS COMP ANDDEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The commonly used binders for tantalum powder used in traditional tantalum capacitors are camphor, stearic acid, polyethylene glycol, etc. Among them, camphor is the most commonly used, but camphor is easy to volatilize and its performance is unstable, which makes the tantalum block processing process difficult. The peculiar smell is strong, and it is easy to pollute the environment; at the same time, the purity of camphor is low, because after mixing tantalum powder, a large amount of impurities are introduced, which reduces the electrical performance of tantalum capacitors, and after camphor and tantalum powder are mixed, the fluidity of tantalum powder is poor, forming The weight deviation of tantalum block is large, and the consistency of tantalum block production is poor
Stearic acid has a good lubricating effect, and after being mixed with tantalum powder, its fluidity is better. For this reason, in the prior art, some researchers use stearic acid and tantalum powder for mixed treatment, such as the patent No. 201310493371.3 "Improve Tantalum Capacitor Manufacturing Method of Porosity of Anode Block ", in its step (2) mixing powder, respectively weigh polyvinyl alcohol powder type pore opening agent and lubricant with 0.1% to 1% of tantalum powder weight, and add tantalum powder; but, in When the specific volume of tantalum powder is low, the tantalum powder will be treated with stearic acid mixed with tantalum powder, which will lead to a large bulk density of tantalum powder, many faults during pressing and molding, and low production efficiency
Polyethylene glycol has adhesive properties. In the prior art, some researchers use it as a binder for tantalum powder, such as the patent No. 201310493333.8 "Manufacturing method of tantalum capacitor to improve fluidity of tantalum powder during preparation" In the powder mixing step of step (2), put the tantalum powder into the polyethylene glycol solution, stir evenly with a stainless steel rod, add deionized water, and stir for 10 to 15 minutes to allow the tantalum powder to disperse evenly in the solution, so that the tantalum powder The outer layer of the powder particles can form a uniform adhesive layer; however, the fluidity after the powder mixing treatment is poor, and the consistency of the pressed molded product is poor
[0004] In summary, camphor as an additive in the process of improving tantalum powder cannot meet the requirements of the product, and in the prior art, stearic acid and polyethylene glycol are used in the process of improving tantalum powder. After treatment, the modified tantalum powder still has many disadvantages, so that when the tantalum powder is used to prepare the anode block of tantalum capacitor, it still faces low production efficiency, short service life of the mold, and the weight of the same batch of products. big deviation etc.

Method used

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  • Tantalum powder performance improving method, tantalum powder and tantalum capacitor anode block prepared from tantalum powder
  • Tantalum powder performance improving method, tantalum powder and tantalum capacitor anode block prepared from tantalum powder

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] The specific volume of the tantalum powder used is 50000μF·V / g.

[0015] Weigh 500g of tantalum powder, 15g of stearic acid, and 10g of polyethylene glycol; measure 200mL of absolute ethanol;

[0016] Mix the weighed stearic acid, polyethylene glycol and measured absolute ethanol in a beaker, heat to 60°C, keep the temperature for 10 minutes, stir and dissolve, and after the polyethylene glycol and stearic acid are completely dissolved, the modified Sexual fluid;

[0017] Add the modified liquid to the tantalum powder, mix, heat to 60°C, mix at a constant temperature for 3 hours, and naturally cool to room temperature to obtain the modified tantalum powder;

[0018] Detect the fluidity and bulk density of modified tantalum powder;

[0019] Put the modified tantalum powder in the molding die, press molding, the molding weight is 45mg / a tantalum block, and the pressing density is 5.2g / cm 3 ;Randomly select 10 molded products, weigh them, and calculate the relative erro...

Embodiment 2

[0030] The specific volume of tantalum powder is 8000μF·V / g.

[0031] Weigh 1000g of tantalum powder, 20g of stearic acid, 10g of polyethylene glycol; measure 150mL of absolute ethanol;

[0032] Mix the weighed stearic acid, polyethylene glycol and measured absolute ethanol in a beaker, heat to 50°C, keep the temperature for 15 minutes, stir and dissolve, and after the polyethylene glycol and stearic acid are completely dissolved, the modified Sexual fluid;

[0033] Add the modified liquid to the tantalum powder, mix, heat to 50°C, mix at a constant temperature for 4 hours, and naturally cool to room temperature to obtain the modified tantalum powder;

[0034] Detect the fluidity and bulk density of modified tantalum powder;

[0035] Put the modified tantalum powder in the molding die, press molding, the molding weight is 95mg / a tantalum block, and the pressing density is 5.2g / cm 3 ;Randomly select 10 molded products, weigh them, and calculate the relative error, and count ...

Embodiment 3

[0047] The specific volume of the tantalum powder used is 3500μF·V / g.

[0048] Weigh 2000g of tantalum powder, 20g of stearic acid, 10g of polyethylene glycol; measure 90mL of absolute ethanol;

[0049] Mix the weighed stearic acid, polyethylene glycol and measured absolute ethanol in a beaker, heat to 70°C, keep the temperature for 10 minutes, stir and dissolve, and after the polyethylene glycol and stearic acid are completely dissolved, the improved Sexual fluid;

[0050] Add the modified liquid to the tantalum powder, mix, heat to 70°C, mix at a constant temperature for 2 hours, and naturally cool to room temperature to obtain modified tantalum powder;

[0051] Detect the fluidity and bulk density of modified tantalum powder;

[0052] Put the modified tantalum powder in the molding die, press molding, the molding weight is 150mg / a tantalum block, and the pressing density is 5.2g / cm 3 ;Randomly select 10 molded products, weigh them, and calculate the relative error, and c...

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Abstract

The invention relates to the technical field of tantalum capacitors, in particular to a tantalum powder performance improving method, tantalum powder and a tantalum capacitor anode block prepared from the tantalum powder. Stearic acid, polyethylene glycol and solvent are mixed and prepared into a modified solution, and then the consumption of the prepared mixture is limited, so after the tantalum powder is added, flowability of the tantalum powder can be effectively improved, a prepared tantalum block is good in consistency, forming efficiency of the tantalum block is improved, the friction damage rate of the tantalum block and a mould is reduced, the yield of the tantalum block is increased, production efficiency is improved, and no bad atmosphere volatizes.

Description

technical field [0001] The invention relates to the technical field of tantalum capacitors, in particular to a method for improving the performance of tantalum powder, the tantalum powder and a tantalum capacitor anode block prepared from the tantalum powder. Background technique [0002] The production of the anode tantalum block of tantalum capacitor mainly adopts the compression molding process. During the compression molding process, a certain proportion of binder needs to be added to improve the fluidity of the tantalum powder, and the mold cavity can be uniformly filled during compression molding. , to reduce the powder weight deviation between the formed tantalum blocks; at the same time, it can also improve the lubrication of the tantalum powder, reduce the friction between the forming mold and the tantalum powder, prolong the service life of the mold, and reduce the scratches on the surface of the tantalum block; After the tantalum block is formed, the adhesive can ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F1/00H01G9/042
CPCH01G9/042B22F1/145
Inventor 刘一峰王俊刘华蔡大俊胡鹏钟山王鹏飞
Owner CHINA ZHENHUA GRP XINYUN ELECTRONICS COMP ANDDEV CO LTD
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