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Phenol-benzaldehyde multifunctional epoxy resin modified by polyphenylene ether and its application

A technology of epoxy resin and epoxy resin, applied in epoxy resin coatings, coatings, fireproof coatings, etc., can solve the problems of insufficient heat resistance, low Tg, etc.

Active Publication Date: 2020-10-27
NANYA PLASTICS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the patent JP2009029923, it is mentioned that comparative example I is 60gPPE and 40g bisphenol F epoxy resin (BPF epoxy) to synthesize a prepolymerization solution (i.e. 100 parts of PPE and 66 parts of BPF epxy) under the catalyst, and comparative example II is 70gPPE and 30g Bisphenol A epoxy resin (BPAepoxy) is synthesized pre-polymerization solution (that is, 100 parts of PPE and 42.8 parts of BPAepxy) under the catalyst, and the polyphenylene ether resin structure and proportioning of above-mentioned patent CN 102516530 epoxy group modification are equivalent, comparative example The characteristics of hot-pressed fiberglass laminates show insufficient heat resistance and low Tg

Method used

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  • Phenol-benzaldehyde multifunctional epoxy resin modified by polyphenylene ether and its application
  • Phenol-benzaldehyde multifunctional epoxy resin modified by polyphenylene ether and its application
  • Phenol-benzaldehyde multifunctional epoxy resin modified by polyphenylene ether and its application

Examples

Experimental program
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Effect test

Embodiment 0-1

[0039] Example 0-1: Synthesis of polyphenylene ether PPE (Ι) with suitable number average molecular weight Mn 1500-6000:

[0040] With 100 parts of polyphenylene ether PPE (Asahi 5202A) with number average molecular weight Mn=13500, add 150 parts of solvent toluene, adjust the solid content to 40%, and then add 30 parts of restructuring agent bisphenol A (BPA), add in 4 times 30 parts of peroxybenzoic acid (BPO) 7.5 parts each time, carry out cracking and recombination reaction at 80 ° C for 2 hours, then add 370 parts of solvent toluene, configure a polyphenylene ether PPE resin solution with a solid content of 20%, add 100 parts of water, wash with water Set the liquid to separate for 30 minutes, remove the water layer, wash with water once again in the same procedure, and finally filter the aqueous resin solution to obtain a polyphenylene ether PPE (I) resin solution with a number average molecular weight Mn=3791, with a yield of 98%.

Embodiment 0-2

[0042] With 500 parts of step (1) polyphenylene ether PPE (Ι) resin solution, convert 100 parts of solid polyphenylene ether PPE, add 400 parts of phenol-benzaldehyde multifunctional epoxy resin (Nanya Plastics Company product name NPPN-433), and add Catalyst triphenylphosphine (TPP) 0.5 part is 0.1%, is heated up to 170 ℃, carries out addition reaction 2 hours, obtains the polyphenylene ether modified phenol-benzaldehyde multifunctional epoxy resin solution, yield 100%, The obtained polyphenylene ether PPE modified phenol-benzaldehyde multifunctional epoxy resin I (20% PPE) had a number average molecular weight of Mn=997, a weight average molecular weight of Mw of 3851, and an epoxy equivalent of 309.5 g / eq.

Embodiment 0-3

[0044] Dissolve 100 parts of solid polyphenylene ether PPE (Sabic MX-90) in 150 parts of toluene, add 369 parts of phenol-benzaldehyde multifunctional epoxy resin (Nanya Plastics Company product name NPPN-433), and add catalyst triphenylphosphine (TPP) 0.5 part is 0.1%, is heated up to 170 ℃, carries out addition reaction 2 hours, obtains the polyphenylene ether modified phenol-benzaldehyde multifunctional epoxy resin solution, yield 100%, the obtained polyphenylene ether PPE Modified phenol-benzaldehyde multifunctional epoxy resin П (21.3% PPE) number average molecular weight Mn=1258, weight average molecular weight Mw5937, epoxy equivalent=343g / eq.

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Abstract

The invention relates to polyphenyl ether modified phenol-benzaldehyde multifunctional epoxy resin and application thereof. The polyphenyl ether modified phenol-benzaldehyde multifunctional epoxy resin has the formula (I) shown in the specification. A preparation method of the polyphenyl ether modified phenol-benzaldehyde multifunctional epoxy resin includes the following steps that 100 parts of polyphenyl ether resin is dissolved in a solvent, 100-450 parts of phenol-benzaldehyde multifunctional epoxy resin and 0.01-5 parts of catalyst are added, a stirring reaction is carried out for 1-4 hours at the temperature of 90-180 DEG C, a solvent is added for adjusting solid type parts, and the polyphenyl ether modified phenol-benzaldehyde multifunctional epoxy resin solution is obtained. The resin is added into a glass fiber laminated plate formula composition, excellent electrical performance and heat resistance are achieved, the dielectric constant Dk is 4.03 (1GHz), the loss factor Df is 0.0046 (1GHz), and after water absorption is carried out for 2 hr through a pressure cooker PCT (pressure cooking test), tin dip-soldering heat resistance is carried out for 60 min or above at the temperature of 288 DEG C without plate blasting. The polyphenyl ether modified phenol-benzaldehyde multifunctional epoxy resin can be applied to insulating materials of electronic assemblies with high reliability requirements such as copper clad laminated plates and EMC packaging.

Description

technical field [0001] The invention relates to a polyphenylene ether-modified phenol-benzaldehyde multifunctional epoxy resin. The epoxy resin composition is applied to glass fiber laminated boards and exhibits low dielectric constant (Dk), low dissipation factor (Df) and Excellent heat resistance, suitable for signal transmission of high-frequency printed circuit boards. Background technique [0002] Based on polyphenylene ether resin (PPO or PPE), which has excellent characteristics in low dielectric constant and low dissipation factor (Low Dk / Df), it has been widely used in the industry, but when it is applied to produce glass fiber laminates due to PPE The impregnation with glass fiber cloth is not good, and if it is mixed with epoxy resin, it will have poor compatibility, which will cause phase separation between PPE and epoxy resin, which will affect the appearance and dielectric properties of the prepreg. [0003] The patent US6512075 proposes a phenol-benzaldehyde ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G81/00C08G59/14C09D187/00C09D163/00C09D5/18C09D7/61
Inventor 李政中黄永通吴振华余昭宪
Owner NANYA PLASTICS CORP
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