A kind of preparation technology for the catalyst of high temperature catalytic decomposition of N2O

A preparation process and high-temperature catalysis technology, which is applied in the fields of physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, nitrous oxide capture, etc. Problems such as component loss, to achieve the effect of uniform appearance, small resistance, and not easy to lose

Active Publication Date: 2018-10-30
四川蜀泰化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the catalyst active component of the invention adopts the impregnation method, and the active component is mainly loaded on the outer surface of the carrier, which easily leads to the aggregation of the active component on the outer surface of the catalyst carrier; Large, the active components loaded on the surface of the carrier are aggregated and loaded, the load stability is poor, and it is easy to be washed by the air flow and cause the loss of active components, resulting in rapid decay of catalyst activity and short service life.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A high-temperature catalytic decomposition of N 2 The preparation technology of the catalyst of O is characterized in that, described production technology comprises the steps:

[0030] (1) be that 10 parts of zirconium nitrate, 75 parts of cerium nitrate, 4 parts of cobalt nitrate, 0.5 part of lanthanum nitrate, 0.1 part of nickel nitrate and 0.1 part of magnesium nitrate are dissolved in deionized water to form nitrate Mixed solution, the dissolution temperature is 60°C; the concentration of the nitrate mixed solution is 200g / L; then dropwise add ammonia water with a mass percentage concentration of 15% in the nitrate mixed solution until the pH of the mixed solution is 7.0; After completion, the mixed solution was heated up to 70°C, kept at 70°C and stirred for 2 hours, then added aluminum hydroxide and stirred evenly, then pressed and dehydrated to obtain a precipitate with a water content of 40% by mass;

[0031] (2) Dry the precipitate with a water mass percentag...

Embodiment 2

[0034] A high-temperature catalytic decomposition of N 2 The preparation technology of the catalyst of O is characterized in that, described production technology comprises the steps:

[0035] (1) 15 parts of zirconium nitrate, 85 parts of cerium nitrate, 10 parts of cobalt nitrate, 2 parts of lanthanum nitrate, 1 part of nickel nitrate and 0.5 part of magnesium nitrate are dissolved in deionized water to form nitrate Mixed solution, the dissolution temperature is 100°C; the concentration of the nitrate mixed solution is 220g / L; then dropwise add ammonia water with a mass percentage concentration of 20% in the nitrate mixed solution until the pH of the mixed solution is 10.0; After completion, the mixed solution was heated up to 90°C, kept at 90°C and stirred for 5 minutes, then added aluminum hydroxide and stirred evenly, then pressed and dehydrated to obtain a precipitate with a water content of 60% by mass;

[0036] (2) Dry the precipitate with a water mass percentage of 6...

Embodiment 3

[0039] A high-temperature catalytic decomposition of N 2 The preparation technology of the catalyst of O is characterized in that, described production technology comprises the steps:

[0040] (1) 80 parts of cerium nitrate, 12.5 parts of zirconium nitrate, 7 parts of cobalt nitrate, 1.25 parts of lanthanum nitrate, 0.5 part of nickel nitrate and 0.3 part of magnesium nitrate are dissolved in deionized water to form nitrate For the mixed solution, the dissolution temperature is 80°C; the concentration of the mixed nitrate solution is 210g / L; then, dropwise add ammonia water with a concentration of 17.5% by mass in the mixed solution until the pH of the mixed solution is 8.0; After completion, the mixed solution was heated up to 80°C, kept at 80°C and stirred for 3.5 hours, then added aluminum hydroxide and stirred evenly, then pressed and dehydrated to obtain a precipitate with a water content of 50% by mass;

[0041] (2) Dry the precipitate obtained in step (1) with a water ...

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PUM

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Abstract

The invention discloses a preparation technology of a catalyst used for high temperature catalytic decomposition of N2O. The preparation technology comprises the following steps: dissolving magnesium nitrate, cobalt nitrate, lanthanum nitrate, cerium nitrate, nickel nitrate and zirconium nitrate in water to form a mixed nitrate solution; adding ammonia water and aluminum hydroxide, and carrying out compacting, dehydrating, drying and baking to obtain a powder material; and uniformly rolling the powder material, desalinized water and a bonding agent, drying the rolled materials to obtain a granulation material, compacting the granulation material to form a porous cylinder, and calcining the porous cylinder to obtain the catalyst. The preparation technology has the following advantages: a co-precipitation method is selected, an active component reacts with a carrier substance precursor and a precipitating agent to realize co-precipitation, and the active component interacts with the carrier, so the active component is well and stably dispersed; and the active component and the carrier precipitate are commonly calcined at a high temperature of 1000-1300 DEG C, so the active component of the catalyst has good heat tolerance and difficulty loses, thereby the catalyst has the advantages of high efficiency, good stability and long service life.

Description

technical field [0001] The invention relates to the technical field of industrial catalysis, and more specifically relates to a catalyst for high-temperature catalytic decomposition of N 2 O catalyst preparation process. Background technique [0002] Due to the growth of world population, the rapid development of cities and the continuous increase of energy consumption per capita, the natural environment in which human beings live has been severely impacted, the environmental quality has declined, and the subsequent harm to human health and the destruction of ecosystems It has become a common concern of people, and environmental protection and sustainable development have become one of the most urgent tasks for contemporary people. [0003] The major greenhouse gases currently in the atmosphere include CO 2 ,CH 4 ,N 2 O, HFCs, PFCs and SF 6 . Among them, N 2 O not only produces the greenhouse effect, but also is a serious air pollutant. N 2 O is a trace gas whose co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/83B01J35/02B01D53/86B01D53/56
CPCY02C20/10
Inventor 李华波许云波严会成李文静
Owner 四川蜀泰化工科技有限公司
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