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Polyethylene composition and antistatic film

A technology of polyethylene and composition, applied in the field of polyethylene composition and antistatic film, can solve the problems of poor film forming property, easy film rupture and the like

Active Publication Date: 2017-04-05
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the poor film-forming properties and easy rupture of the film when the existing polyethylene raw material is prepared by the flat film stretching method to prepare the polyethylene antistatic film, that is, it is not suitable for the preparation of the antistatic film by the flat film stretching method. defects, and provide a new polyethylene composition and antistatic film made of the polyethylene composition

Method used

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  • Polyethylene composition and antistatic film
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Examples

Experimental program
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Embodiment approach

[0032] According to a preferred embodiment of the present invention, the polyethylene composition is figure 1 Prepared in the shown multi-reactor parallel device, described multi-reactor parallel device comprises first reactor 1, second reactor 2, third reactor 3, solid / liquid (gas) separator 4, homogenizer The silo 5 and the melt granulation system 6, wherein the first reactor 1, the second reactor 2 and the third reactor 3 are connected in parallel, and the number of the solid / liquid (gas) separator 4 is three One, communicated with the first reactor 1, the second reactor 2 and the third reactor 3 respectively, the component A prepared by the first reactor 1, the component B prepared by the second reactor 2 and the component B prepared by the third reactor The component C prepared by the reactor 3 is separately phase-separated in different solid / liquid (gas) separators 4, and then the phase-separated component A, component B and component C are sent to the homogenizer in pro...

Embodiment 1

[0048] This example is used to illustrate the polyethylene composition and antistatic film provided by the present invention.

[0049] The polyethylene composition provided in this embodiment contains component A, component B, component C, conductive filler and lubricant. Component A, component B and component C are all linear low density polyethylene (LLDPE) of ethylene / alpha olefin copolymerization, and all adopt identical catalyst system (metallocene catalyst system is the support prepared by CN102453124A embodiment 1 type metallocene catalyst, the same below). The properties of component A, component B, component C, conductive filler and lubricant are as follows:

[0050] Melt index MI of component A A =1.5g / 10min, density ρ A =0.913g / cm 3 , molecular weight distribution index M w / M n =3.4, the molar content of α-olefin comonomer=7.5mol%;

[0051] Melt index MI of component B B =2.1g / 10min, density ρ B =0.913g / cm 3 , molecular weight distribution index M w / M ...

Embodiment 2

[0061] This example is used to illustrate the polyethylene composition and antistatic film provided by the present invention.

[0062]The polyethylene composition provided in this embodiment contains component A, component B, component C, conductive filler and lubricant. Component A, component B and component C are all ethylene / α-olefin copolymerized linear low-density polyethylene (LLDPE), and are all prepared by using the same metallocene catalyst system. The properties of component A, component B, component C, conductive filler and lubricant are as follows:

[0063] Melt index MI of component A A =0.01g / 10min, density ρ A =0.930g / cm 3 , molecular weight distribution index M w / M n =3.0, the molar content of α-olefin comonomer=1.6mol%;

[0064] Melt index MI of component B B =10.0g / 10min, density ρ B =0.930g / cm 3 , molecular weight distribution index M w / M n =2.8, the molar content of α-olefin comonomer=1.9mol%;

[0065] Melt index MI of component C C =60g / 10mi...

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Abstract

The invention provides a polyethylene composition and an antistatic film. The polyethylene composition contains a conductive filling material, a component A, a component B and a component C; the component A is ethane / alpha alkene copolymerized linear low density polyethylene, the fusion index MIA is 0.01-2 g / 10 min under temperature of 190 DEG C and loading of 2.16 kg, density RhoA is 0.880-0.936 g / cm<3>; the component B is ethane / alpha alkene copolymerized linear low density polyethylene, the fusion index MIB is 2.1-14.9 g / 10 min under temperature of 190 DEG C and loading of 2.16 kg, density RhoB is 0.910-0.930 g / cm<3>; the component C is ethane / alpha alkene copolymerized linear low density polyethylene, the fusion index MIC is 15-150 g / 10 min under temperature of 190 DEG C and loading of 2.16 kg, and density RhoC is 0.880-0.930 g / cm<3>. The polyethylene composition employs a flat membrane stretching method for preparing a polyethylene film, the stretching ratio is large, film forming rate is high, and the obtained film has good antistatic property.

Description

technical field [0001] The present invention relates to a polyethylene composition and an antistatic film. Background technique [0002] Biaxially Oriented Polyethylene (BOPE) film is a film material formed by a polyethylene (PE) resin with a special molecular structure through a biaxial stretching process. Compared with the polyethylene film produced by the existing extrusion blow molding process and extrusion casting process, BOPE film has greatly improved physical properties, and has high mechanical strength, good puncture resistance and impact resistance, and excellent optical properties. , good heat sealing and moisture resistance, energy saving and environmental protection, etc., especially when the thickness is reduced by 50%, the key performance can still reach the performance of other polyethylene films. Therefore, BOPE film can be widely used in packaging bags, heavy packaging bags, vacuum heat-sealing films, low-temperature packaging films, composite films, medic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L71/02C08K7/24C08K3/04C08K3/22C08J5/18B29D7/01
CPCB29D7/01C08J5/18C08J2323/08C08J2423/08C08K2201/001C08K2201/011C08L23/0815C08L2201/04C08L2203/16C08L2205/025C08L2205/035C08L71/02C08K7/24C08K3/04C08K2003/2241
Inventor 权慧张师军高达利徐萌初立秋李杰邹浩吕芸
Owner CHINA PETROLEUM & CHEM CORP
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