Photosensitive composition and cured film thereof
A technology of photosensitive composition and polymeric compound, applied in optics, optomechanical equipment, photosensitive materials for optomechanical equipment, etc.
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[0164] Hereinafter, although this invention is demonstrated in detail based on an Example, this invention is not limited to an Example.
Synthetic example 1
[0165] Synthesis Example 1: Synthesis of Silane Compound B-1
[0166] In a reaction vessel equipped with a stirring device, a reflux condenser, a dropping funnel, and a thermometer, 100 parts by mass of isocyanatopropyltriethoxysilane (KBM9007, manufactured by Shin-Etsu Chemical Co., Ltd.) and 108 parts by mass of ureidopropyltrimethoxysilane (T1915, manufactured by Tokyo Chemical Industry Co., Ltd.) was added dropwise to a mixed solution of 485 parts by mass of N-methylpyrrolidone (NMP). Then, the temperature of the mixed liquid was raised to 65° C., and the reaction was carried out for 2 days while maintaining the temperature. At the end of the reaction, the disappearance of the isocyanate group peak was confirmed by IR.
[0167] The solid content concentration of the obtained solution was 30.0% by mass.
[0168] Through the above reaction, compound B-1 represented by the following formula was obtained. figure 1 It is an IR spectrum for confirming the completion of the re...
Synthetic example 2
[0170] Synthesis Example 2: Synthesis of Silane Compound B-2
[0171] In a reaction vessel equipped with a stirring device, a reflux condenser, a dropping funnel, and a thermometer, 100 parts by mass of isocyanatopropyltriethoxysilane (KBM9007, manufactured by Shin-Etsu Chemical Co., Ltd.) and 44 parts by mass of trimethylsilanol (LS-310, manufactured by Shin-Etsu Chemical Co., Ltd.) was added dropwise to a mixed solution of 336 parts by mass of N-methylpyrrolidone (NMP). Then, the temperature of the mixed solution was raised to 65° C., and the mixture was reacted for 2 hours while maintaining the temperature. The completion of the reaction is to confirm the disappearance of the isocyanate group peak by IR.
[0172] The solid content concentration of the obtained solution was 30% by mass.
[0173] Through the above reaction, compound B-2 represented by the following formula was obtained.
[0174]
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