Photocurable inkjet ink, cured film, electronic circuit board, and manufacturing method thereof
A technology of inkjet ink and photohardening, which is applied in the direction of copying/marking method, ink, printing, etc., and can solve the needs and other problems
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[0238] 6. Preparation method of ink
[0239] The ink of the present invention can be prepared by mixing each component used as a raw material by a known method.
[0240] In particular, the ink of the present invention is preferably prepared by mixing the above-mentioned component (A) and the polymerization initiator (C), and optionally the monomer (B) and / or other components, and then using, for example, fluorine The obtained solution was filtered and degassed by a resin-made membrane filter. The ink prepared in the above-described manner is excellent in ejectability by an ink jet apparatus.
[0241] The viscosity of the ink of the present invention at 25° C. measured by an E-type viscometer is preferably 200 mPa·s or less, more preferably 1 mPa·s to 200 mPa·s, still more preferably 2 mPa·s to 150 mPa·s, and particularly Preferably, it is 3 mPa·s to 100 mPa·s. When the viscosity of the ink of this invention is in the said range, the ejection characteristic by an inkjet appa...
example
[0276] Hereinafter, the present invention will be described more specifically based on examples, but the present invention is not limited to these examples.
example 1
[0278]
[0279] As the monomer (a-1), 3.0 g of dicyclopentyl acrylate, namely Fancryl FA-513AS (trade name; Hitachi Chemical Co., Ltd., also referred to as "FA-513AS" hereinafter), was used as the monomer (a- 2) 3.0 g of cyclohexyl methacrylate i.e. Light EsterCH (trade name; Kyeisha Chemical Co., Ltd., hereinafter also referred to as "CH-MA"), tricyclodecane dimethanol as monomer (B) 2.5 g of diacrylate, IRR214-K (trade name; Daicel-Cytec (stock)), and 2-(4-methylbenzyl)-2- as a polymerization initiator (C) (Dimethylamino)-1-(4-morpholinophenyl)butan-1-one, i.e., IRGACURE379 (trade name; BASF Japan Co., Ltd.) 1.2 g was mixed to obtain a solution, and the pore diameter was used. The filtrate (inkjet ink 1) was obtained by filtering with a 0.2 μm ultra-high molecular weight polyethylene (hydrophobic) membrane filter (Nihon Entegris Co., Ltd.).
[0280] Using an E-type viscometer (Toki Sangyo Co., Ltd. TV-22 (trade name), the same applies hereinafter), the viscosity of the in...
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