Aluminum passivation solution and preparation method thereof
A technology of aluminum passivation and sodium fluoride, applied in the direction of metal material coating process, etc., can solve the problems of insufficient adhesion, large porosity of passivation film, fast passivation speed, etc., to achieve low porosity, passivation The effect of moderate time and moderate film forming speed
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Embodiment 1-10
[0050] Examples 1-10 respectively provide the composition of the aluminum passivation solution of the present invention, specifically as listed in Table 1, wherein the unit of the ingredients is g / L.
[0051] Table 1 embodiment 1-10 formula composition
[0052] Example 1 2 3 4 5 6 7 8 9 10 Zinc chromate 3 3 3.5 3.5 4 4 4.5 4.5 5 5 cobalt sulfate 0.5 1 0.8 0.6 0.7 0.9 0.6 1 0.7 0.8 Zirconium Sulfate 2 3 2.8 2.2 2.5 3 2.9 2.1 2 2.7 sodium fluoride 0.8 1.5 0.6 0.9 1.4 1.5 0.5 0.7 1 1.3 sulfuric acid 3 4 2 2.5 3.5 3 4 2 3 4 citric acid 2 2 1 2 2 1 1 2 2 2 water margin margin margin margin margin margin margin margin margin margin
[0053] The preparation method of the passivation solution of the above examples 1-10 is as follows: add 600ml deionized water in a 2000ml beaker, add sulfuric acid and stir well, add zinc chromate, cobalt sulfate, zirc...
Embodiment 15
[0068] Take 100ml of the aluminum passivation solution of Example 7, add water to dilute to 50 times the volume, that is, 5000ml, and mix well to make a passivation working solution (bath solution). The passivation time is 5 minutes. After passivation, the test piece is rinsed with deionized water, and then dried with hot air at 60°C. Observe that the passivation status of each test piece is better, and the color is consistent. Take the 10th, 30th, 50th, 70th, and 100th piece respectively for neutral salt spray corrosion test to measure the porosity of the passivation film layer, passivation film and spray The adhesion of the plastic coating can reach the passivation effect listed in Table 3.
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