Electrode for lithium secondary battery comprising hygroscopic materials and lithium secondary battery comprising the same
A lithium secondary battery, hygroscopic technology, applied in the field of lithium secondary battery electrodes and lithium secondary batteries containing it, can solve the problems of electrode moisture removal, etc., achieve the effect of eliminating side reactions and improving battery performance
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Embodiment 1
[0080] Example 1: Production of Negative Electrode for Lithium Secondary Battery Containing Hygroscopic Substance
[0081] As the negative electrode active material, the average particle size is 25 μm of 86% by weight of graphite, 1% by weight of acetylene black (Denka black) (conductive agent), 2% by weight of SBR (bonding agent) and 1% by weight of CMC (enhancement agent). Thickener) was mixed with NMP as a solvent to prepare negative electrode slurry. The negative electrode active material slurry prepared above was coated on one side of a copper (Cu) thin film as a 10 μm negative electrode current collector with a thickness of 65 μm to form an active material layer, and it was dried, and then the hygroscopic material The average particle size (D 50 ) of 0.5 μm silica gel was mixed with NMP in an amount of 1 / 10 parts by weight of the graphite to prepare a mixed solution, and the mixed solution was slowly permeated into the active material layer for 30 minutes. After infi...
Embodiment 2 to Embodiment 5
[0083] A negative electrode was produced in the same manner as in Example 1 above, except that the particle size of the silica gel was changed to the particle size shown in Table 1 below.
Embodiment 6 to Embodiment 10
[0085] In addition to using hygroscopic substances of different sizes and / or types as shown in Table 1 below instead of the above-mentioned average particle diameter (D 50 ) was 0.5 μm of silica gel, a negative electrode was produced in the same manner as in Example 1 above.
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