Lithium iron phosphate preparing method
一种磷酸亚铁锂、酸液的技术,应用在锂离子电池领域,能够解决无记忆效应、环境危害等问题,达到良好技术效果、容易脱附、净化效率高的效果
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Embodiment 1
[0035] A preparation method for lithium iron phosphate, comprising the steps of:
[0036] Step (1), select raw materials for preparing lithium ferrous phosphate and prepare lithium ferrous phosphate products by high-temperature solid-state reaction method; the raw materials described in step (1) are iron source, phosphorus source, lithium source, specifically iron source, phosphorus source Source, lithium source are ferrous oxalate, ammonium dihydrogen phosphate, lithium carbonate respectively; Described high-temperature solid phase reaction method is: according to iron source: phosphorus source: lithium source=1:1:1 Molar ratio mixing grinding; After grinding and drying, transfer the material to a pre-calcining furnace for calcination at 600°C under a nitrogen atmosphere. The sintering time is 1 hour. After the first sintering, the material is ball-milled, and then the second sintering is carried out. The temperature of the second sintering is 650°C. The sintering time is 1 h...
Embodiment 2
[0046] A preparation method for lithium iron phosphate, comprising the steps of:
[0047] Step (1), select raw materials for preparing lithium iron phosphate and prepare lithium iron phosphate product by high-temperature solid-state reaction method. The raw materials described in the step (1) are iron source, phosphorus source, and lithium source, and the specific iron source, phosphorus source, and lithium source are respectively ferrous oxalate, ammonium dihydrogen phosphate, and lithium carbonate. The high-temperature solid-phase reaction method is: mixing and grinding according to the molar ratio of iron source: phosphorus source: lithium source = 1:1:1. After grinding and drying, the material is transferred to a pre-calcining furnace for calcination under a nitrogen atmosphere at 700°C. The sintering time is 5 hours. After the first sintering, the material is ball-milled, and then the second sintering is carried out. The temperature of the second sintering is 750°C. The ...
Embodiment 3
[0056] A preparation method for lithium iron phosphate, comprising the steps of:
[0057] Step (1), select raw materials for preparing lithium iron phosphate and prepare lithium iron phosphate product by high-temperature solid-state reaction method. In step (1), the iron source, phosphorus source, lithium source and carbon source are weighed, and the specific iron source, phosphorus source, lithium source and carbon source are respectively ferrous oxalate, ammonium dihydrogen phosphate, lithium carbonate and glucose. The added amount is iron: phosphorus: lithium = 1:1:1 (molar ratio), and the molar ratio of glucose to lithium source is 0.2:1. The high-temperature solid-phase reaction method is: mixing and grinding the raw materials according to the molar ratio. After grinding and drying, transfer the material to a pre-calcining furnace for calcination at 600°C under a nitrogen atmosphere. The sintering time is 1 hour. After the first sintering, the material is ball-milled, an...
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