Biodegradable polymer
A biodegradable, polymer-based technology used in the construction of medical devices such as sutures to address physician error and inappropriate use of closure materials due to patient physiology
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[0320] Synthesis of polymers according to the invention
[0321] Generally, the synthesis of the polymers of the invention proceeds by first synthesizing the ABA tri-block or the AB di-block. In this general reaction, a pre-prepared poly(propylene oxide) B block (which can be purchased or synthesized from an initial diol and an excess of the appropriate epoxide, depending on the desired block length) is preferably combined with hydroxyl Acids or their cyclic lactones are reacted to produce low molecular weight ABA tri-blocks or AB di-blocks. Basically, poly(propylene oxide) generally terminated with a hydroxyl group or, in the case of an AB di-block, at one end with a hydroxyl group and at the other end with a non-reactive group The blocks are reacted with hydroxyacids or their cyclic lactones to produce ABA triblocks or AB diblocks comprising polypropylene and biodegradable components terminated with hydroxyl groups or other groups.
[0322] After the ABA triblock or AB d...
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