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3D printed conductive compositions anticipating or indicating structural compromise

A 3D printing and composite technology, applied to the conductive layer on the insulating carrier, the conductive coating, the equipment used to manufacture the conductive/semiconductive layer, etc., can solve the problem of low conductivity and achieve the effect of increasing the conductivity

Active Publication Date: 2017-10-20
XEROX CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

While these materials have been explored extensively in academia and industry, the focus has generally been on minimizing the amount of conductive additives needed to form a permeable network, where the conductivity is relatively low

Method used

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  • 3D printed conductive compositions anticipating or indicating structural compromise
  • 3D printed conductive compositions anticipating or indicating structural compromise
  • 3D printed conductive compositions anticipating or indicating structural compromise

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0066] By extruding a polymer substrate (polycaprolactone; "PCL") with 10% by weight of multi-walled carbon nanotubes (MWNT) together with 30% by weight of silver (Ag) flakes on a Haake twin-screw extruder Conductive composite segments were prepared by melt mixing at 30 rpm for 30 minutes. The resulting material was cryogenically ground and the ground compound was extruded into filaments using a melt flow indexer (MFI) and a modified die. Extrusion conditions on the MFI included a 1.8 mm hole and a 16.96 kg weight in order to produce the final filament. The final filament has a diameter of about 1.75mm.

example 2

[0068] A 10 cm cross-section of the extruded filament of Example 1 with the tip coated with silver paint was used to measure electrical resistance in order to calculate bulk conductivity. Resistance measurements are done using a digital multimeter. The bulk conductivity was calculated using Equation 1 above.

example 3

[0070] A composite similar to that of Example 1 was prepared, but using 30% by weight of Ag nanoparticles instead of Ag flakes.

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Abstract

An article includes a body and at least one 3D-printable conductive composite segment in mechanical communication with the body. The body includes a first material and the at least one conductive composite segment includes a matrix material, a plurality of carbon nanotubes, and conductive additives. The conductive additives include a plurality of metallic particulates, a plurality of graphitic particles or a combination thereof.

Description

technical field [0001] The present disclosure relates to smart articles comprising conductive compositions that can be used to indicate structural damage or potential structural damage. Background technique [0002] Additive manufacturing (also known as three-dimensional printing) as practiced in industry has so far mainly involved printing structural features. There is a need for materials and processes that integrate functional properties, such as electronic features, into additive manufacturing. Recently, polymer composite compositions of potentially useful conductive materials in additive manufacturing have been commercialized, but their conductivities are generally low, in the range of ~10 -3 S / cm to ~2.0 S / cm or more. Commercially available materials, especially conductive materials such as acrylonitrile butadiene styrene (ABS) or polylactic acid (PLA) generally have limited mechanical properties (e.g., are not flexible and / or are rather brittle), which Use as a fun...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B5/14H01B1/22H01B1/24H01B13/00G01N27/02
CPCG01N27/02H01B1/22H01B1/24H01B5/14H01B13/00H01B13/0026B33Y70/10B82Y30/00G01N27/20B29C64/106G01L1/2206B28B1/001B33Y10/00B33Y80/00B29K2105/167B29K2105/162B29K2507/04B29K2505/00B29K2995/0005C09D5/24G01R1/00
Inventor C·摩尔拉格R·普莱斯塔伊可B·乔莎克瑞恩S·J·维拉
Owner XEROX CORP
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