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Soil insensitive polycarboxylic acid water reducer and preparation method thereof

A technology of polycarboxylate and water reducer, applied in the preparation of non-soil-sensitive polycarboxylate water-reducer, non-soil-sensitive polycarboxylate water-reducer, concrete admixture, polycarboxylate water-reducer In the field of preparation, it can solve the problems of soil sensitivity of sand and gravel raw materials, and achieve the effect of solving soil sensitivity, short production cycle and coordinating reactivity rate

Inactive Publication Date: 2017-11-07
SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a non-soil-sensitive polycarboxylate water reducer, which is not sensitive to the mud content of sand and gravel materials in concrete, and can be used in concrete with high mud content to have higher Water-reducing ability and small slump loss to solve the problem of sensitivity to sand and gravel raw materials in the application of traditional polycarboxylate water-reducing agents in concrete applications

Method used

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  • Soil insensitive polycarboxylic acid water reducer and preparation method thereof
  • Soil insensitive polycarboxylic acid water reducer and preparation method thereof

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Embodiment 1

[0016] Embodiment 1: The non-soil-sensitive polycarboxylate water reducer of the present invention is based on 4-hydroxybutyl vinyl ether macromonomer, unsaturated carboxylic acid, unsaturated sulfonate, unsaturated ester small monomer Comonomer, made by copolymerization reaction with initiator and chain transfer agent as molecular regulator, the mass ratio of each component is: 4-hydroxybutyl vinyl ether: unsaturated carboxylic acid: unsaturated sulfonate Acid acid: unsaturated ester small monomer: initiator: chain transfer agent: deionized water=72:4:6:16:1:1.5:80.

[0017] The preparation method of the non-soil-sensitive polycarboxylate water reducer includes the following process steps: add 72 parts of 4-hydroxybutyl vinyl ether with a molecular weight of 2400 and 40 parts of deionized water to 500ml according to the above mass ratio In a three-necked flask, heat and start the stirrer to heat up, and at the same time, 1 part of initiator, i.e. ammonium persulfate and 1.5 p...

Embodiment 2

[0018] Embodiment 2: The non-soil-sensitive polycarboxylate water reducer of the present invention is based on 4-hydroxybutyl vinyl ether macromonomer, unsaturated carboxylic acid, unsaturated sulfonate, unsaturated ester small monomer Comonomer, made by copolymerization reaction with initiator and chain transfer agent as molecular regulator, the mass ratio of each component is: 4-hydroxybutyl vinyl ether: unsaturated carboxylic acid: unsaturated sulfonate Acid acid: unsaturated ester small monomer: initiator: chain transfer agent: deionized water=120:4.5:8:20:1.5:2:95.

[0019]The preparation method of the non-soil-sensitive polycarboxylate water reducer includes the following process steps: add 120 parts of 4-hydroxybutyl vinyl ether with a molecular weight of 4000 and 60 parts of deionized water into 500ml In a three-necked flask, heat and start the stirrer to heat up, and at the same time, 1.5 parts of initiator, namely ammonium persulfate, and 2 parts of chain transfer ag...

Embodiment 3

[0020] Embodiment 3: The non-soil-sensitive polycarboxylate water reducer of the present invention is based on 4-hydroxybutyl vinyl ether macromonomer, unsaturated carboxylic acid, unsaturated sulfonate, unsaturated ester small monomer Comonomer, made by copolymerization reaction with initiator and chain transfer agent as molecular regulator, the mass ratio of each component is: 4-hydroxybutyl vinyl ether: unsaturated carboxylic acid: unsaturated sulfonate Acid acid: unsaturated ester small monomer: initiator: chain transfer agent: deionized water=72:4:8:12:1.5:0.5:80.

[0021] The preparation method of the non-soil-sensitive polycarboxylate water reducer includes the following process steps: add 72 parts of 4-hydroxybutyl vinyl ether with a molecular weight of 2400 and 40 parts of deionized water to 500ml according to the above mass ratio In a three-necked flask, heat and start the stirrer to raise the temperature, and at the same time, dissolve 0.1 part of initiator, namely ...

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Abstract

The invention relates to a soil insensitive polycarboxylic acid water reducer and a preparation method of the reducer. The water reducer is prepared by taking a 4-hydroxybutyl vinyl ether macromonomer, unsaturated carboxylic acid, unsaturated sulfonate and an unsaturated ester micromonomer as a comonomer, and an initiator and a chain transfer agent as a molecular regulator for copolymerization reaction. A mass ratio of the 4-hydroxybutyl vinyl ether macromonomer to unsaturated carboxylic acid to unsaturated sulfonate to the unsaturated ester micromonomer to the initiator to the chain transfer agent to deionized water is (24-120):(4-8):(6-8):(10-20):(0.8-1.5):(0.4-2):(70-120). The invention further provides the preparation method of the water reducer. The water reducer is insensitive to a sand content of a sandstone material in concrete; when the water reducer is used for the concrete with the high sand content, the water reducer has higher water reducing capability and smaller slump loss than the traditional polycarboxylic acid water reducer; and the water reducer solves the problem that the traditional polycarboxylic acid water reducer is sensitive to soil, a raw material of sandstone, in the concrete application.

Description

technical field [0001] The invention relates to a concrete admixture, in particular to a water reducer insensitive to the mud content of sand and gravel materials in concrete, in particular to a non-soil sensitive polycarboxylate water reducer, which belongs to the technical field of building materials . The invention also relates to a preparation method of a polycarboxylate water reducer, in particular to a preparation method of a non-soil sensitive polycarboxylate water reducer. Background technique [0002] As a green and environmentally friendly concrete chemical admixture, polycarboxylate superplasticizer has been widely used in the industry because of its excellent functions. In many concrete projects, traditional high-efficiency concrete such as naphthalene series is increasingly unable to meet engineering needs due to limitations in technical performance. Polycarboxylate-based high-performance water-reducing agent, based on the mechanism of dispersing cement to des...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F220/06C08F212/14C08F220/28C08F222/02C08F228/02C04B24/16C04B103/30
CPCC04B24/165C08F283/065C04B2103/302C08F220/281C08F212/14
Inventor 汪咏梅李茜茜叶子吴伟刘昭洋董树强王龙飞刘江涛余京烩刘翠芬
Owner SHIJIAZHUANG CHANGAN YUCAI BUILDING MATERIALS
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