L-aspartic acid chelated calcium and preparation method thereof
A technology of aspartic acid and chelated calcium, which is applied in the field of calcium agents, can solve the problems of incomplete reaction, long time, and low yield, and achieve the effects of saving production costs, short reaction time, and high yield
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[0022] The invention provides a kind of preparation method of L-aspartic acid chelated calcium, comprises the steps:
[0023] S1: Add calcium hydroxide and L-aspartic acid into water, and then homogeneously disperse; wherein, the molar ratio of calcium hydroxide and L-aspartic acid is 1: (1.5~2.5), calcium hydroxide and L - The ratio of the total mass of aspartic acid to the mass of water is 25:(70-80).
[0024] S2: adjust the pH value of the product obtained in S1 to 7.3-7.5, and then decolorize and filter to obtain a solution with a solid particle size of less than 30 μm;
[0025] S3: put the solution into the reaction kettle, and react at 95-105°C and 105-115MPa for 50-70min;
[0026] S4: Concentrate the product obtained in S3 to obtain a concentrated solution; reduce the pressure and temperature of the concentrated solution to obtain L-aspartic acid chelated calcium crystals; wherein, in the concentrated solution, the mass fraction of water is 10% to 15%; The pressure afte...
Embodiment 1
[0032] The present embodiment provides a kind of preparation method of L-aspartic acid chelated calcium, comprises the steps:
[0033] S1: Add calcium hydroxide and L-aspartic acid to water, and then homogeneously disperse; wherein, the molar ratio of calcium hydroxide and L-aspartic acid is 1:2, calcium hydroxide and L-aspartic acid The ratio of the total mass of acid to the mass of water is 25:75.
[0034] S2: adjust the pH value of the product obtained in S1 to 7.4, and then decolorize and filter to obtain a solution with a solid particle size of less than 30 μm;
[0035] S3: put the solution into the reactor, and react at 100°C and 110MPa for 60min;
[0036] S4: Concentrate the product obtained in S3 to obtain a concentrated solution; reduce the pressure and temperature of the concentrated solution to obtain L-aspartic acid chelated calcium crystals; wherein, in the concentrated solution, the mass fraction of water is 12%; The pressure is 50MPa, and the temperature after...
Embodiment 2
[0041] The present embodiment provides a kind of preparation method of L-aspartic acid chelated calcium, comprises the steps:
[0042] S1: Add calcium hydroxide and L-aspartic acid into water, and then homogeneously disperse; wherein, the molar ratio of calcium hydroxide and L-aspartic acid is 1:1.5, calcium hydroxide and L-aspartic acid The ratio of the total mass of acid to the mass of water is 25:70.
[0043] S2: adjust the pH value of the product obtained in S1 to 7.3, and then decolorize and filter to obtain a solution with a solid particle size of less than 30 μm;
[0044] S3: Put the solution into the reactor, and react at 95°C and 105MPa for 50min;
[0045] S4: Concentrate the product obtained in S3 to obtain a concentrated solution; reduce the pressure and temperature of the concentrated solution to obtain L-aspartic acid chelated calcium crystals; wherein, in the concentrated solution, the mass fraction of water is 10%; The pressure is 45MPa, and the temperature af...
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