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A kind of superalloy casting and preparation method thereof

A high-temperature alloy and casting technology, which is applied in casting molding equipment, metal processing equipment, casting molds, etc., can solve the problems of destroying the stability of the high-temperature long-term aging structure of the alloy, deteriorating the creep and durability of the alloy, and achieving excellent high-temperature resistance. The effects of corrosion performance, good structural stability, and good high-temperature durability

Active Publication Date: 2019-11-22
AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to improve the temperature bearing capacity and high-temperature creep durability of the alloy, the content of refractory elements such as rhenium, tungsten, molybdenum, and tantalum in the alloy is continuously increasing. However, increasing the content of refractory elements can improve the temperature bearing capacity of the alloy and increase the creep durability At the same time, it is easy to promote the precipitation of harmful phases such as brittle TCP during service, thereby destroying the stability of the high-temperature long-term aging structure of the alloy and deteriorating the creep durability of the alloy.

Method used

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  • A kind of superalloy casting and preparation method thereof
  • A kind of superalloy casting and preparation method thereof
  • A kind of superalloy casting and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-11

[0028] The chemical composition of embodiment 1-11 alloy

[0029] The mass percent of the chemical composition of the alloy is: Cr 3.5-7.5%, Mo 1.0-4.0%, W 4.5-8.5%, Re 0-4.0%, Ta 4.0-8.0%, Al 4.0-7.0%, Co 6.8-9.2 %, Ti 0 to 2.0%, C 0 to 0.05%, B 0 to 0.04%, Hf 0 to 0.4%, Nb 0 to 1%, Ni as the balance; the chemical composition of Cr, Mo, W, B and Hf in the alloy The composition is controlled as follows: 1.0≤Cr to Mo mass percentage ratio≤7.5, W 4.5~8.5%; wherein, when 1.0≤Cr to Mo mass percentage ratio≤2.0, W 4.5~6.0%, 0.25%≤B+Hf ≤0.44%; when 2.0<Cr to Mo mass percentage ratio≤4.0, W 6.0~7.0%, 0<B+Hf<0.25%; when 4.0<Cr to Mo mass percentage ratio≤7.5, W 7.0~ 8.5%, 0.25%<B+Hf≤0.44%. Table 2 shows the mass percentages of the chemical components of alloy examples 1-11 of the present invention.

[0030] Table 2 The mass percent of the chemical composition of alloy examples 1 to 11 of the present invention

[0031]

[0032]

Embodiment 1

[0034] The heat-resistant corrosion-resistant long-life superalloy involved in this embodiment uses the master alloy ingot with the chemical composition of Example 1 in Table 2 to cast directionally solidified single crystal gas turbine blades with a length of more than 300 mm.

[0035] The double vacuum induction method is used for smelting, according to the required chemical composition according to the ratio of ingredients, put into the vacuum induction melting furnace for smelting, the smelting process includes five steps of melting, refining, cooling, alloying and pouring; in the melting step, the nickel , chromium, molybdenum, tungsten, rhenium, tantalum, cobalt, and niobium are loaded into the crucible, and refined for 38-42 minutes after being melted, and the alloy liquid melt is stirred after refining, and then the power is turned off to cool down until the alloy liquid conjunctiva; power on again, add aluminum and Stir the alloy liquid melt after smelting for 18-20 mi...

Embodiment 2

[0037] The heat-resistant corrosion-resistant long-life superalloy involved in this embodiment adopts the master alloy ingot of the chemical composition in Example 2 in Table 2 to cast a hollow directionally solidified single crystal gas turbine blade with a length of more than 300 mm and a minimum wall thickness of 0.5 mm. .

[0038] The double vacuum induction method is used for smelting, according to the required chemical composition according to the ratio of ingredients, put into the vacuum induction melting furnace for smelting, the smelting process includes five steps of melting, refining, cooling, alloying and pouring; in the melting step, the nickel , chromium, molybdenum, tungsten, rhenium, tantalum, cobalt, and carbon are loaded into the crucible, and refined for more than 38 to 42 minutes after refining. After refining, the alloy liquid melt is stirred, and then the power is turned off to cool down until the alloy liquid conjunctiva; After smelting with titanium for...

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Abstract

The invention belongs to the field of high-temperature alloy metal materials and relates to a high-temperature alloy casting for a hot-end part of a gas turbine engine and a preparation method of thehigh-temperature alloy casting. The alloy is prepared from the following chemical components in percentage by mass: 3.5 percent to 7.5 percent of Cr, 1.0 percent to 4.0 percent of Mo, 4.5 percent to 8.5 percent of W, 0 percent to 4.0 percent of Re, 4.0 percent to 8.0 percent of Ta, 4.0 percent to 7.0 percent of Al, 6.8 percent to 9.2 percent of Co, 0 percent to 2.0 percent of Ti, 0 percent to 0.05percent of C, 0 percent to 0.04 percent of B, 0 percent to 0.4 percent of Hf, 0 percent to 1 percent of Nb and the balance of Ni. By controlling the mass percent ratio of the Cr and the Mo and regulating the ratio of a W element and (B and Hf) elements, the high-temperature lasting service life, the high-temperature gas heat corrosion resisting performance, the casting technology performance andthe tolerance of small-angle crystal boundary defects are improved. The alloy provided by the invention is suitable for manufacturing a worm wheel working blade and a guide blade of the gas turbine engine.

Description

technical field [0001] The invention belongs to the field of high-temperature alloy metal materials, and relates to a high-temperature alloy casting used for gas turbine hot-end components and a preparation method thereof, in particular to a heat-resistant corrosion-resistant long-life superalloy used for manufacturing gas turbine turbine working blades and guide blades . Background technique [0002] With the development of natural gas resources in my country and the increasing demand for energy conservation, environmental protection, and sustainable economic and social development, gas turbines, which have the advantages of small size, high efficiency, low pollution, and wide power range, compared with traditional power plants such as diesel engines and steam turbines, are being used. Widely used in industrial power generation, ship power, oil and natural gas transmission and other fields. [0003] With the increase of gas turbine thermal efficiency, output power and turbi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C19/05C22C1/02C22F1/10C22C1/03B22C9/04B22C9/22
Inventor 陈晶阳肖程波李青张明军杨海青胡聘聘
Owner AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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