A kind of quaternary ammonium salt type sodium hydroxypropyl phosphate quick-cracking asphalt emulsifier and its preparation method
A technology of hydroxypropyl phosphate and asphalt emulsifier, which is applied in chemical instruments and methods, phosphorus organic compounds, organic chemistry, etc., can solve the problems of high requirements for production and experimental equipment, high cost of emulsifier raw materials, high temperature reaction, etc., and achieve Various performance indicators are excellent, good aggregate adhesion and storage stability, and the effect of cheap raw materials
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[0049] For above asphalt emulsifier, the present invention also provides its preparation method, comprises the following steps:
[0050] (1) Dissolve sodium dihydrogen phosphate in water, heat to a certain temperature, then gradually add epichlorohydrin, and mix and react to obtain reaction intermediate I, which is 3-chloro-2-hydroxypropyl phosphate sodium
[0051]
[0052] (2) Mix octadecyl dimethyl tertiary amine and alcohol solvent, then add reaction intermediate I, mix and react, promptly obtain quaternary ammonium salt type hydroxypropyl phosphate sodium fast-cracking asphalt emulsifier;
[0053] Or, include the following steps:
[0054](1) Dissolve trisodium phosphate in water, heat to a certain temperature, then gradually add epichlorohydrin, mix and react to obtain reaction intermediate II, and reaction intermediate II is sodium glycidyl phosphate
[0055]
[0056] (2) Mix octadecyl dimethyl tertiary amine and alcohol solvent, then add the reaction intermediate...
Embodiment 1
[0078] (1) Preparation of quaternary ammonium salt type sodium hydroxypropyl phosphate quick-cracking asphalt emulsifier:
[0079] 1) Add 245.7g sodium dihydrogen phosphate (NaH 2 PO 4 2H 2 O) and 483g of water, stirred and dissolved, heated to 85°C. Then 97.1 g of epichlorohydrin was added dropwise, and stirred at 85° C. for 7.5 h to obtain an aqueous solution of 3-chloro-2-hydroxypropyl phosphate sodium.
[0080] The above synthetic intermediate product was separated and purified by recrystallization and then detected by FTIR. The results are as follows: 3445cm -1 It is the stretching vibration absorption peak of O-H, 1635cm -1 C-O asymmetric stretching vibration absorption peak, 1297cm -1 It is the stretching vibration absorption peak of P=O, 1093cm -1 It is the stretching vibration absorption peak of P-O-R, 921cm -1 P-OH vibration absorption peak, 665cm -1 C-Cl bending vibration absorption peak, 538cm -1 It is the O-H out-of-plane bending vibration absorption peak...
Embodiment 2
[0091] (1) Preparation of quaternary ammonium salt type sodium hydroxypropyl phosphate quick-cracking asphalt emulsifier:
[0092] 1) Add 518.9g trisodium phosphate (Na 3 PO 4 12H 2 O) and 672g of water, stirred and dissolved, heated to 42°C. Then 97.1 g of epichlorohydrin was added dropwise, and stirred at 42° C. for 5 h to obtain an aqueous solution of sodium glycidyl phosphate.
[0093] The above-mentioned intermediate product synthesized was separated and purified by recrystallization and then detected by FTIR. The results are as follows: 3015cm -1 It is the absorption peak of epoxy group C-H stretching vibration, 1673cm -1 C-O asymmetric stretching vibration absorption peak, 1443cm -1 is the asymmetric bending vibration of methylene, 1360cm -1 It is the stretching vibration absorption peak of P=O, 1023cm -1 It is the stretching vibration absorption peak of P-O-R, 933cm -1 It is the vibration absorption peak of the epoxy group, 736cm -1 is the C-H out-of-plane ben...
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