Sodium chloride-containing pesticide production wastewater resource treatment system and method
A technology for production wastewater and resource treatment, which is applied in biological water/sewage treatment, water/sewage treatment, natural water treatment, etc. It can solve the problems of waste water not being recycled, low organic carbon content, and adverse environmental effects, and achieve the realization of Recycling, less solid waste generation, and the effect of reducing the dilution factor
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Embodiment 1
[0038] The water quality characteristics of the pesticide production wastewater that needs to be treated are: pH of wastewater is 8.4, conductivity 32ms / cm, CODcr 7730mg / L, Na 33000 mg / L, NH 4 + -N 500mg / L, Cl 53000mg / L, SO 4 2- 4000mg / L.
[0039] The MBR membrane used is a flat membrane with a membrane pore size of 0.1~0.2um; the membrane module roll membrane of the nanofiltration membrane device used has a membrane pore size of 0.001-0.0001um; the reverse osmosis membrane used is a cellulose acetate roll membrane module; The dialysis membrane is a heterogeneous membrane; the electrocatalytic oxidation plate is used, the cathode is a titanium plate, and the anode is a titanium-based chlorine analysis plate;
[0040] The specific operation steps are as follows:
[0041] 1) Biochemical water distribution: According to the TDS concentration in the wastewater is 7.6%, the TDS of the wastewater is adjusted to 2%~8%, and the biochemical treatment is carried out. The water inta...
Embodiment 2
[0052] The water quality characteristics of the pesticide production wastewater that needs to be treated are: pH of the wastewater is 2.2, conductivity 42ms / cm, CODcr 8340mg / L, Na + 39000 mg / L, NH 4 + -N 300mg / L, Cl - 55000mg / L, SO 4 2- 5000mg / L.
[0053] The MBR membrane used is a flat membrane with a membrane pore size of 0.1~0.2um; the membrane module roll membrane of the nanofiltration membrane device used has a membrane pore size of 0.001-0.0001um; the reverse osmosis membrane used is a cellulose acetate roll membrane module; The dialysis membrane is a heterogeneous membrane; the electrocatalytic oxidation plate is used, the cathode is a titanium plate, and the anode is a titanium-based chlorine analysis plate;
[0054] Concrete operation steps are identical with embodiment 1.
[0055] During operation, the biochemical water distribution device adjusts the TDS of wastewater to 1.5%; the water flow rate of the MBR device is 350L / m - 2 d -1 ;Nanofiltration membr...
Embodiment 3
[0059] The water quality characteristics of the pesticide production wastewater that needs to be treated are: the pH of the wastewater is 10.1, the conductivity is 53ms / cm, CODcr5840mg / L, Na + 25000 mg / L, NH 4 + -N 200mg / L, Cl - 23000mg / L, SO 4 2- 3000mg / L.
[0060] The MBR membrane used is a flat membrane with a membrane pore size of 0.1~0.2um; the membrane module roll membrane of the nanofiltration membrane device used has a membrane pore size of 0.001-0.0001um; the reverse osmosis membrane used is a cellulose acetate roll membrane module; The dialysis membrane is a heterogeneous membrane; the electrocatalytic oxidation plate is used, the cathode is a titanium plate, and the anode is a titanium-based chlorine analysis plate;
[0061] Concrete operation steps are identical with embodiment 1.
[0062] During operation, the TDS of the wastewater adjusted by the biochemical water distribution device is 2.5%; the outlet flow of the MBR device is 250L / m - 2 d -1 ;Nanof...
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