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Preparation method of a highly flexible metal nanowire transparent conductive composite film

A metal nanowire and composite film technology, which is applied in nanotechnology, nanotechnology, cable/conductor manufacturing, etc., can solve the problems of insufficient adhesion between the metal nanowire film and the modified layer, and the complicated preparation process of the flexible substrate. Low price, high flexibility, and the effect of reducing production costs

Active Publication Date: 2019-10-25
河北森斯环保科技有限公司
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Problems solved by technology

[0006] In view of the deficiencies in the technical background, the present invention proposes a method for preparing a highly flexible metal nanowire transparent conductive composite film, which solves the problems of complex preparation process of flexible substrates and insufficient adhesion between the metal nanowire film and the modification layer in the past

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  • Preparation method of a highly flexible metal nanowire transparent conductive composite film
  • Preparation method of a highly flexible metal nanowire transparent conductive composite film

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Embodiment Construction

[0024] The technical scheme of the present invention is how to provide a highly flexible metal nanowire transparent conductive composite film, the composite film structure from bottom to top is: mixed cellulose ester microporous filter membrane 1, metal nanowire film 2, polymethacrylic acid Methyl ester film 3, poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonic acid) film 4, in which the metal nanowire film 2 is located on the surface of the mixed cellulose ester microporous filter membrane 1. The methyl acrylate film 3 is located on the surface of the metal nanowire film 2, and the poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonic acid) film 4 is located on the surface of the polymethyl methacrylate film 3.

[0025] The following embodiments illustrate the technical solutions of the present invention and the beneficial effects that can be obtained in detail:

[0026] (1) Take 0.5ml of ethanol solution of silver nanowires with a concentration of 1mg / ml, dilute to 500ml wit...

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Abstract

The invention discloses a highly flexible metal nanowire transparent conductive composite film and a preparation method thereof, comprising a flexible substrate and a conductive layer, characterized in that the flexible substrate is a transparent mixed cellulose ester microporous filter membrane, and the The conductive layer includes a metal nanowire film, a polymethyl methacrylate film and a poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonic acid) film. The present invention uses a transparent mixed cellulose ester microporous filter membrane as a substrate, so that the substrate has high flexibility; by using metal nanowires as the main conductive layer, the problem of expensive transparent conductive films in traditional optoelectronic devices is solved; through The preparation process of directly suctioning and depositing metal nanowire films on flexible substrates can effectively reduce the production cost of transparent conductive films; by preparing polymethyl methacrylate films and poly(3,4 ‑ethylenedioxythiophene)‑poly(styrenesulfonic acid) film to enhance the optoelectronic performance of the composite film. The metal nanowire transparent conductive composite film can be widely used in healthy and environment-friendly flexible optoelectronic devices.

Description

Technical field [0001] The invention relates to the field of organic optoelectronics, in particular to a method for preparing a highly flexible metal nanowire transparent conductive composite film. Background technique [0002] Among transparent conductive films, indium tin oxide (ITO) films prepared by magnetron sputtering process are most commonly used. However, ITO thin films also have some obvious shortcomings: (1) Indium as raw material is scarce, and the price is becoming more expensive, so substitutes are urgently needed; (2) Sputtering is used to prepare ITO thin films, which requires high temperature, which limits the choice of device substrates; (3) ITO thin films Fragile and poor mechanical stability; (4) The work function of the ITO film is low, which cannot meet the higher requirements of the transparent conductive film made by the rapidly changing optoelectronic devices in different fields. Looking for new high-performance transparent conductive film is an importan...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B5/14H01B13/00H01L51/44H01L51/52H01L51/48H01L51/56B82Y30/00B82Y40/00
CPCH01B5/14H01B13/00B82Y30/00B82Y40/00H10K71/60H10K30/82H10K50/81Y02E10/549
Inventor 刘萍曾葆青王亚雄王悦辉王红航
Owner 河北森斯环保科技有限公司
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