Metal complex and organic light emitting device thereof
A technology of organic light-emitting devices and metal complexes, which is applied in the fields of light-emitting materials, organic chemistry, and electric solid-state devices, and can solve problems such as low luminous efficiency, poor thermal stability of phosphorescent materials, and short lifespan.
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Embodiment 1
[0060] Embodiment 1: the preparation of compound 1
[0061]
[0062] Preparation of 1-3
[0063] 1-1 (7.354g, 36.9mmol) was dissolved in THF (250ml) solution and cooled in an ice-water bath. Trifluoromethanesulfonic acid (3.58ml, 40.6mmol) was added and the resulting mixture was stirred cooled for 30min, then allowed to warm to room temperature and stirred overnight. Water, brine and saturated sodium carbonate were added to the mixture and the resulting mixture was extracted several times with EtOAc. The combined organics were separated and washed with brine, dried and reduced vacuum to form 15.8 g of an orange oil which solidified. The mixture was subjected to column chromatography to obtain 1-3 7.68 g, 85% yield.
[0064] Preparation of 1-4
[0065] 1-3 (5.57g, 22.80mmol) was dissolved in THF (150ml) solution in isopropanol / CO 2 Cool in a bath and add a solution of methyllithium in ether (1.6M, 57.0ml, 91mmol) via syringe. The reaction mixture was stirred and cooled...
Embodiment 2
[0071] Embodiment 2: the preparation of compound 8
[0072] 1-3 in Example 1 was replaced by equimolar 8-3, and the other steps were the same as in Example 1 to obtain the target compound 8.
[0073]
[0074] Mass Spectrum m / z: 897.18 (calculated: 897.19). Theoretical element content (%)C 45 h 52 IrN 8 : C, 60.24; H, 5.84; Ir, 21.42; N, 12.49 Measured element content (%): C, 60.25; H, 5.85; Ir, 21.43; N, 12.48. The above results confirmed that the obtained product was the target product.
Embodiment 3
[0075] Embodiment 3: the preparation of compound 23
[0076]1-3 in Example 1 was replaced by equimolar 23-3, and the other steps were the same as in Example 1 to obtain the target compound 23.
[0077]
[0078] Mass Spectrum m / z: 862.24 (calculated: 862.25). Theoretical element content (%)C 46 h 61 IrN 4 : C, 64.08; H, 7.13; Ir, 22.29; N, 6.50 The measured element content (%): C, 64.09; H, 7.12; Ir, 22.28; N, 6.51. The above results confirmed that the obtained product was the target product.
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