The invention provides a metal organic complex and an organic light-emitting device thereof. The metal organic complex has a structure which is as show in the formula (I), the structure comprises a primary ligand and an auxiliary ligand, wherein an electron-rich double-nitrogen coordination structure in the auxiliary ligand structure is beneficial to stabilizing central trivalent metal cations, meanwhile, the electron cloud distribution on metal can also be influenced, then the photoelectric property of a whole complex molecule is greatly influenced, in addition, a four-membered ring formed bythe ligands of the double-nitrogen coordination structure and the metal has stronger rigidity, unnecessary vibration energy loss can be conveniently reduced, and efficient light-emitting performancecan be achieved. The metal complex has better heat stability and chemical properties by adjusting substituent groups. The metal complex is prepared into the device and especially is served as a dopingmaterial, and the device has the advantages of being low in driving voltage, high in light-emitting efficiency and superior to an existing common OLED device.