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Halogen-free flame retarding type thermoplastic elastomer and preparation method thereof

A thermoplastic elastomer, flame retardant technology, applied in the field of thermoplastic elastomer, can solve the problems of affecting physical health and life safety, can not be used to manufacture flame retardant conveyor belts, mechanical properties decline, etc., to achieve excellent mechanical properties and weather resistance. , Reduce the dynamic vulcanization temperature and time, the effect of good flame retardant performance and mechanical properties

Active Publication Date: 2018-09-14
ANHUI ZHONGYI RUBBER BELTS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the flame-retardant thermoplastic elastomers used and produced in my country contain halogen and antimony. Either use halogen-containing subject materials, or add halogen- and antimony-containing flame retardants. Once ignited, a large amount of toxic and harmful gases will be produced. Affect people's health and life safety, pollute the environment and corrode mechanical equipment, causing serious secondary disasters
Some existing halogen-free flame-retardant thermoplastic elastomers, due to the addition of a large amount of inorganic flame retardants, greatly reduce the mechanical properties, and cannot be used to manufacture important products such as flame-retardant conveyor belts, cables, auto parts, and rail transit shock absorbers.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] This embodiment provides a halogen-free flame-retardant thermoplastic elastomer, which is made of the following raw materials in parts by weight:

[0027] 40 parts of EPDM, 20 parts of SEPS, 40 parts of PP, 3 parts of zinc oxide, 1 part of stearic acid, 1 part of sulfur, 4 parts of DCP, 1 part of TAIC, 0.5 parts of accelerator M, 0.5 parts of accelerator TMTD, antioxidant RD 0.5 parts, anti-aging agent BLE 0.5 parts, anti-scorch agent CTP 1 part, antioxidant 1010 2 parts, white carbon black 8 parts, conductive carbon black 10 parts, aramid pulp 8 parts, antistatic agent P 4 parts, silane Coupling agent Si69 0.5 parts, TOP 8 parts, Al(OH) 3 10 copies, APP 15 copies.

[0028] The preparation method of the halogen-free flame-retardant thermoplastic elastomer provided in this embodiment includes the following steps:

[0029] (1) Preparation of EPDM masterbatch

[0030] Add EPDM, conductive carbon black, zinc oxide, stearic acid, accelerator, anti-aging agent, and anti-s...

Embodiment 2

[0038] This embodiment provides a halogen-free flame-retardant thermoplastic elastomer, which is made of the following raw materials in parts by weight:

[0039] 50 parts of EPDM, 15 parts of SEPS, 35 parts of PP, 4 parts of zinc oxide, 1.5 parts of stearic acid, 1.2 parts of sulfur, 3 parts of DCP, 0.8 parts of TAIC, 1 part of accelerator CZ, 0.5 parts of accelerator TMTD, anti-aging agent 1 part of 2246-S, 0.5 parts of anti-aging agent 4010NA, 1 part of anti-scorch agent CTP, 1.5 parts of antioxidant 1010, 7 parts of white carbon black, 12 parts of conductive carbon black, 7 parts of aramid pulp, 3 parts of antistatic agent P parts, silane coupling agent si69 0.8 parts, TCP 12 parts, zinc borate 5 parts, MCA 10 parts.

[0040] The preparation method of this embodiment is the same as that of Example 1.

Embodiment 3

[0042] This embodiment provides a halogen-free flame-retardant thermoplastic elastomer, which is made of the following raw materials in parts by weight:

[0043]60 parts of EPDM, 10 parts of SEPS, 30 parts of PP, 5 parts of zinc oxide, 2 parts of stearic acid, 1.5 parts of sulfur, 2 parts of DCP, 0.5 parts of TAIC, 1 part of accelerator DM, 1 part of accelerator TMTD, anti-aging agent 1 part of RD, 1 part of anti-aging agent 4010NA, 1 part of anti-scorch agent CTP, 1 part of antioxidant 1010, 6 parts of white carbon black, 15 parts of conductive carbon black, 6 parts of aramid pulp, 2 parts of antistatic agent P, 1 part of silane coupling agent Si69, 10 parts of DPOP, Mg(OH) 2 10 parts, MPP 10 parts.

[0044] The preparation method of this embodiment is the same as that of Example 1.

[0045] The detection data of above-mentioned embodiment sees the following table:

[0046] .

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PUM

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Abstract

The invention discloses a halogen-free flame retarding type thermoplastic elastomer and a preparation method thereof. The halogen-free flame retarding type thermoplastic elastomer is prepared throughthe following steps: selecting an EPDM / PP / SEPS (Ethylene-Propylene-Diene Monomer / Polypropylene / Styrene-Ethylene-Propylene-Styrene) high molecular composite system, a conductive carbon black / white carbon black / aramid pulp reinforcing conductive system and a compound flame-retarding system without halogen and antimony as main components of the thermoplastic elastomer; dynamically vulcanizing for 2 to 3min under the conditions that the rotary speed of an internal mixer is 40rpm and the temperature is 160 to 165 DEG C through a technological process of preparing EPDM master batch, carrying out silane modification treatment on a flame retardant, carrying out high-speed mixing and pre-plasticizing, carrying out combined dynamic vulcanization of the internal mixer and an extruder and the like; then dynamically vulcanizing through the extruder; dynamically vulcanizing for 5 to 7min under the conditions that the rotary speed of a screw rod is 30 to 50rpm and the temperature is 165 to 180 DEG C.The product prepared by the preparation method has good physical and mechanical performance, safety performance and environment-friendly performance, and meets the performance requirements of coal mine rubber products, automobile rubber products and rail transit rubber products on the thermoplastic elastomer are met.

Description

technical field [0001] The invention relates to the technical field of thermoplastic elastomers, in particular to a halogen-free flame-retardant thermoplastic elastomer and a preparation method thereof. Background technique [0002] Flame-retardant thermoplastic elastomers are important materials for coal mine rubber products, automotive rubber products, home appliance rubber products, rail transit rubber products and cables, and have a great market demand. At present, most of the flame-retardant thermoplastic elastomers used and produced in my country contain halogen and antimony. Either use halogen-containing subject materials, or add halogen- and antimony-containing flame retardants. Once ignited, a large amount of toxic and harmful gases will be produced. It affects people's health and life safety, pollutes the environment and corrodes mechanical equipment, causing serious secondary disasters. Some existing halogen-free flame-retardant thermoplastic elastomers, due to th...

Claims

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Application Information

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IPC IPC(8): C08L23/16C08L23/12C08L53/02C08L77/10C08K13/06C08K9/06C08K3/36C08K5/521C08K5/14C08K5/09C08K3/04B29B7/00B29C35/02
CPCB29B7/005B29C35/02C08K2201/001C08L23/12C08L23/16C08L2201/02C08L2201/08C08L2201/22C08L2205/035C08L2205/16C08L53/025C08L77/10C08K13/06C08K9/06C08K3/36C08K5/521C08K5/14C08K5/09C08K3/04
Inventor 宋长江宋鑫魏雪梅袁陆海吕继明王从开李朝红周震宇汪健
Owner ANHUI ZHONGYI RUBBER BELTS
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