A kind of ceramic wood based on oxime end cap and manufacturing method
A manufacturing method, a technology of ceramics, applied in the manufacture of tools, wood heating, wood impregnation, etc., can solve the problems of hardness, anti-corrosion performance, anti-insect performance, waterproof performance, dimensional stability, etc.
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Embodiment 1
[0027] The manufacture method based on oxime end-blocking ceramic wood comprises the following steps:
[0028] (1) Prepare prepolymer, react 15% polyisocyanate and 8% polyester polyol.
[0029] (2) Add 15% aldoxime blocking agent to the prepolymer, and seal the NCO group with the aldoxime blocking agent to form a closed prepolymer, which will decompose carbon dioxide, olefins and primary amines in this step; Amines block free or dissociated NCO groups.
[0030] (3) Add 1% olefin polymerization catalyst, 16% amino acid and 45% water to the blocked prepolymer to form an impregnation solution.
[0031] (3) Immerse the wood in the impregnating liquid, and the impregnating liquid enters the wood under the pressure of 1-10 MPa for 12-24 hours.
[0032] (4) Take out the impregnated wood, then put it into the heating kettle, and heat the impregnated wood for 10-20 hours at a heating temperature of 100-120°C. The NCO group is unblocked, and at the same time, the hydroxyl group in th...
Embodiment 2
[0036] The manufacture method based on oxime end-blocking ceramic wood comprises the following steps:
[0037] (1) Prepare prepolymer, react 10% polyisocyanate and 12% polyester polyol.
[0038] (2) Add 10% aldoxime blocking agent to the prepolymer, and seal the NCO group with the aldoxime blocking agent to form a closed prepolymer, which will decompose carbon dioxide, olefins and primary amines in this step; Amines block free or dissociated NCO groups.
[0039] (3) Add 2% olefin polymerization catalyst, 25% amino acid and 41% water to the blocked prepolymer to form an impregnation solution.
[0040] (3) Immerse the wood in the impregnating liquid, and the impregnating liquid enters the wood under the pressure of 1-10 MPa for 12-24 hours.
[0041] (4) Take out the impregnated wood, then put it into the heating kettle, and heat the impregnated wood for 10-20 hours at a heating temperature of 100-120°C. The NCO group is unblocked, and at the same time, the hydroxyl group in t...
Embodiment 3
[0045] The manufacture method based on oxime end-blocking ceramic wood comprises the following steps:
[0046] (1) To prepare a prepolymer, 11% of polyisocyanate and 9% of polyester polyol were reacted.
[0047] (2) Add 11% aldoxime blocking agent in the prepolymer, seal the NCO group with the aldoxime blocking agent to form a closed prepolymer, and in this step, carbon dioxide, olefins and primary amines will be decomposed; Amines block free or dissociated NCO groups.
[0048] (3) Add 1.5% olefin polymerization catalyst, 17.5% amino acid and 50% water to the blocked prepolymer to form an impregnation solution.
[0049] (3) Immerse the wood in the impregnating liquid, and the impregnating liquid enters the wood under the pressure of 1-10 MPa for 12-24 hours.
[0050] (4) Take out the impregnated wood, then put it into the heating kettle, and heat the impregnated wood for 10-20 hours at a heating temperature of 100-120°C. The NCO group is unblocked, and at the same time, the h...
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