A new n-benzylacridone type alkaloid and its preparation method and application
A benzylacridone type, alkaloid technology, applied in the field of medicine, can solve the problems such as no research reports on fungus, achieves the effects of facilitating pharmacological and clinical research, the preparation method is simple and feasible, and the structure is novel
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Embodiment 1
[0028] Example 1 Preparation of N-benzylacridone-type alkaloids
[0029] Step (1), take the dried fungus (9 kg) and place it in 95% ethanol, immerse the medicinal material for 2-4 cm, and soak it at room temperature for 18 hours; then heat under reflux for 3 hours, stand for filtration, and concentrate the obtained filtrate to alcohol-free taste, to obtain the total thick paste of fungus and vegetables (850 grams);
[0030] Step (2), according to the volume ratio of 1:1.5, uniformly suspend the total thick paste of the fungus in the 1.3% HCl solution, let stand for 22 hours, and filter the supernatant;
[0031] Step (3), adjust pH=11 of the supernatant with ammonia water, extract with chloroform, ethyl acetate and n-butanol successively, and concentrate and dry each extract to obtain chloroform thick paste (36.8 g), ethyl acetate thick paste (258.5 g) g), n-butanol thick paste (364.0 g); the above-mentioned thick paste was screened for lipid-lowering activity by DiI-LDL cell ...
Embodiment 2
[0041]The hypolipidemic activity of Example 2 Compound I
[0042] experimental method
[0043] (1) Preparation of DiI-LDL
[0044] DiI (Beijing Zhongsheng Ruitai Technology Co., Ltd.) was dissolved in DMSO to prepare a 15 mg / mL DiI mother solution. The DiI stock solution was added to the LDL / LPDS (V / V=1:2) mixture so that the final concentration of DiI was 300 μg / mg LDL. Water bath at 37°C for 18h. The density of the mixture was adjusted to 1.063 g / mL with sodium bromide and ultracentrifuged for 24 h. In the uppermost layer of the gradient is labeled LDL, which is separated from free DiI. The upper layer of DiI-LDL was collected, dialyzed for 24 h and then transferred to PBS buffer (3 L) for 24 h. The dialyzed DiI-LDL was filtered and sterilized with a 0.22 μm filter, and its protein content was measured before use.
[0045] (2) Labeling HepG2 cells with DiI-LDL
[0046] HepG2 cells (Shanghai Jining Industrial Co., Ltd.) were seeded on a 24-well plate, cultured in DMEM ...
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