Composite material used for blow moulding and having environmental stress cracking resistance and preparation method thereof

An environmental stress cracking and composite material technology, applied in the field of composite materials for blow molding, can solve the problems of inability to meet impact strength, toughness and stability, active medium deformation, short service life, etc., and improve the environmental stress cracking resistance performance. , the effect of promoting the degradation rate and reducing the input cost

Inactive Publication Date: 2019-01-15
JRB PACKING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, plastic products can be seen everywhere, whether they are widely used in industry, agriculture or packaging fields, but the existing plastic products are usually made of low-density polyethylene resin as the main raw material, combined with other additives after melting It is made by kneading. It is prone to deformation or even cracking when it is subjected to external force or contacting some active media during actual use. The service life is short. The problem

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach

[0015] This example is the first embodiment of a blow molding composite material with environmental stress crack resistance and the preparation method of the composite material of the present invention. First, the blow molding composite material with environmental stress crack resistance, Its raw materials include by weight: 50 parts of linear low density polyethylene, 30 parts of high density polyethylene, 8 parts of ultraviolet absorber, 1 part of antioxidant 1010, 10 parts of ethylene-vinyl acetate copolymer, styrene-butadiene - 4 parts of styrene block copolymer, 2 parts of chlorinated polyethylene, 1 part of barium zinc stabilizer, 4 parts of acetyl tributyl citrate, 4 parts of fiber reinforced filler, 2 parts of silane coupling agent, 3 parts of degradation agent , 2 parts of reinforcing agent, 3 parts of adhesive.

[0016] Wherein, the fiber-reinforced filler is a blend formed by mixing glass fibers, nano-boron fibers, and cotton fibers in a mass ratio of 1:3:3.

[001...

Embodiment 2

[0025] This embodiment is the second embodiment of a blow molding composite material with environmental stress crack resistance and the preparation method of the composite material of the present invention. First, the blow molding composite material with environmental stress crack resistance, Its raw materials include by weight: 70 parts of linear low density polyethylene, 45 parts of high density polyethylene, 12 parts of ultraviolet absorber, 10102 parts of antioxidant, 20 parts of ethylene-vinyl acetate copolymer, styrene-ethylene-butylene - 5 parts of styrene block copolymer, 3.5 parts of chlorinated polyethylene, 3 parts of barium zinc stabilizer, 10 parts of acetyl tributyl citrate, 8 parts of fiber reinforced filler, 4 parts of silane coupling agent, 7 parts of degradation agent , 4 parts of reinforcing agent, 5 parts of adhesive.

[0026] Wherein, the fiber-reinforced filler is a blend formed by mixing glass fibers, nano-boron fibers, and cotton fibers in a mass ratio ...

Embodiment 3

[0035] This example is the third embodiment of a blow molding composite material with environmental stress crack resistance and the preparation method of the composite material of the present invention. First, the blow molding composite material with environmental stress crack resistance, Its raw materials include by weight: 60 parts of linear low density polyethylene, 40 parts of high density polyethylene, 10 parts of ultraviolet absorber, 10101.5 parts of antioxidant, 15 parts of ethylene-vinyl acetate copolymer, styrene-butadiene- 4.5 parts of styrene block copolymer, 3 parts of chlorinated polyethylene, 2 parts of barium zinc stabilizer, 7 parts of acetyl tributyl citrate, 6 parts of fiber reinforced filler, 3 parts of silane coupling agent, 5 parts of degradation agent, 3 parts of reinforcing agent, 4 parts of adhesive.

[0036] Wherein, the fiber-reinforced filler is a blend formed by mixing glass fibers, nano-boron fibers, and cotton fibers in a mass ratio of 1:3:3.

...

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PUM

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Abstract

The invention discloses a composite material used for blow moulding and having environmental stress cracking resistance and a preparation method thereof. The composite material includes the raw materials in parts by weight: 50-70 parts of linear low density polyethylene, 30-45 parts of high density polyethylene, 8-12 parts of an ultraviolet absorbent, 1-2 parts of an antioxidant, 10-20 parts of anethylene-vinyl acetate copolymer, 4-5 parts of a thermoplastic elastomer, 2-3.5 parts of chlorinated polyethylene, 1-3 parts of a barium-zinc stabilizer, 4-10 parts of a plasticizer, 4-8 parts of a fiber reinforced filler, 2-4 parts of a silane coupling agent, 3-7 parts of a degradant, 2-4 parts of a reinforcing agent, and 3-5 parts of an adhesive. The method includes the steps: adding all the components into a high-speed mixer, stirring and then transferring into a low-speed mixer, stirring and cooling down, then transferring into a twin-screw extruder, carrying out melt blending extrusion,carrying out mold shaping and carrying out pressure-holding cooling, and then demoulding to take the product. The composite material has excellent environmental stress cracking resistance, toughness,fire resistance and chemicals resistance on the basis of meeting the hardness required for use, and has the advantages of low investment cost, safety and environmental protection.

Description

technical field [0001] The invention relates to a composite material for blow molding with resistance to environmental stress cracking and a preparation method of the composite material. Background technique [0002] Environmental stress cracking refers to the cracking of plastic resin under the synergistic effect of environmental factors and stress factors. When the molded plastic product is under stress, it will be very easy to contact with some active media (such as detergent, acid, alkali or organic solvent). Brittle cracks appear and eventually cause the plastic product to break. In the prior art, plastic products can be seen everywhere, whether they are widely used in industry, agriculture or packaging fields, but the existing plastic products are usually made of low-density polyethylene resin as the main raw material, combined with other additives after melting It is made by kneading. It is prone to deformation or even cracking when it is subjected to external force ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/06C08L23/28C08L1/02C08L53/02C08K13/04C08K7/14C08K7/06C08K5/11
CPCC08K2201/011C08L23/0815C08L2205/035C08L2205/16C08L2207/04C08L2207/062C08L23/06C08L23/0853C08L23/286C08L1/02C08L53/02C08K13/04C08K7/14C08K7/06C08K5/11C08L53/025
Inventor 李清太彭国权殷湘
Owner JRB PACKING CO LTD
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