Preparation method of special chlorinated paraffin for surface treatment of fabric

A chlorinated paraffin and surface treatment technology, which is applied in the field of preparation of chlorinated paraffin for fabric surface treatment, can solve the problems of inability to achieve good flame retardant effect, difficult fabric quality improvement, poor flame retardant effect, etc., and achieve good flame retardant Effects of protection, improvement of softness, and cost reduction

Active Publication Date: 2019-01-18
ANHUI XINGXIN CHEM TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Chlorinated paraffins are used in paints, chlorinated rubber and styrene-butadiene resin coatings. In plastics, they are used as flame retardants, binders, cementing agents and fillers, and can also be used as lubricating additives. They also have Moisture resistance and chemical resistance, it can also be used in surface treatment agents for fabrics and packaging materials to improve the flame and fire resistance of fabrics and packaging materials, however, the chlorinated paraffins currently used for fabric treatment can achieve resistance The flame retardant effect is poor, and it cannot achieve a good flame retardant effect when used alone. At the same time, the chlorinated paraffin currently available on the market for fabric treatment has a single function. In addition to flame retardant and lubricating effects, it is difficult to further improve the quality of the fabric. Therefore, the purpose of the present invention is to study a kind of chlorinated paraffin with better flame retardancy and more functions, which is specially used for fabrics.

Method used

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  • Preparation method of special chlorinated paraffin for surface treatment of fabric

Examples

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Comparison scheme
Effect test

Embodiment 1

[0016] A preparation method of special chlorinated paraffin for fabric surface treatment, comprising the following steps:

[0017] (1) Take 1 part by weight of hexabromocyclododecane, add it to 6 times the weight of absolute ethanol, stir evenly, add 16 parts by weight of triethanolamine, slowly raise the temperature to 70°C, and keep stirring for 30 minutes , to remove ethanol by distillation to obtain modified triethanolamine;

[0018] (2) Get 110 parts by weight of solid paraffin, join it in chloroform of 1.6 times its weight, stir evenly, add 10 parts by weight of phosphoric acid, ultrasonic 1 hour, distill and remove chloroform, obtain phosphoric acid modified paraffin;

[0019] (3) Get the above-mentioned phosphoric acid modified paraffin, send it into the reactor, feed chlorine, adjust the temperature of the reactor to 80°C, react until the specific gravity of the liquid is 1.30, discharge, add 20 parts by weight of pentaerythritol, and increase the temperature to 90°C...

Embodiment 2

[0024] A preparation method of special chlorinated paraffin for fabric surface treatment, comprising the following steps:

[0025] (1) Take 2 parts by weight of hexabromocyclododecane, add it to 10 times the weight of absolute ethanol, stir evenly, add 20 parts by weight of triethanolamine, slowly raise the temperature to 75°C, and keep stirring for 40 minutes , to remove ethanol by distillation to obtain modified triethanolamine;

[0026] (2) Get 130 parts by weight of solid paraffin, join in the chloroform of its weight 2 times, stir evenly, add the phosphoric acid of 17 parts by weight, ultrasonic 2 hours, distill and remove chloroform, obtain phosphoric acid modified paraffin;

[0027] (3) Get the above-mentioned phosphoric acid modified paraffin, send it into the reactor, feed chlorine, adjust the temperature of the reactor to 120°C, react until the liquid specific gravity is 1.55, discharge, add 24 parts by weight of pentaerythritol, raise the temperature to 95°C, add 0...

Embodiment 3

[0032] A preparation method of special chlorinated paraffin for fabric surface treatment, comprising the following steps:

[0033] (1) Take 1 part by weight of hexabromocyclododecane, add it to 8 times the weight of absolute ethanol, stir evenly, add 19 parts by weight of triethanolamine, slowly increase the temperature to 72 ° C, keep stirring for 32 minutes , to remove ethanol by distillation to obtain modified triethanolamine;

[0034] (2) Get 120 parts by weight of solid paraffin, join it in chloroform of 1.7 times its weight, stir evenly, add 18 parts by weight of phosphoric acid, ultrasonic 1 hour, distill and remove chloroform, obtain phosphoric acid modified paraffin;

[0035] (3) Get the above-mentioned phosphoric acid modified paraffin, send it into the reactor, feed chlorine, adjust the temperature of the reactor to 110°C, react until the liquid specific gravity is 1.50, discharge, add 22 parts by weight of pentaerythritol, raise the temperature to 92°C, add 0.22 p...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a preparation method of special chlorinated paraffin for the surface treatment of a fabric. The preparation method comprises the following steps: treating solid paraffin by adopting phosphoric acid, then preparing chlorinated paraffin by adopting a chlorine method, then blending the chlorinated paraffin and pentaerythritol, performing the catalytic reaction in the presenceof p-methylbenzene sulfonic acid, thus obtaining phosphate modified chlorinated paraffin, then dispersing the phosphate modified chlorinated paraffin into dimethyl carbonate, and blending with modifying ester amine to react, thus obtaining the quaternization modifying chlorinated paraffin. Triethanolamine is treated by adopting hexabromocyclododecane, so that the surface hydrophobic performance ofthe fabric is effectively improved; and the quaternization modified chlorinated paraffin is used for treating the fabric, so that the softness, electrostatic resistance, sterilization performance, and yellowing resistance of the fabric can be effectively improved.

Description

technical field [0001] The invention belongs to the field of chlorinated paraffins, and in particular relates to a preparation method of chlorinated paraffins specially used for fabric surface treatment. Background technique [0002] Chlorinated paraffins are used in paints, chlorinated rubber and styrene-butadiene resin coatings. In plastics, they are used as flame retardants, binders, cementing agents and fillers, and can also be used as lubricating additives. They also have Moisture resistance and chemical resistance, it can also be used in surface treatment agents for fabrics and packaging materials to improve the flame and fire resistance of fabrics and packaging materials, however, the chlorinated paraffins currently used for fabric treatment can achieve resistance The flame retardant effect is poor, and it cannot achieve a good flame retardant effect when used alone. At the same time, the chlorinated paraffin currently available on the market for fabric treatment has ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G73/38
CPCC10G73/38
Inventor 司彩霞
Owner ANHUI XINGXIN CHEM TECH
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