Water-swelling delayed curing material

A technology of solidifying materials and water-swelling technology, which is applied in the field of leakage sealing, which can solve the problems of weak cement strength, high strength, and low strength, and achieve good sealing and anti-seepage effects

Inactive Publication Date: 2019-01-22
长沙工研院环保有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, leakage often occurs on the interface with high pressure difference. It takes a certain amount of time for the cement to solidify (the early strength is small, and the strength is strong after complete solidification), and the solidification process requires a relatively static environment, otherwise the bonding and connection of hydrates will be affected. , and once holes are formed on the interface with high pressure difference, the water flow will flow out continuously, disturbing the overlapping and connection of hydrates, and the early strength of cement is weak, so it is difficult to withstand the impact of water flow at the interface with high pressure difference, so it is difficult to form an effective to block

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] 1. Bond water-soluble cellulose to the surface of the spherical mold to form a shell, and then remove the mold and fill the shell with cement to form a "shell-core" structure. The thickness of the "shell" in the "shell-core" structure is 1mm;

[0022] 2. According to the mass ratio of cement and starch-grafted acrylic water-absorbing resin of 1:1, the above-mentioned "shell core" structure and starch-grafted acrylic water-absorbing resin are evenly mixed to obtain a water-swellable solidified material;

[0023] 3. When the water-swelling and delayed-curing material encounters water, the starch-grafted acrylic water-absorbing resin first absorbs water and swells, and the pores are squeezed to achieve early-stage sealing, and at the same time, the water-soluble cellulose continues to dissolve;

[0024] 4. After the starch-grafted acrylic water-absorbing resin is blocked, the water-soluble fiber is completely dissolved, the cement contacts with water, and the curing reactio...

Embodiment 2

[0027] 1. Bond water-soluble starch on the surface of a spherical mold to form a shell, and then remove the mold and fill the shell with fly ash to form a "shell-core" structure. The thickness of the "shell" in the "shell-core" structure is 0.2 mm;

[0028] 2. According to the mass ratio of fly ash and protein graft copolymer water-absorbent resin of 1:10, the above-mentioned "shell core" structure and protein graft copolymer water-absorbent resin are evenly mixed to obtain a water-swellable solidified material;

[0029] 3. When the water-swelling delayed curing material encounters water, the protein-grafted copolymer water-absorbing resin first absorbs water and swells and squeezes the pores to achieve pre-blocking, and at the same time, the water-soluble starch continues to dissolve;

[0030] 4. After the protein graft copolymer water-absorbing resin is blocked, the water-soluble starch is completely dissolved, and the fly ash contacts with water, and the curing reaction beg...

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Abstract

The invention provides a water-swelling delayed curing material, which comprises a curing material, a water-soluble material and an expanding material, wherein the surface of the curing material is coated with the water-soluble material to form a shell-nuclear structure. The surface of the curing material is coated with the water-soluble material to form the shell-nuclear structure so as to effectively avoid a contradiction of simultaneous expansion and curing. When the water-swelling curing material meets water, an expanding component adsorbs water to expand to extrude with a hole so as to realize early-stage blocking. Meanwhile, the water-soluble material as a shell in the shell-nuclear structure slowly dissolves after meeting water so as to generate an organic molecule which has a crosslinking function, an accelerating function is realized on the curing of subsequent curing materials and the fixing of the curing material for the expanding material, water further carries out curing reaction with the curing component, and blocking and seepage prevention are favorably finished under the joint function of the curing material, the expanding material and water.

Description

technical field [0001] The invention belongs to the field of leakage plugging, in particular to a water-swelling and time-delayed solidification material. technical background [0002] With the strengthening of people's awareness of environmental protection, landfills and other places involving the leakage of dangerous liquids have adopted multi-level protective measures. Since it is difficult to effectively evaluate the effect of these protective measures due to geological effects, they are often added to them. Leakproof material. Water-swelling (such as water-absorbing resin) and water-curing (such as cement) are two common types of leak-proof materials. The former swells when it meets water, and the latter undergoes a curing reaction and solidifies when it meets water. The effect of blocking holes. [0003] However, these two types of materials still have some deficiencies in engineering applications. [0004] The water-swellable material introduces water molecules int...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/00C04B41/63
CPCC04B28/00C04B41/63C04B24/38C04B24/383C04B24/24C04B41/4803
Inventor 何曦
Owner 长沙工研院环保有限公司
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