The invention discloses an activated carbon fiber modification method, a water treatment filter device and an application of the water treatment filter device, and belongs to the field of water treatment and filler. Firstly, carbon fiber precursors are pretreated by deionized water, immersed by a salpeter solution with ammonium dihydrogen phosphate and then dried and sintered, and modified active carbon fiber is obtained. The specific surface area and surface oxygen-containing groups of the activated carbon fiber are increased, the microorganism affinity is enhanced, the film formation speed and the film formation amount of water treatment filler obtained on basis of the activated carbon fiber are remarkably increased, dissolved and suspended pollutants in water can be better absorbed, the water treatment filler device can be used for sewage treatment engineering such as treatment of organic dye wastewater, wastewater of a pharmaceutical factory, papermaking wastewater and the like as well as purification of domestic wastewater, raw water of a water factory and the like, and the advantages that the method is simple and easy to implement, the water treatment filler has a simple structure, the design is reasonable, and manufacture is easy are achieved.