Sunlight-driven water purifying material and preparation method and application thereof
A technology for purifying materials and driving water, which is applied in chemical instruments and methods, general water supply saving, gel preparation, etc. It can solve the problems of pressurization, low efficiency of light and heat evaporation water, and low efficiency, so as to improve utilization rate and high efficiency The effects of interception performance and high-efficiency solar-to-thermal conversion performance
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Embodiment 1
[0042]Embodiment 1, the preparation of sunlight-driven water purification material
[0043] For the preparation of double skeleton structure, this example prepares a polyamide foam with a size of 5.5cm×8.0cm×1cm, mixes 20mg of ammonium persulfate and 20 microliters of N,N,N',N'-tetramethylmethylene di The amine was added to 20 mL of deionized water, and the solution was evenly sprayed on the polycyanamide foam with a sprayer, and dried at room temperature. At the same time, 2.264 g of N-isopropylacryloyl and 120 mg of N,N'-methylenebisacryloyl were ultrasonically dissolved into 20 mL of deionized water, soaked with ammonium persulfate and N,N,N',N' -The polycyanamide foam of tetramethylmethylenediamine adsorbs the solution, seals it at room temperature, and lets it stand for 12 hours, takes out the double-skeleton hydrogel, and dialyzes it in deionized water for 1 day to remove unreacted substances.
[0044] Weigh 100mg of graphene oxide prepared by Hummers, ultrasonically di...
Embodiment 2
[0048] Embodiment 2, sunlight drives water purification material to purify water
[0049] Purify water as follows:
[0050] 1) The white side of the uncoated graphene oxide of the material prepared in Example 1 is placed downwards, and the black side coated with the graphene oxide film is placed upwards in the funnel, the upper part of the funnel is sealed, and placed in a solar simulator light source Under the launch port, place a conical flask or other water collection device at the lower end of the funnel;
[0051] 2) Turn on the light source, the incident light is converted into heat energy by the graphene oxide coated on the periphery, heating the internal double skeleton structure, the hydrogel structure collapses and squeezes out the adsorbed water, and at the same time part of the water evaporates into the closed funnel, Condensation occurs on the wall of the funnel, which flows back into the collection device at the lower end;
[0052] 3) Transfer the water purifica...
Embodiment 3
[0054] Embodiment 3, the purification of single molecule by sunlight-driven water purification material
[0055] This example uses common organic dye molecules to demonstrate the purification effect of sunlight-driven water purification materials on a single molecule. The selected molecules include rhodamine B (rhodamine B, RB), rhodamine 6G (rhodamine 6G, RGG), methyl Methyl orange (CR), methylene blue (MLB), Evans blue (EB), basic fuchsin (BF) and brilliant yellow (BY) were used as the research objects. The above organic dyes were prepared into 50mgmL -1 , 100mgmL -1 and 200mgmL -1 In the aqueous solution, the materials prepared in Example 1 were respectively soaked in the above solution, and after being balanced, they were transferred to the funnel. According to the steps of Example 2, the device was irradiated with natural sunlight to complete the water collection, and the ultraviolet-visible spectrum was used to irradiate the device. Draw the working curve of different...
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