Preparation method for carbon-containing quantum dot white light emitting room temperature ionic liquid

A room temperature ionic liquid, carbon quantum dot technology, applied in chemical instruments and methods, nano-carbon, luminescent materials, etc., can solve the problems of low luminous efficiency, complicated construction methods, etc., achieve simple operation, simple and feasible preparation method, and broaden the spectrum. range effect

Active Publication Date: 2019-02-22
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Aiming at the deficiencies of the prior art, especially the complicated construction method of luminescent room temperature ionic liquids and low luminous efficiency, the present invention provides a preparation method of carbon-containing quantum dot white light emitting room temperature ionic liquids. Carbon quantum dots emit green li...

Method used

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  • Preparation method for carbon-containing quantum dot white light emitting room temperature ionic liquid
  • Preparation method for carbon-containing quantum dot white light emitting room temperature ionic liquid
  • Preparation method for carbon-containing quantum dot white light emitting room temperature ionic liquid

Examples

Experimental program
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Effect test

Embodiment 1

[0052] Preparation of Green Light Emitting Carbon Quantum Dots

[0053] Weigh 0.16g o-phenylenediamine, 0.083g 1-aminopropyl-3-methylimidazolium bromide, stir and dissolve in 10mL deionized water; React for 12 hours; after the reaction, turn off the oven, cool to room temperature naturally, and obtain a reaction solution, measure the fluorescence quantum yield of carbon quantum dots in the reaction solution obtained to be 6.94%; further use the reaction solution through silica gel column chromatography, and use ethyl acetate The ester was used as the eluent for purification, and the solvent was evaporated to dryness to obtain green light-emitting carbon quantum dots.

Embodiment 2

[0055] Preparation of Green Light Emitting Carbon Quantum Dots

[0056] As described in Example 1, the difference is that the amount of 1-aminopropyl-3-methylimidazolium bromide added is 0 g, and the fluorescence quantum yield of carbon quantum dots in the resulting reaction solution is 7.90%.

Embodiment 3

[0058] Preparation of Green Light Emitting Carbon Quantum Dots

[0059] As described in Example 1, the difference is that the addition of 1-aminopropyl-3-methylimidazolium bromide is 0.17g, and the fluorescence quantum yield of carbon quantum dots in the resulting reaction solution is 10.31%. After purification, the obtained The fluorescence quantum yield of green light-emitting carbon quantum dots is 11.68%.

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Abstract

The invention discloses a preparation method for a carbon-containing quantum dot white light emitting room temperature ionic liquid. The method comprises the following steps: respectively preparing green light emitting carbon quantum dots and red light emitting carbon quantum dots by a hydrothermal method and a phosphoric acid thermal method by taking o-phenylenediamine as a precursor; dissolvingthe green light emitting carbon quantum dots and red light emitting carbon quantum dots in room temperature ionic liquid to obtain a carbon-containing quantum dot green light emitting room temperatureionic liquid and a carbon-containing quantum dot red light emitting room temperature ionic liquid; obtaining the carbon-containing quantum dot white light emitting room temperature ionic liquid withthe colour coordinates of (0.3298, 0.3284) by combining the prepared carbon-containing quantum dot blue light emitting room temperature ionic liquid and regulating the mixing ratio of the carbon-containing quantum dot green light emitting room temperature ionic liquid, the carbon-containing quantum dot red light emitting room temperature ionic liquid and the carbon-containing quantum dot blue light emitting room temperature ionic liquid. The green light emitting quantum dots and the red light emitting quantum dots prepared by the preparation method can be dissolved in a room temperature ionicliquid directly; the colour radicals of the prepared white light emitting room temperature ionic liquid completely consist of carbon quantum dots. The preparation method disclosed by the invention iseasy to operate, suitable for large-scale industrial production, and is beneficial to expand the application of the carbon quantum dots in the field of fluorescent printing ink.

Description

technical field [0001] The invention relates to a preparation method of a carbon-containing quantum dot white light emitting room temperature ionic liquid, which belongs to the field of new materials. Background technique [0002] Ionic liquids are a class of low-temperature molten salts composed of relatively large cations and anions. Among them, ionic liquids that are liquid at room temperature are called room temperature ionic liquids. Room temperature ionic liquids have good thermal stability, low volatility, and nonflammability, and are known as "green solvents" with programmable molecules and adjustable properties. In recent years, room temperature ionic liquids with photoluminescent properties have attracted extensive attention from researchers. The usual practice is to graft fluorescent chromophores onto ionic liquids, or use coordination to introduce rare earth elements into room temperature ionic liquids. It has been reported in the literature that π-conjugated g...

Claims

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Application Information

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IPC IPC(8): C09K11/02C09K11/65C01B32/15B82Y20/00
CPCB82Y20/00C09K11/025C09K11/65C01B32/15Y02B20/00
Inventor 李洪光孙晓峰
Owner SHANDONG UNIV
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