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Hydrocarbon oil catalytic conversion method of a light hydrocarbon and heavy hydrocarbon composite raw material

A catalytic conversion method and catalytic cracking technology are applied in the field of catalytic conversion for improving the yield of gasoline and propylene, and can solve the problems of low gasoline yield, high propylene yield, complicated process, etc., and achieve accelerated cracking of heavy hydrocarbons, increased gasoline production, The effect of even contact

Active Publication Date: 2021-01-01
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent uses two riser reactors, the embedded riser uses mixed C4, FCC light gasoline, light naphtha, and light diesel oil as raw materials, and the outer embedded riser uses Daqing mixed oil or Daqing vacuum residue as raw materials , the gasoline yield is low, and the process is relatively complicated, making it difficult to implement
[0009] Therefore, how to solve the problem of high propylene yield and low gasoline yield in the prior art has become the focus of attention of researchers and a key problem to be solved

Method used

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  • Hydrocarbon oil catalytic conversion method of a light hydrocarbon and heavy hydrocarbon composite raw material
  • Hydrocarbon oil catalytic conversion method of a light hydrocarbon and heavy hydrocarbon composite raw material
  • Hydrocarbon oil catalytic conversion method of a light hydrocarbon and heavy hydrocarbon composite raw material

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] according to figure 1 The device shown and figure 2 The one-piece nozzle shown was tested.

[0051] The heights of light hydrocarbon reaction zone I, heavy hydrocarbon reaction zone and light hydrocarbon reaction zone II account for 5%, 35% and 55% of the total height of the riser reactor respectively. The ratio of the outer diameter of the light hydrocarbon casing to the outer diameter of the heavy hydrocarbon outer casing is 2.20:1, and the ratio of the aperture diameter of a single light hydrocarbon nozzle on the light hydrocarbon nozzle to the diameter of a single heavy hydrocarbon outer nozzle on the heavy hydrocarbon nozzle is 1.429:1. The pre-lift medium was nitrogen.

[0052] 3 million catalytically cracked naphtha with a mass flow rate of 150 g / h is sprayed from 4 light hydrocarbon nozzles 31 on the light hydrocarbon nozzle 15 of the integrated nozzle 11, and is injected into the light hydrocarbon reaction zone I in the riser reactor 4 and regenerated Cata...

Embodiment 2

[0057] according to figure 1 The device shown and figure 2 The one-piece nozzle shown was tested.

[0058] The heights of light hydrocarbon reaction zone I, heavy hydrocarbon reaction zone and light hydrocarbon reaction zone II account for 5%, 35% and 55% of the total height of the riser reactor respectively. The ratio of the outer diameter of the light hydrocarbon casing to the outer diameter of the heavy hydrocarbon outer casing is 2.20:1, and the ratio of the aperture diameter of a single light hydrocarbon nozzle on the light hydrocarbon nozzle to the diameter of a single heavy hydrocarbon outer nozzle on the heavy hydrocarbon nozzle is 1.429:1. The pre-lift medium was nitrogen.

[0059] 3 million catalytically cracked naphtha with a mass flow rate of 150 g / h is sprayed from 4 light hydrocarbon nozzles 31 on the light hydrocarbon nozzle 15 of the integrated nozzle 11, and is injected into the light hydrocarbon reaction zone I in the riser reactor 4 and regenerated Cata...

Embodiment 3

[0064] according to figure 1 The device shown and figure 2 The one-piece nozzle shown was tested.

[0065] The heights of light hydrocarbon reaction zone I, heavy hydrocarbon reaction zone and light hydrocarbon reaction zone II account for 5%, 35% and 55% of the total height of the riser reactor respectively. The ratio of the outer diameter of the light hydrocarbon casing to the outer diameter of the heavy hydrocarbon outer casing is 2.20:1, and the ratio of the aperture diameter of a single light hydrocarbon nozzle on the light hydrocarbon nozzle to the diameter of a single heavy hydrocarbon outer nozzle on the heavy hydrocarbon nozzle is 1.429:1. The pre-lift medium was nitrogen.

[0066] 3 million catalytically cracked naphtha with a mass flow rate of 150 g / h is sprayed from 4 light hydrocarbon nozzles 31 on the light hydrocarbon nozzle 15 of the integrated nozzle 11, and is injected into the light hydrocarbon reaction zone I in the riser reactor 4 and regenerated Cata...

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Abstract

The invention relates to a catalytic conversion method for hydrocarbon oil containing a light hydrocarbon-heavy hydrocarbon composite raw material. The method of the invention mainly solves the problems of high propylene yield and low gasoline yield in the prior art. The catalytic conversion method provided by the invention comprises the following steps: allowing preheated light hydrocarbons (gasoline fractions) and heavy hydrocarbons to be simultaneously and respectively sprayed out from an integrated spray nozzle into different reaction zones of a lift pipe reactor to contact and react witha catalyst from a regenerator, allowing reaction products and a carbon deposit catalyst to flow out from the lift pipe reactor and to enter a cyclone separation system for separation, allowing the separated catalyst to undergo steam stripping, then enter the regenerator for charring and then return to the bottom of the lift pipe reactor for cyclic use, and allowing the reaction products to undergofractional distillation via fractionating towers so as to obtain corresponding products, wherein the integrated spray nozzle is a spray nozzle capable of simultaneously and respectively spraying thelight hydrocarbons and the heavy hydrocarbons out from different spray heads; and the reaction zones are composed of a light hydrocarbon reaction zone I, a heavy hydrocarbon reaction zone and a lighthydrocarbon reaction zone II successively arranged along the vertical direction of the reactor from bottom to top. The catalytic conversion method provided by the invention has the characteristic of capacity of improving the yield of gasoline and propylene.

Description

technical field [0001] The invention relates to a catalytic conversion method for hydrocarbon raw materials, more specifically, to a catalytic conversion method for increasing the yield of gasoline and propylene in the absence of hydrogen. Background technique [0002] With the rapid development of the global economy, it has become an important development trend of the contemporary oil refining industry to develop oil refining technologies that effectively utilize oil resources, especially heavy and low-quality crude oil resources, and to maximize the acquisition of high-quality clean light oil products and basic chemical raw materials. As the main production process of light oil products in the oil refining industry, catalytic cracking has attracted extensive attention from major research and development institutions at home and abroad because of its wide applicability and relatively low processing cost. [0003] At present, the trend of heavy and inferior raw materials for...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G55/06C10G3/00C07C4/06C07C11/06
CPCC07C4/06C10G3/42C10G55/06C10G2300/107C10G2300/1077C10G2400/02C10G2400/20C07C11/06Y02P20/52Y02P20/584Y02P30/20
Inventor 侯凯军王智峰高永福李荻张忠东王福善王宝杰董建林孟凡芳熊晓云刘超伟刘涛
Owner PETROCHINA CO LTD