Thermosetting electroconductive adhesive

A conductive, heat-curing technology, applied in the direction of conductive adhesives, adhesives, conductive materials, etc.

Active Publication Date: 2019-04-26
THREE BOND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In addition, in a conductive adhesive such as JP 2000-53733 A, if a large amount of conductive particles such as silver powder is introduced, the conductivity will be improved accordingly, but there will be a problem of storage stability. A small amount of addition shows good conductivity

Method used

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  • Thermosetting electroconductive adhesive
  • Thermosetting electroconductive adhesive
  • Thermosetting electroconductive adhesive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~5、 comparative example 1~7

[0044] To prepare the adhesive, prepare the following ingredients.

[0045] (A) Component: Oligomer having a (meth)acryloyl group

[0046] ・Aliphatic urethane acrylate (number of functional groups: 2) (Ebecryl 8402 manufactured by Daicel Allnex Co., Ltd.)

[0047] ・Polyester polyfunctional acrylate (Aronix M-8030 manufactured by Toagosei Co., Ltd.)

[0048] ・Aromatic urethane acrylate (number of functional groups: 6) (Ebecryl 220 manufactured by Daicel Allnex Co., Ltd.)

[0049] (B) Component: A monomer having one methacryloyl group in the molecule

[0050] ・Isobornyl methacrylate (manufactured by LIGHT ESTER IBX Kyoeisha Chemical Co., Ltd.)

[0051] ・2-Hydroxypropyl methacrylate (manufactured by LIGHT ESTER HOP (N) Kyoeisha Chemical Co., Ltd.)

[0052] (B') Component: Monomers other than (B) Component

[0053] ・Isobornyl Acrylate (Light Acrylate IBXA Kyoeisha Chemical Co., Ltd.)

[0054] ・2-Hydroxypropyl acrylate (Light Acrylate HOP-A(N) produced by Kyoeisha Chemical Co...

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Abstract

In the past, it was necessary to add many electroconductive particles in order to improve electroconductivity, and adding many particles caused the initial viscosity to rise and made it difficult to stabilize storage stability. In the present invention, however, selecting monomers makes it possible to improve the electroconductivity even if many electroconductive particles are not added, and usingspecific electroconductive particles makes it possible to stabilize the storage stability. A thermosetting electroconductive adhesive including components (A)-(D), wherein the component (A) is an oligomer having (meth)acryl groups, the component (B) is monomers having one methacryl group in the molecule, the component (C) is an organic peroxide having a specific structure, and the component (D) is electroconductive particles surface-treated by stearic acid.

Description

technical field [0001] The present invention relates to a thermosetting isotropic conductive adhesive. Background technique [0002] In a thermosetting composition composed of an oligomer having a (meth)acryloyl group and a monomer, it is known to use a stabilizer such as a polymerization inhibitor as a means of maintaining storage stability. (Hereinafter, an acryloyl group and a methacryloyl group are also called a (meth)acryloyl group). However, it is known that if the stabilizer is excessively introduced, the curability is lowered, and in the worst case, no cure occurs. In addition, in a conductive adhesive such as JP 2000-53733 A, if a large amount of conductive particles such as silver powder is contained, metal ions will affect the peroxide, so gelation will easily occur. In particular, when stored in a non-air-permeable container, there is a problem that gelation occurs in a short period of time. This is because, in the curing form of the (meth)acrylic resin compos...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C09J4/02C09J9/02C09J11/04C09J11/06H01B1/00H01B1/20
CPCC09J9/02C09J11/04H01B1/00H01B1/20C08K2003/0806C09J2433/00C09J2203/326C09J2301/408C08K2201/001C08K2201/019C08K9/04C08K5/14C09J4/06C08F290/067C09J11/06C09J4/00C08K3/08C09J133/08
Inventor小玉智也太田综一长田诚之真船仁志加藤诚森井佳奈子
OwnerTHREE BOND CO LTD