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A kind of preparation method of lithium ion electrochemical energy storage device

An electrochemical, lithium-ion technology, applied in the field of lithium-ion electrochemical energy storage devices, can solve the problems of long pre-lithium intercalation time, low production efficiency, and the performance of lithium-ion electrochemical energy storage devices needs to be improved, so as to improve production efficiency. , to ensure the overall performance, to solve the effect of large-scale production

Active Publication Date: 2020-12-15
INST OF ELECTRICAL ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Therefore, the technical problem to be solved by the present invention is to overcome the fact that the production of lithium-ion electrochemical energy storage devices in the prior art needs to be carried out in a protective gas environment that isolates water and oxygen, the production efficiency is low, and the time for pre-embedding lithium is long, The performance of lithium-ion electrochemical energy storage devices needs to be improved, so as to provide a device that can be produced in a non-protective atmosphere environment, has good compatibility with other equipment, and has high production efficiency, short pre-embedded lithium time, and lithium-ion Preparation method of lithium-ion electrochemical energy storage device with good performance of electrochemical energy storage device

Method used

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  • A kind of preparation method of lithium ion electrochemical energy storage device
  • A kind of preparation method of lithium ion electrochemical energy storage device
  • A kind of preparation method of lithium ion electrochemical energy storage device

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Experimental program
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Embodiment 1

[0063] The first pipe is a PP pipe with an inner diameter of 3 mm and a length of 20 mm. Then put the heat-sealed energy storage device into the hot-pressing forming equipment, control the temperature of the hot-pressing forming equipment to 120°C, and then vacuumize the inside of the shell for 48 hours by opening the valve on the second pipeline, Remove the moisture inside the shell. Then, after the energy storage device is naturally cooled, liquid is injected into the inside of the housing through the second pipeline, and the pressure is maintained at -70kPa until the electrolyte is completely infiltrated. Then block the communication between the PP pipeline and the second pipeline, and after pre-embedding lithium on the negative electrode of the battery cell by electrochemical method, finally connect the positive electrode, negative electrode and lithium electrode of the lithium ion energy storage device to charge Discharge equipment, first charge and discharge the negativ...

Embodiment 2

[0071] The first pipe is a pipe made of the same material as the heat-sealing glue with an inner diameter of 2 mm and a length of 50 mm. . Then put the heat-sealed energy storage device into the hot-pressing forming equipment, control the temperature of the hot-pressing forming equipment to 100°C, and at the same time, vacuumize the inside of the shell for 72 hours by opening the valve on the second pipeline, Remove the moisture inside the shell. Then, after the energy storage device is naturally cooled, liquid is injected into the inside of the casing through the second pipeline, and the pressure is maintained at -90kPa until the electrolyte is completely infiltrated. Then block the communication between the first pipeline and the second pipeline, and after pre-intercalating lithium on the negative electrode of the battery cell by electrochemical method, finally connect the positive electrode, negative electrode and lithium electrode of the lithium ion energy storage device ...

Embodiment 3

[0079] The first pipe is a nickel pipe with an inner diameter of 5 mm and a length of 5 mm, whose outer and inner surfaces are coated with heat-sealing glue. Then put the heat-sealed energy storage device into the hot-pressing forming equipment, control the temperature of the hot-pressing forming equipment to 150°C, and at the same time, vacuumize the inside of the shell for 12 hours by opening the valve on the second pipeline, Remove the moisture inside the shell. Then, after the energy storage device is naturally cooled, liquid is injected into the casing through the second pipeline, and the pressure is maintained at -30kPa until the electrolyte is completely infiltrated. Then block the connection between the nickel tube and the second pipeline, pre-embed lithium on the positive electrode or the negative electrode of the battery cell by electrochemical method, and finally connect the positive electrode, the negative electrode and the lithium electrode of the lithium ion ener...

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Abstract

The invention relates to the technical field of energy storage devices, in particular to a preparation method of a lithium ion electrochemical energy storage device, comprising: short-circuiting the negative electrode of the battery cell with the metal lithium electrode, and setting a partition between the battery cell and the metal lithium electrode For the diaphragm of the two, the battery cell, metal lithium electrode and diaphragm are packaged in the case, at least one first pipeline is embedded in the case, after the case is heat-sealed, the inside of the case is vacuumed, and the electrolytic solution is injected into the case. Liquid, block the connection between the first pipeline and the second pipeline, the positive pole of the battery cell is connected to the positive pole of the power supply, the negative pole of the battery cell is connected to the negative pole of the power supply, and the negative pole of the battery cell is charged and discharged. , heat sealing the opening at the other end of the first pipeline, and disconnecting the second pipeline from the first pipeline to obtain a lithium ion electrochemical energy storage device. The invention provides a preparation method of a lithium-ion electrochemical energy storage device which can be produced in a non-protective atmosphere environment, has short lithium pre-intercalation time and good performance.

Description

technical field [0001] The invention relates to the technical field of lithium ion electrochemical energy storage devices, in particular to a preparation method of lithium ion electrochemical energy storage devices. Background technique [0002] At present, the domestic energy system is gradually shifting from traditional fossil energy to a new energy system dominated by electricity. In order to achieve this goal, energy storage devices are also developing in the direction of higher energy density and lower manufacturing costs. Among them, lithium-ion electrochemical storage High-energy devices have become one of the most promising directions due to their high-rate discharge and improved cycle life. However, there are still some problems in the large-scale production of lithium-ion electrochemical energy storage devices, such as the inevitable lithium supplementation of the negative electrode, the removal of the electrolyte in the rich liquid system, the removal of gas durin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/058H01M10/04H01M4/04
CPCY02E60/10Y02P70/50
Inventor 安亚彬马衍伟孙现众张熊
Owner INST OF ELECTRICAL ENG CHINESE ACAD OF SCI