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Method for producing molten glass and method for producing glass article

A technology of molten glass and manufacturing method, which is applied in the manufacture of aluminosilicate glass and the manufacture of glass objects, to achieve the effects of reducing melting delay, reducing manufacturing, and excellent homogeneity

Active Publication Date: 2021-12-31
ASAHI GLASS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the glass is required to have chemical resistance, high durability, few bubbles in the glass, high homogeneity, and high flatness. glass is harder

Method used

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  • Method for producing molten glass and method for producing glass article
  • Method for producing molten glass and method for producing glass article
  • Method for producing molten glass and method for producing glass article

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0120] Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to these Examples.

[0121]

[0122] The particle size distribution was measured by wet laser diffraction using a laser diffraction / scattering particle size distribution measuring device (manufactured by Horiba, Ltd., product name: LA-950), and D10, D50, or D90 was determined. When the particles are aggregated in the dispersion medium, the aggregates are dispersed by ultrasonic waves, and the particle size distribution of the primary particles constituting the aggregates is measured.

[0123]

[0124] Silica sand, alumina, an alkali metal source, and other raw materials are adjusted so that alkali-aluminosilicate glass of a predetermined glass composition is obtained to form a glass raw material composition.

[0125] The prepared glass raw material composition and cullet were mixed at a predetermined ratio, put into a crucible, and melted in the crucible. Measure t...

example 1~5

[0149] Examples 1 and 2 are examples, and examples 3 to 5 are comparative examples. Silica sand, alumina, an alkali metal source, a magnesium source, and a clarifying agent shown in Table 3 were adjusted so as to become the following glass composition (i) to prepare a glass raw material composition. The addition amount of the clarifying agent was 1.4 mol% with respect to a glass raw material composition.

[0150] The temperature at the bottom of the crucible, the thickness of the floating matter layer, and the number of bubbles were measured for the glass raw material compositions of each example by the above-mentioned method. The mass ratio of glass raw material composition: cullet was 50:50. The results are shown in Table 3.

[0151]

[0152] SiO 2 : 68.0 mol%, Al 2 o 3 : 10.0 mol%, MgO: 8.0 mol%, Na 2 O: 14.0 mol%. SiO 2 / Al 2 o 3 The molar ratio is 6.8.

[0153] [table 3]

[0154]

[0155] According to the results in Table 3, use alumina U with a D90 of 20...

example 6~9

[0157] Examples 6-8 are examples, and Example 9 is a comparative example. Silica sand, alumina, an alkali metal source, a magnesium source, and a clarifier shown in Table 4 were adjusted so as to become the above-mentioned glass composition (i) to prepare a glass raw material composition. The addition amount of clarifying agent is identical with example 1.

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Abstract

The present invention provides a method for producing molten glass capable of reducing the melting delay of glass raw materials. The manufacturing method of described molten glass is to melt the glass raw material composition containing silica sand, aluminum oxide and alkali metal source to produce 2 50 mol% or more, Al 2 o 3 is more than 5 mol% and Li 2 O, Na 2 O, K 2 A molten glass with a glass composition of 5 mol% or more in total O, D90 of silica sand is 450 μm or more, and the difference between D90 and D10 is 350 μm or more, D90 of alumina is 200 μm or less, and the pore diameter measured by mercury porosimetry In the pore volume distribution in the range of 0.004 to 5 μm, the ratio of the volume of the pore diameter of 0.1 to 5 μm is 60% or more.

Description

technical field [0001] The present invention relates to a method for producing molten glass and a method for producing glass articles, and in particular, to a method for producing aluminosilicate glass and a method for producing glass articles. Background technique [0002] Since strength is required for a cover glass of a liquid crystal display device or the like, alkali aluminosilicate glass is generally used. In addition, the glass is required to have chemical resistance, high durability, few bubbles in the glass, high homogeneity, and high flatness. The case of glass is more difficult. [0003] In addition, in general, in a glass melting process, it is important to uniformly and rapidly melt silica sand, which is the most difficult to melt in the glass raw material composition, into the molten glass in order to improve the quality of the glass product and increase the productivity. [0004] In Patent Document 1, as a method for producing alkali aluminosilicate glass, a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C1/02C03B3/02C03C3/085C03C3/087C03C3/091
CPCC03B3/02C03C1/02C03C3/085C03C3/087C03C3/091C03B3/00
Inventor 山本峰子前原辉敬土井洋二佐佐木薰
Owner ASAHI GLASS CO LTD