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A fluidized bed activated carbon adsorption and denitrification method for low-sulfur flue gas

An activated carbon adsorption and fluidized bed technology, applied in separation methods, climate sustainability, chemical instruments and methods, etc., can solve the problems of catalyst poisoning, consumption, large construction investment, etc., and achieve the effect of small mass transfer radius

Active Publication Date: 2021-11-16
SHENYANG DONGDASHANHUI ENVIRONMENTAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The construction investment is very large, the area is large, and the denitrification also consumes a large amount of energy-intensive ammonia, and the operating cost is high. The sulfur recovery treatment at the rear is a pure industrial process, which is very difficult for non-chemical enterprises to operate and manage.
[0004] At present, most of the high-sulfur flue gas has undergone desulfurization transformation, and most of the sulfur has reached the standard. Since most of them adopt the wet desulfurization process, the flue gas temperature is 50-60°C. If the SCR process is used for denitrification after desulfurization, It needs to consume a lot of energy to raise the temperature; moreover, sulfur and nitrate will be generated during the heating process, which will increase the processing cost
If the SCR process is used for denitrification before wet desulfurization, due to the relatively high sulfur in the flue gas, it is easy to cause catalyst poisoning and affect the denitrification efficiency, especially when low temperature denitrification is used; higher

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A sintering machine adopts semi-dry desulfurization method, and the SO in the generated low-sulfur flue gas 2 Concentration 60mg / m 3 , SO 3 The concentration of 2mg / m 3 , NO X Concentration of 378mg / m 3 , the content of free water is 0;

[0029] The low-sulfur flue gas is passed into the fluidized bed from the inlet of the fluidized bed. The fluidized bed is a pipeline reactor, the outlet of the fluidized bed is connected with the feed port of the bag filter, and the outlet of the bag filter Fan connection; start the induced draft fan, the temperature of the low-sulfur flue gas is 139°C, and the flow velocity of the low-sulfur flue gas in the fluidized bed is 3m / s;

[0030] The activated carbon is crushed into activated carbon powder with a particle size of ≤120 mesh; the activated carbon powder is sprayed into the fluidized bed through the powder spraying device, and the injection amount is based on the activated carbon powder and the NO in the low-sulfur flue gas...

Embodiment 2

[0033] Method is with embodiment 1, and difference is:

[0034] (1) SO in low-sulfur flue gas generated by wet desulfurization process 2 Concentration 80mg / m 3 , SO 3 Concentration 5mg / m 3 , NO X The concentration of 425mg / m 3 , the content of free water is 52mg / m 3 ;

[0035] (2) The temperature of the low-sulfur flue gas is 54°C, and the flow velocity of the low-sulfur flue gas in the fluidized bed is 5m / s;

[0036] (3) Grinding the activated carbon into activated carbon powder with a particle size of ≤180 mesh; X The mass ratio of the fluidized bed is 20; at the same time, a demister is set at the inlet of the fluidized bed, and lime powder is added to the activated carbon powder, the particle size of the lime powder is ≤180 mesh, and the lime powder accounts for 5% of the total mass of the activated carbon powder; the activated carbon as straw charcoal;

[0037] (4) Contact time 8s; purification of NO in flue gas X Concentration of 73mg / m 3 , SO 2 Concentration...

Embodiment 3

[0039] Method is with embodiment 1, and difference is:

[0040] (1) SO in low-sulfur flue gas generated by wet desulfurization process 2 The concentration of 90mg / m 3 , SO 3 Concentration 8mg / m 3 , NO X Concentration of 539mg / m 3 , the content of free water is 57mg / m 3 ;

[0041] (2) The temperature of the low-sulfur flue gas is 50°C, and the flow velocity of the low-sulfur flue gas in the fluidized bed is 8m / s;

[0042] (3) Grinding the activated carbon into activated carbon powder with a particle size of ≤180 mesh; X The mass ratio is 30; a heating device is installed at the inlet of the fluidized bed to heat the low-sulfur flue gas so that the temperature of the low-sulfur flue gas reaches 55°C, and then enters the fluidized bed; the relative humidity is detected online at 80%; the activated carbon Cracking charcoal for anthracite;

[0043] (4) Contact time 6s; purify NO in flue gas X Concentration 88mg / m 3 , SO 2 Concentration 5mg / m 3 , SO 3 Concentration 3mg...

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Abstract

A fluid bed activated carbon adsorption denitrification method for low-sulfur flue gas is carried out according to the following steps: (1) passing the low-sulfur flue gas into the fluid bed from the inlet of the fluid bed; (2) crushing the activated carbon into activated carbon powder; The powder spraying device sprays activated carbon powder into the fluidized bed, and the activated carbon powder and the low-sulfur flue gas are mixed in the fluidized bed and move to the outlet of the fluidized bed, and perform desulfurization and denitration; (3) Control the flow of the activated carbon powder and the low-sulfur flue gas The contact in the bed is 3 to 10s, the dust is adsorbed and collected in the bag filter; the low-sulfur flue gas is desulfurized, denitrified and dedusted to form purified flue gas and discharged. The method of the invention saves the energy consumption of denitration; the reactor can be very small, and the investment is reduced; the investment and consumption of the catalyst are not required; and the coordinated treatment of pollutants is realized.

Description

technical field [0001] The invention belongs to the technical field of metallurgy and environmental protection, and in particular relates to a fluidized-bed activated carbon adsorption and denitrification method for low-sulfur flue gas. Background technique [0002] The current flue gas denitration methods include SCR, SNCR, moving bed activated carbon adsorption method and oxidation absorption method, and oxidation absorption is divided into dry absorption and wet absorption. SCR, SNCR, and moving bed activated carbon adsorption use ammonia to reduce the denitrification process. The production process of ammonia itself is high energy consumption and high pollution, and the pollutants produced are several times that of ammonia. Using it to denitrify the total amount of pollutants is not The reduction, but the increase, is just the variation and transfer of pollutants. The rationality of this treatment process is open to question; the recovery and treatment of denitrification...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D46/02B01D53/06
CPCB01D46/02B01D53/06B01D2253/102B01D2257/302B01D2257/402B01D2257/404B01D2258/0283Y02C20/10
Inventor 孙中强
Owner SHENYANG DONGDASHANHUI ENVIRONMENTAL TECH CO LTD
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