Method for preparing nano metallized explosive

A nano-metal and nano-metal powder technology, which is applied in the direction of explosives, non-explosive/non-thermal agent components, non-explosive fillers/gelling agents/thickeners, etc., can solve the problem of high activity of nano-metal powders, easy reaction deactivation, The possibility is not high, to achieve the effect of increasing the detonation pressure output, improving the energy release characteristics, and solving the problem that it is not easy to mix uniformly

Inactive Publication Date: 2019-10-18
INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in practical applications, it has been found that the problem of nano-metal powder is serious surface oxidation and low active content. When the particle size of aluminum powder is 50nm, the active aluminum content is about 50%. In recent years, this problem has been solved by surface coating. Technology can be basically solved
Nano-metal powder has high activity and is easy to react and deactivate in water. Therefore, the current application possibility of water suspension granulation technology for nano-metallized explosives is not high.
Mechanical stirring is the most commonly used mixing method, and it is a very effective method for mixing micron metal powder and explosives, but when the particle size of the metal powder is reduced to submicron (particle size less than 1 micron), especially when the nanometer size, the metal powder agglomerates, The uniform mixing of explosives and metal powder cannot be achieved even if the stirring time is increased several times
The screw mixing method is more effective for compounds with relatively low viscosity and solid content, but for explosive compounds filled with high solid particles such as metallized explosives, it is difficult to ensure the uniformity of component mixing and the safety of the mixing preparation process. is also an important factor limiting its application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Weigh 100g of TATB explosive, 30g of aluminum powder with a particle size of 100nm, 10g of tetrafluoroethylene, and 60mL of a binder solution with a mass fraction of 5wt%, and add them into a mixing tank and seal them. Turn on the power, set the vibration frequency to 53Hz, the amplitude to 0.3mm, and the vibration time to 9min. Click the start button, and when the mixing stops, transfer the slurry in the mixing tank to the drying oven for drying. Squeeze into a powder column with a diameter of 20mm, and the test detonation heat value is 5465J / g.

Embodiment 2

[0020] Weigh 100g of LLM-105 explosive, 20g of aluminum powder with a particle size of 100nm, 10g of tetrafluoroethylene, and 60mL of binder solution with a mass fraction of 5wt%, and add them into the mixing tank and seal them. Turn on the power, set the vibration frequency to 50Hz, the amplitude to 0.5mm, and the vibration time to 9min. Click the start button, and when the mixing stops, transfer the slurry in the mixing tank to the drying oven for drying. Squeeze into a powder column with a diameter of 20mm, and the test detonation heat value is 5823J / g.

Embodiment 3

[0023] Weigh 100g of FOX-7 explosive, 10g of aluminum powder with a particle size of 200nm, 30g of tetrafluoroethylene, and 60mL of binder solution with a mass fraction of 5wt%, and add them into the mixing tank and seal them. Turn on the power, set the vibration frequency to 60Hz, the amplitude to 0.6mm, and the vibration time to 6min. Click the start button, and when the mixing stops, transfer the slurry in the mixing tank to the drying oven for drying. Squeeze into a powder column with a diameter of 20mm, and the test detonation heat value is 5281J / g.

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PUM

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Abstract

The invention discloses a method for preparing a nano metallized explosive. The method for preparingthe nano metallized explosivecomprises the following steps that nano metal powders, an explosive, afluoropolymer, and a binder are added into a mixing tank and sealed, then the mixing tank is placed on a vibration table,a power sourceis turned on, vibration frequency,amplitude, and vibration time are adjusted, mixing is conducted after a start button is activated, mixture of the nano metal powders, the explosive, the fluoropolymer, and the binder is completed according to a set mixing time to form a composite slurry, and a nanometalized explosive composite is obtained after drying. According to the method for preparingthe nano metallized explosive, in order to improve the energy release characteristics of metallized explosives, the nano metal powders and the fluoropolymer are used as fillers to improve capacity and pressure output;at the same time, for the high viscosity and easy agglomeration characteristics of the nano metal powders, the nano metallized explosive is prepared by adopting acoustic resonance mixing technology to achieve uniform mixing between the nano metal powder and explosive particles.

Description

technical field [0001] The invention relates to the technical field of preparation of energetic materials, in particular to a method for preparing nanometer metallized explosives by acoustic resonance mixing. Background technique [0002] Metallized explosives have become the preferred material for weapons and ammunition due to their high calorific value, long duration of shock wave overpressure and diversification of damage effects. Among them, metal powders such as magnesium, aluminum, boron, etc. mainly react with detonation products and oxygen in the environment, and release heat to maintain a high-pressure and high-temperature state for a long time, increasing the damage effect of weapons and ammunition on targets. Metal powder mainly reacts with explosive products and oxygen in the environment to release energy in the secondary reaction process. However, in practical applications, due to the limited oxygen in the explosive products and the environment, a large amount ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C06B27/00C06B23/00
CPCC06B23/001C06B27/00
Inventor 王军师鹏翔徐瑞娟屈延阳
Owner INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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