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Method for improving mechanical property of segmented copolymer thermoplastic elastomer

A thermoplastic elastomer and block copolymer technology, applied in the field of thermoplastic elastomers, can solve the problems of instant deformation, failure, increase in tensile strength, etc., and achieve the effect of improving mechanical properties

Active Publication Date: 2019-11-05
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polymer materials are usually used in the fields of rubber, plastics, coatings, etc. Among them, coatings cannot bear the shearing action of force, and will deform immediately under the action of external force; When the force is large, plastic deformation will occur, and the plastic deformation process is accompanied by the orientation of the polymer chain and the increase of the tensile strength; due to the existence of the chemical cross-linked network, the rubber can undergo large deformation under a small force, and its large deformation Under the condition of elastic recovery, the cross-linked network undergoes obvious tensile orientation, accompanied by a sharp increase in tensile strength, until the cross-linked network is destroyed.

Method used

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  • Method for improving mechanical property of segmented copolymer thermoplastic elastomer
  • Method for improving mechanical property of segmented copolymer thermoplastic elastomer
  • Method for improving mechanical property of segmented copolymer thermoplastic elastomer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Example 1: Mechanical enhancement of equi-quadaxial pre-stretching thermal relaxation based on polystyrene-poly(n-butyl acrylate)-polystyrene (molecular weight: 1.5W-12W-1.5W) triblock thermoplastic elastomer film

[0021] The polystyrene-poly(n-butyl acrylate)-polystyrene triblock thermoplastic elastomer film is pre-stretched to 1.5 times, 3 times, 6 times, and 12 times the area of ​​the initial film respectively by equal 4-axis; Under stretching conditions, put it in 120°C for 8 hours and then cool it down at room temperature. The mechanical properties of the films obtained before and after pre-stretching thermal relaxation were compared. from figure 1 It can be seen that the greater the degree of pre-stretching of the film, the greater the breaking strength of the film obtained after thermal relaxation; the film whose pre-stretching is about 1.5 times the area of ​​the initial film is thermally relaxed, and the breaking strength is 1.5 times that of the initial film...

Embodiment 2

[0023] Example 2: Biaxial asymmetric pre-stretching (uniaxial pre-stretching) based on polystyrene-polyacrylate n-butyl acrylate-polystyrene (molecular weight: 1.5W-12W-1.5W) tri-block thermoplastic elastomer film ) Mechanical enhancement of thermal relaxation

[0024] The polystyrene-poly(n-butyl acrylate)-polystyrene triblock thermoplastic elastomer film is pre-stretched to 2 times, 4 times, and 6 times the length of the initial film respectively by uniaxial; under fixed pre-stretching conditions, Put it in 110°C for 7 hours and then cool it down at room temperature. The mechanical properties of the films obtained before and after pre-stretching thermal relaxation were compared. from image 3 It can be seen that the pre-stretched thermally relaxed films have similar stress-strain curves perpendicular to the stretching direction; from Figure 4 It can be seen that the pre-stretched thermally relaxed films have similar moduli perpendicular to the stretching direction; from ...

Embodiment 3

[0026] Example 3: Pentablock thermoplastic elastomer based on polystyrene-n-butyl polyacrylate-polystyrene-n-butyl polyacrylate-polystyrene (molecular weight: 1.5W-12W-1.5W-12W-1.5W) Mechanical enhancement of biaxially asymmetric pre-stretching thermal relaxation of films The polystyrene-poly(n-butylacrylate)-polystyrene-poly(n-butylacrylate-polystyrene) pentablock thermoplastic elastomer film was biaxially Symmetrical pre-stretching, stretching on one side is 3 times the length of the original film, and stretching on one side is 2 times the length of the original film; under fixed pre-stretching conditions, put it in 120°C for 6 hours and then cool it at room temperature. The mechanical properties of the films obtained before and after pre-stretching thermal relaxation were compared. A film with a larger stretch ratio parallel to the stretching direction has a higher breaking strength and a larger modulus, which is about 2 times the breaking strength of the initial film; a fi...

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Abstract

The invention discloses a method for improving a mechanical property of a segmented copolymer thermoplastic elastomer. The method comprises the following steps that uniaxial pre-stretching, equibiaxial pre-stretching or equal multiaxial pre-stretching or biaxial asymmetric pre-stretching is carried out on the segmented copolymer thermoplastic elastomer, then heat relaxation is carried out on the segmented copolymer thermoplastic elastomer under the condition of keeping the pre-stretching, and then the mechanical property and a driving performance of the segmented copolymer thermoplastic elastomer can be improved. The preparation process and equipment are simple and easy to control, the mechanical property is adjustable, and the self-reinforced polymer material can be developed well throughthe method.

Description

technical field [0001] The invention relates to the field of thermoplastic elastomers, in particular to a method for improving the mechanical properties of block copolymer thermoplastic elastomers. Background technique [0002] Polymer materials are usually used in rubber, plastics, coatings and other fields; among them, coatings cannot bear the shearing action of force, and will deform immediately under the action of external force; When the force is large, plastic deformation will occur, and the plastic deformation process is accompanied by the orientation of the polymer chain and the increase of the tensile strength; due to the existence of the chemical cross-linked network, the rubber can undergo large deformation under a small force, and its large deformation Under the condition of elastic recovery, the cross-linked network undergoes obvious stretching orientation under greater stress, accompanied by a sharp increase in tensile strength until the cross-linked network is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C55/00B29C55/02B29C71/02B29K96/04
CPCB29C55/005B29C55/02B29C71/02B29K2096/04
Inventor 肖友华罗英武李铁风马子鹏
Owner ZHEJIANG UNIV
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