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Polyurethane resin for high black color development leather and preparation method thereof

A polyurethane resin and color development technology, which is applied in the fields of polyurethane resin materials for synthetic leather and materials for synthetic leather, can solve the problems of insignificant improvement in color development performance, small molecular weight of dispersant, poor physical properties, etc., so as to improve the black color development. sexual effect

Active Publication Date: 2021-07-16
ZHEJIANG HUAFON SYNTHETIC RESIN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the amount of polyurethane dispersants on the market is low, the black color development performance of polyurethane resin for leather is not significantly improved. When the amount is increased, the cost will be greatly increased on the one hand, and the physical properties will be adversely affected on the other hand. Furthermore, due to the large molecular weight of the resin, the added dispersant has a relatively small molecular weight, which easily migrates to the surface of the leather, causing fog on the leather surface and seriously affecting the color development effect.

Method used

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  • Polyurethane resin for high black color development leather and preparation method thereof
  • Polyurethane resin for high black color development leather and preparation method thereof
  • Polyurethane resin for high black color development leather and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] The weight percentage composition of the main polyurethane resin and the auxiliary high black color developing resin is as follows:

[0050]Main body polyurethane resin 70%

[0051] Auxiliary high black color developing resin 30%

[0052] The main polyurethane resin is mainly prepared from the following raw materials in parts by weight:

[0053]

[0054] The preparation method of main body polyurethane resin, comprises the steps:

[0055] (1) Add polypolyol and chain extender to the reaction vessel, then add solvent accounting for 70% of the total amount, add catalyst, heat up to 50°C after mixing, stir for 20 minutes, and mix well;

[0056] (2) Add diisocyanate accounting for 95% of the total amount, heat up to 60°C, and react for 2 hours;

[0057] (3) Add the remaining solvent and diisocyanate until the viscosity of the reaction solution reaches 112Pa·s / 25°C, add an end-capping agent, and stir for 30 minutes to obtain the main polyurethane resin.

[0058] The a...

Embodiment 2

[0070] The weight percentage composition of the main polyurethane resin and the auxiliary high black color developing resin is as follows:

[0071] Main body polyurethane resin 90%

[0072] Auxiliary high black color developing resin 10%

[0073] The main polyurethane resin is mainly prepared from the following raw materials in parts by weight:

[0074]

[0075] The preparation method of main body polyurethane resin, comprises the steps:

[0076] (1) Add polypolyol and chain extender to the reaction vessel, then add solvent accounting for 70% of the total amount, add catalyst, heat up to 50°C after mixing, stir for 30min, and mix well;

[0077] (2) Add diisocyanate accounting for 95% of the total amount, heat up to 60°C, and react for 2 hours;

[0078] (3) Add the remaining solvent and diisocyanate until the viscosity of the reaction solution reaches 106 Pa·s / 25°C, add an end-capping agent, and stir for 30 minutes to obtain the main polyurethane resin.

[0079] The auxi...

Embodiment 3

[0090] The weight percentage composition of the main polyurethane resin and the auxiliary high black color developing resin is as follows:

[0091] Main body polyurethane resin 80%

[0092] Auxiliary high black color developing resin 20%

[0093] The main polyurethane resin is mainly prepared from the following raw materials in parts by weight:

[0094]

[0095] The preparation method of main body polyurethane resin, comprises the steps:

[0096] (1) Add polypolyol and chain extender to the reaction vessel, then add solvent accounting for 70% of the total amount, add catalyst, heat up to 50°C after mixing, stir for 20 minutes, and mix well;

[0097] (2) Add diisocyanate accounting for 95% of the total amount, heat up to 70°C, and react for 2 hours;

[0098] (3) Add the remaining solvent and diisocyanate until the viscosity of the reaction solution reaches 109Pa·s / 25°C, add an end-capping agent, and stir for 30 minutes to obtain the main polyurethane resin.

[0099] The ...

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Abstract

The invention discloses a polyurethane resin for high black color development leather and a preparation method thereof, which is composed of 1% to 30% of an auxiliary high black color development resin and the rest of a main polyurethane resin, and the main polyurethane resin is a solvent type Polyurethane resin is mainly made of isocyanate, polypolyol, chain extender, solvent, end-capping agent and auxiliary agent, and the auxiliary high black color development resin is prepared by using the following raw materials in parts by weight: Polyurethane used in the main resin 10-50 parts of polyol, 3-15 parts of polyether polyol, 40-90 parts of aromatic polyester polyol, 30-130 parts of diisocyanate, 5-40 parts of diethanolamine, 0-30 parts of chain extender, catalyst 0.01-0.05 parts, 0.1-1 parts of end-capping agent, 150-450 parts of N,N-dimethylformamide. The invention has excellent performance in black color development performance, greatly improved wear resistance, and is suitable for polyurethane resin for dry-process solvent-type leather.

Description

technical field [0001] The invention relates to a method for preparing polyurethane resin for leather with high black color development, and belongs to the technical field of materials for synthetic leather, in particular to the field of polyurethane resin materials for synthetic leather. Background technique [0002] Polyurethane resin synthetic leather has excellent performance, plump feel and appearance similar to natural leather. It is an excellent leather substitute and has a wide range of applications in the fields of shoes, bags, clothing, furniture and other synthetic leather products. . [0003] Because synthetic leather is mainly used as daily consumer goods, people have higher requirements on the appearance of synthetic leather, and synthetic leather with high blackness can bring more excellent appearance effect. Preparation of polyurethane resin for leather with high black color development performance, and adding various carbon black dispersants are the two mos...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/66C08G18/32C08G18/40C08G18/42C08G18/48C08L75/06C08L75/08C08L75/04
CPCC08G18/3206C08G18/3275C08G18/4018C08G18/4211C08G18/4238C08G18/425C08G18/4833C08G18/6607C08G18/6622C08G18/664C08G18/6674C08L75/06C08L75/08C08L75/04
Inventor 潘伟净张初银孙凡马元明吴震彭峰方飞
Owner ZHEJIANG HUAFON SYNTHETIC RESIN