Method for improving formation interface of lithium ion battery

A lithium-ion battery and interface technology, applied in secondary batteries, electrochemical generators, secondary battery charging/discharging, etc. Improve electrochemical performance, improve chemical interface, and improve the effect of black spots

Active Publication Date: 2020-01-07
安徽益佳通电池有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem solved by the present invention is to provide a method for improving the formation interface of lithium-ion batteries, so as to solve the problem that a small amount of "black spots" appear on the negative electrode sheet after the negative pressure formation of the battery cell proposed in the background technology, and the existence of "spots" indicates The poor chemical formation interface will reduce the electrochemical performance of the battery during use, and its service life will also be shortened, resulting in an increase in cost.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A method for improving the formation interface of a lithium-ion battery, the specific steps are as follows:

[0027] 1) After the lithium-ion battery is baked, liquid injection is performed, which is divided into two times;

[0028] 2) Increase the vacuum position of the battery cell during one injection to ensure that the air inside the battery cell is removed;

[0029] 3) In the state of maintaining negative pressure between the cell and the electrolyte, use nitrogen pressure to perform multiple cycle injections;

[0030] 4) After the liquid injection is completed, the battery cells are put on hold;

[0031] 5) After the shelving is completed, perform secondary liquid injection, pump negative pressure, and then use nitrogen to drive the electrolyte into the cell;

[0032] 6) After the second liquid injection, the battery cell undergoes high-temperature aging;

[0033] 7) Put the aged cell on the fixture, put two gaskets on the screw, and tighten it;

[0034] 8) Th...

Embodiment 2

[0037] The difference between this embodiment and the embodiment 1 is that the liquid injection adopts the method of (vacuum pumping + pressure maintaining + nitrogen injection + pressure maintaining + pressure release), and the liquid injection is performed in three cycles.

Embodiment 3

[0039] The difference between this embodiment and embodiment 1 is that the increase of the vacuum position can completely extract the air inside the winding core, so that the electrode piece can absorb the electrolyte well.

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PUM

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Abstract

The invention provides a method for improving a formation interface of a lithium ion battery. The method comprises steps that 1) after the lithium ion battery is baked, liquid injection is performed totally twice, the vacuumizing position of a battery core is increased during primary liquid injection, that the air in the battery core is removed is guaranteed, a negative pressure state is kept between the battery core and the electrolyte, nitrogen pressure is utilized for multiple times of liquid injection circulation, after the liquid injection is finished, the battery core is subjected to standing, after standing is finished, secondary liquid injection is performed, pumping negative pressure is performed, the electrolyte is injected into the battery core by utilizing the nitrogen, high-temperature aging of the battery core is performed after secondary liquid injection, clamps are arranged on the aged battery core, two gaskets are placed on a screw, the screw is tightened, lithium ionbattery formation is performed by adopting constant current charging, a vacuum valve is opened in the formation process, the battery is subjected to standing for 5 minutes, and the battery is then subjected to 0.2C constant-current charging to 3.34-3.35 V. The method is advantaged in that bad black spots of the formation interface are ameliorated by adjusting the vacuum degree during liquid injection and negative pressure formation, moreover, electrochemical performance of the battery core is improved, and use cost of the battery core is reduced.

Description

technical field [0001] The invention relates to the technical field of lithium-ion battery formation processes, in particular to a method for improving the formation interface of lithium-ion batteries. Background technique [0002] As a "secondary" battery, lithium-ion batteries have the advantages of high specific energy, long life, low pollution, and no memory effect, making them have a broad market in passenger cars, energy storage, forklifts, and ships. In the production process of lithium-ion batteries, formation is a relatively important process. During formation, a layer of solid electrolyte interfacial film (SEI film) will be formed on the surface of the negative electrode sheet. The quality of the SEI film directly affects the cycle life and safety of the battery cell. , thermal stability, self-discharge and internal resistance and other electrochemical properties. Therefore, under the premise of ensuring the excellent electrochemical performance of the battery cel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/44H01M10/0525
CPCH01M10/0525H01M10/446Y02E60/10
Inventor 王秀祥周德清王永军张前兵苏小柳
Owner 安徽益佳通电池有限公司
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