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Dry desulfurization agent for ships, preparation method thereof, and ship dry desulfurization process

A dry desulfurization technology for ships, applied in chemical instruments and methods, separation methods, gas treatment, etc., can solve the problems of by-product utilization, large equipment footprint, and a large amount of waste liquid, etc., to eliminate dust, Low power consumption and high desulfurization efficiency

Inactive Publication Date: 2020-01-21
董红彭
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the more complex process requires more operators, more equipment needs maintenance, and the equipment occupies a large area
In addition, a large amount of waste liquid will be generated during the desulfurization process, and a large amount of water-containing by-products will be produced. At the same time, there are certain problems in the utilization of by-products.

Method used

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  • Dry desulfurization agent for ships, preparation method thereof, and ship dry desulfurization process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Preparation and Evaluation of the Desulfurizing Agent of Example 1 Dry Desulfurization Process

[0040] Mix 30g of activated clay larger than 200 meshes and 70g of calcium hydroxide. After mixing evenly, add 50g of water and mix again. Dry for 12 hours to obtain a dry desulfurizer for ships.

[0041] At a flue gas temperature of 180°C and a SOx concentration of 500ppm, the desulfurization efficiency is 92.5% under the condition of a space velocity of 800 / h using the above-mentioned desulfurizer.

Embodiment 2

[0042] Preparation and Evaluation of Desulfurizer in Example 2 Dry Desulfurization Process

[0043] Mix 30g of activated clay greater than 200 meshes, 10g of attapulgite, 50g of calcium oxide and 10g of magnesium hydroxide. After mixing evenly, add 60g of water and mix again. After mixing evenly, carry out extrusion molding. °C for 4 hours, and then dried at 120 °C for 10 hours to obtain a dry desulfurizer for ships.

[0044] In the flue gas at 200°C, the SOx concentration is 700ppm, the desulfurization efficiency is 93.4% under the space velocity of 600 / h using the above desulfurizer.

Embodiment 3

[0045] Preparation and Evaluation of Desulfurizer in Example 3 Dry Desulfurization Process

[0046]Mix 20g of kaolin larger than 200 mesh, 20g of gypsum and 60g of magnesium hydroxide. After mixing evenly, add 40g of water and mix again. Dry at 120°C for 8 hours to obtain a dry desulfurizer for ships.

[0047] At a flue gas temperature of 220°C and a SOx concentration of 1000ppm, using the above-mentioned desulfurizer, the desulfurization efficiency is 91.3% under the condition of a space velocity of 800 / h.

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Abstract

The invention discloses a dry desulfurization agent for ships, a preparation method thereof, and a ship dry desulfurization process, and belongs to the technical field of ship dry desulfurization. Thepreparation method comprises the following steps: mixing a component A and a component B according to a certain ratio; uniformly mixing the component A and the component B, adding water accounting for 20-60% of the total amount of the component A and the component B, uniformly mixing all the components, carrying out extrusion molding to from strips, activating the molded product at 60-120 DEG C for 2-12 hours, and drying the molded product at 120-200 DEG C for 2-12 hours to obtain the dry desulfurization agent for ships. Ship flue gas is fed from the bottom of a moving bed dry desulfurizationreactor, the ship flue gas is desulfurized by a dry desulfurization agent in the moving bed dry desulfurization reactor, and the desulfurized ship flue gas enters a chimney or a heat exchange systemfrom the upper part of the moving bed dry desulfurization reactor to take heat again. A moving bed process is adopted, a certain dust removal function is achieved, dust generated by heavy oil combustion can be effectively eliminated, an existing flue gas system of a ship is slightly changed, the desulfurization efficiency is high and is 90% or above, stability is achieved, and the influence of external factors is small.

Description

technical field [0001] The invention belongs to the technical field of ship dry desulfurization, and in particular relates to a ship dry desulfurizer, a preparation method thereof and a ship dry desulfurization process. Background technique [0002] Ship exhaust gas pollution mainly comes from fuel oil, and about 90% of the sulfur content in ship fuel oil is emitted in the form of sulfur dioxide. At present, there are three main measures to deal with sulfur emissions from ships: using low-sulfur oil, using LNG fuel instead of fuel oil, and installing ship desulfurization systems. The former two have not been widely used due to insufficient supply of low-sulfur fuel oil, fuel storage and transformation costs, etc. Now countries around the world usually adopt the latter measure to install ship desulfurization systems so that ships can use heavy fuel oil normally. [0003] On July 1, 2018, my country implemented the GB 3552-2018 "Ship Pollutant Discharge Standard", which stric...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/81B01D53/50
CPCB01D53/508B01D2258/01
Inventor 董红彭
Owner 董红彭
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